A hollow microsphere masonry dedicated thermal insulation mortar and a dedicated surface mortar, especially a wall self-insulation system-matching hollow microsphere masonry dedicated thermal insulation mortar and a dedicated surface mortar, relate to a constuction energy-saving technology. The hollow microsphere masonry dedicated thermal insulation mortar comprises, by weight, 20-30% of special cement, 2-6% of coal ash, 20-35% of quartz sand, 5-8% of master batch, 35-45% of hollow microphere, and 3-6% of coarse whiting; and the hollow microsphere masonry dedicated surface mortar comprises, by weight, 28-40% of ordinary Portland cement, 3-6% of coal ash, 7-10% polymer, 40-55% of quartz sand, 10-16% of hollow microsphere, and 1-3% of coarse whiting. With a low heat conductivity coefficient, excellent thermal insulation effect, high compression strength, high bonding strength, low contractibility, environment-friendly and fire-proof properties and notable composite economic results, the wall self-insulation system-matching dedicated thermal insulation mortar and a dedicated surface mortar provided in the invention can be widely popularized and used in wall self-insulation system buildings.