44 results about "Bromoanisole" patented technology

The application discloses a preparation method of o-bromoanisole. The o-bromoanisole is synthesized through three steps, anisole is used as raw material, p-sulfonic anisole is first synthesized, 2-bromo-4-sulfonic anisole is synthesized on the basis, and finally, the sulfonic group is removed to obtain o-bromoanisole. Since anisole is used as raw material, the problems of multiple by-products, low yield and low purity existing in the synthesis path of phenol are avoided. Meanwhile, all the raw materials of the application have low cost, the process steps are simple, and etherification is not needed. Meanwhile, since anisole is used as raw material, hydrobromic acid and hydrogen peroxide can be used in the intermediate step, the hydrobromic acid is oxidized to generate bromine, the reaction rate can be controlled, the reaction efficiency is improved, the waste of bromine is reduced, the purity of the prepared product can reach 99.4%, the yield reaches 96.26%, and the product can be applied on a large scale in industry.

The invention discloses a synthesis method of bis-ethyl hexyloxyphenol methoxyphenyl triazine, which relates to the technical field of organic chemistry, and comprises the following steps: preparing an intermediate I, putting zinc chloride into reaction, adding xylene for dispersion, dropwise adding the intermediate I, resorcinol and xylene solvent to obtain a yellow intermediate II crude product, and then adding the yellow intermediate II crude product into the reaction kettle to obtain the bis-ethyl hexyloxyphenol methoxyphenyl triazine. Adding the intermediate II, a xylene solvent, an acid-binding agent, chloro-isooctane and bromo-isooctane into a reaction kettle, carrying out reaction treatment to obtain a high-purity product, and carrying out sampling detection on the step 1, the step 2 and the step 3. According to the synthesis method of the bis-ethyl hexyloxyphenol methoxyphenyl triazine, p-bromoanisole and chloro-isooctane or bromo-isooctane are adopted as raw materials, the production cost is reduced, xylene is a single solvent, the problem that a mixed solvent is difficult to recycle is solved, anhydrous aluminum chloride or anhydrous zinc chloride is adopted as a catalyst, and a recrystallization technology is adopted, so that the yield of the bis-ethyl hexyloxyphenol methoxyphenyl triazine is increased. The purity of the product is improved, and the bis-ethyl hexyloxyphenol methoxyphenyl triazine with higher purity is prepared.