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41 results about "Sodium Glycollate" patented technology

Sodium glycolate is the sodium salt of carboxymethyl ether. Starch glycolates are from potato, rice, wheat or corn origin. Sodium glycolate is a white to off-white, tasteless, odorless, relatively free flowing powder.

Recycling processing technology for high-salt wastewater during carboxymethyl cellulose production

The invention discloses a recycling processing technology for high-salt wastewater during carboxymethyl cellulose production. The processing technology combines extraction and graded crystallization technologies. In the graded crystalization process, through multi-effect (or mechanical recompression) evaporation crystallization, crude salt is recovered from wastewater and condensate water is evaporated, the condensate water reaches the industrial reuse water standard, and refined salt is prepared from crude salt through washing; and then through cooling crystallization, sodium glycollate crystal is separated out, the crystallization mother liquid is used for a next crystallization process, so that closed cycle is realized. In the above graded crystallization process, ethoxyacetic acid is obtained by performing extraction separation on a concentrated liquid, and the viscosity is reduced. The method is simple in operation, low in cost and high in separation recovery rate. The whole processing technology employs closed cycle, has no pollutants, and is easy for industrialization. The technology helps to solve the high-salt wastewater processing problem in the carboxymethyl cellulose production process, also helps to realize the recycling processing purposes of turning harm into good and changing wastes into valuables, and has substantial economic, social and environment benefit.
Owner:JIANGNAN UNIV

Treatment method adopting cellulose ether solvent to recycle vinasse

InactiveCN103483457ACelluloseDistillation
The invention discloses a treatment method adopting cellulose ether solvent to recycle vinasse, which comprises the following steps: during the production process of cellulose ether, an organic solvent medium is adopted to distill the vinasse generated during the recycling process to a supersaturated solution or until the moisture is completely evaporated to dryness, ethyl acetate is adopted to perform first extraction so as to filter and separate lost cellulose ether, the ethyl acetate is distilled for recycling, and the leftover after distillation is a secondary product of etherifying agent; first extraction is performed on the subnatant, quantitative hydrogen chloride is added for acidification, then ethyl acetate is added for secondary extraction so as to recycle acetic acid or glycollic acid, the ethyl acetate is distilled and recycled for recycling, the leftover after distillation is acetic acid or sodium glycollate, secondary extraction is performed on the subnatant, alkali is adopted for neutralization, concentration is performed continuously, and sodium chloride is filtered and recycled. According to the invention, as less organic solvent in the concentrated solution is evaporated, and the organic solvent can be used together with a washing solution in the production technology of cellulose ether, zero emission of the three wastes during the production process of the cellulose ether is realized, waste material is changed into things of value, and higher economic benefit is obtained.
Owner:湖北博斐逊生物新材料有限公司

Preparation method of nedaplatin with extremely low silver content

The invention relates to a preparation method of nedaplatin with an extremely low silver content. The preparation method comprises the following steps: allowing cis-diiododiammine platinum to react with silver nitrate at 10-90 DEG C for 0.5-8 hours, filtering, adding the filtrate in an electrolytic cell composed of an anode (a graphite rod) and a cathode (stainless steel), adjusting the electrolytic voltage and current to allow residual silver ions in the solution to be reduced and precipitated, filtering, adding sodium glycollate into the filtrate, adjusting the pH to become neutral, reacting at 40-70 DEG C for 3-10 hours, performing reduced-pressure concentration and crystallization, filtering, washing the filter cake, drying to obtain the nedaplatin with an extremely low silver content. The reaction molar ratio of cis-diiododiammine platinum and silver nitrate is 1:2, and the reaction molar ratio of cis-diiododiammine platinum and sodium glycollate is 1:1. The electrolytic voltage is 0.6-3.0 V, and the current is 5-200 mA. The nedaplatin prepared by the method of the invention has a silver content of less than 1.0 ppm; the content of nedaplatin in the product is more than 99.00%, and the content of related substances is less than 1.00%; the product quality is stable.
Owner:NANJING UNIV OF TECH

