The invention provides a low-temperature preparation method of a
zirconium-based
ceramic electrolyte membrane for a fuel
cell. The low-temperature preparation method comprises the following steps: preparing a
zirconium source precursor, which is obtained by mixing raw materials according to the ratio, into
slurry; pressing and molding the
ceramic slurry into a pointed cone array shape; carrying out
copper ion and
zinc ion doping, and
sintering through
microwave plasmas; after
sintering for 0.5 to 1h, obtaining the
electrolyte membrane. According to the low-temperature preparation method provided by the invention, plasmas are generated through
microwave ionized gas, and are gathered on a micro-tip to form a point
discharge effect, so that the
ceramic membrane is rapidly heated; the doped
copper ions and
zinc ions can be used for effectively lowering the
sintering temperature; meanwhile, added
borane gas is added and is cracked, and the surface is densified, so that the uniform and denseceramic
electrolyte membrane is obtained at low temperature, and furthermore, the disadvantages of a traditional
zirconium-based ceramic electrolyte membrane that the sintering density under a low-temperature condition is low and the sintering time is long are solved. Furthermore, the low-temperature preparation method has very important practical significance of reducing the sintering temperature and the sintering time of zirconium-based ceramic electrolyte and improving the density.