Method for extracting sodium glycollate from CMC wastewater

The invention relates to a method for extracting sodium glycollate from CMC wastewater. The method specifically comprises the following steps of extracting a mother solution, evaporating CMC salt-containing wastewater by utilization of an MVR evaporator, and removing 80 percent of inorganic salt to obtain organic matters with 10 to 15 percent of salt and 35 to 55 percent of moisture, thus obtaining the mother solution, wherein for 35 to 50 percent of the organic matters in the mother solution, 90 percent of the organic matters is sodium glycollate; adjusting the PH value of the mother solution to 10 by utilization of sodium hydroxide, filtering at a temperature about 60 DEG C while the mother solution is hot, and extracting from the solution by utilization of an ethanol solvent so as to obtain a crude sodium glycollate solid product; acidizing by utilization of sulfuric acid, taking the sulfuric acid as a catalyst, performing esterification by utilization of methanol so as to obtain methyl glycolate, and finally hydrolyzing and converting the methyl glycolate into a glycolic acid solution with a purity of 70 percent. The method disclosed by the invention has the advantages that the design is complete, the use is convenient, salt contents are effectively removed and a part of recycled water reaching industrial reuse water standards is produced after the CMC wastewater is treated, and residual concentrated wastewater is prepared into chemical products with a higher economic value through further chemical treatment.
Owner:JIANGSU TAILIDA NEW MATERIAL CO LTD

Resource treatment process of high-salt wastewater in carboxymethyl cellulose production

The invention discloses a recycling processing technology for high-salt wastewater during carboxymethyl cellulose production. The processing technology combines extraction and graded crystallization technologies. In the graded crystalization process, through multi-effect (or mechanical recompression) evaporation crystallization, crude salt is recovered from wastewater and condensate water is evaporated, the condensate water reaches the industrial reuse water standard, and refined salt is prepared from crude salt through washing; and then through cooling crystallization, sodium glycollate crystal is separated out, the crystallization mother liquid is used for a next crystallization process, so that closed cycle is realized. In the above graded crystallization process, ethoxyacetic acid is obtained by performing extraction separation on a concentrated liquid, and the viscosity is reduced. The method is simple in operation, low in cost and high in separation recovery rate. The whole processing technology employs closed cycle, has no pollutants, and is easy for industrialization. The technology helps to solve the high-salt wastewater processing problem in the carboxymethyl cellulose production process, also helps to realize the recycling processing purposes of turning harm into good and changing wastes into valuables, and has substantial economic, social and environment benefit.
Owner:JIANGNAN UNIV

Productive technology of vanlillin by glyoxylic acid method

The invention discloses a productive technology of vanlillin by a glyoxylic acid method. The productive technology comprises a synthesis process, a fractionation process and a purification process, wherein the synthesis process comprises condensation treatment, oxidation treatment and decarboxylation treatment of methyl catechol and glyoxylic acid. The productive technology particularly comprisesthe following steps: respectively converting the methyl catechol and the glyoxylic acid into guaiacol sodium and sodium glyoxylate in a sodium hydroxide system; carrying out condensation treatment onthe guaiacol sodium and the sodium glyoxylate; after recovering the unreacted methyl catechol in a condensation liquid, carrying out oxidation treatment, namely carrying out catalytic oxidation on anethanol group in 4-hydroxy-3-methoxybenzene sodium glycolate by using copper oxide in the sodium hydroxide system to form a ketone group, thereby generating a corresponding ketonic acid compound; after separating red copper oxide particles from an oxidation liquid, carrying out decarboxylation treatment, namely using sulfuric acid to acidize the oxidation liquid, and simultaneously converting an acid group in the ketonic acid compound into carbon dioxide so as to generate 4-hydroxy-3- methoxybenzaldehyde; and carrying out the fractionation process and the purification process to obtain the vanlillin.
Owner:喜孚狮王龙香料(宁波)有限公司

A treatment method for reclaiming distillation raffinate from cellulose ether solvent

InactiveCN103483457BCelluloseDistillation
The invention discloses a treatment method adopting cellulose ether solvent to recycle vinasse, which comprises the following steps: during the production process of cellulose ether, an organic solvent medium is adopted to distill the vinasse generated during the recycling process to a supersaturated solution or until the moisture is completely evaporated to dryness, ethyl acetate is adopted to perform first extraction so as to filter and separate lost cellulose ether, the ethyl acetate is distilled for recycling, and the leftover after distillation is a secondary product of etherifying agent; first extraction is performed on the subnatant, quantitative hydrogen chloride is added for acidification, then ethyl acetate is added for secondary extraction so as to recycle acetic acid or glycollic acid, the ethyl acetate is distilled and recycled for recycling, the leftover after distillation is acetic acid or sodium glycollate, secondary extraction is performed on the subnatant, alkali is adopted for neutralization, concentration is performed continuously, and sodium chloride is filtered and recycled. According to the invention, as less organic solvent in the concentrated solution is evaporated, and the organic solvent can be used together with a washing solution in the production technology of cellulose ether, zero emission of the three wastes during the production process of the cellulose ether is realized, waste material is changed into things of value, and higher economic benefit is obtained.
Owner:湖北博斐逊生物新材料有限公司
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