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32results about How to "Promote in situ growth" patented technology

Layered double hydroxide composite nano-filtration membrane and preparation method thereof

ActiveCN107583471AHydrophilicHas strong hydrophilicityReverse osmosisFiltration membranePollution
The invention provides a layered double hydroxide composite nano-filtration membrane and a preparation method thereof, and relates to the technical field of membranes. The composite nano-filtration membrane is obtained by modifying to generate a polydopamine functional layer on a base membrane firstly, and then constructing a double hydroxide functional cortex on the surface of a polydopamine-modified membrane in situ. Functional groups of a polydopamine-modified layer can improve the hydrophilcity, the permeability, the selectivity and the anti-pollution performance of the membrane, and can interact with a metal salt precursor, so as to promote the deposition and in-situ growth of the precursor on the surface of the membrane; the double hydroxide layer which is generated in an auxiliary manner is distributed uniformly, has stronger acting force with the base membrane, and is beneficial to the stability of the performance of the membrane. The construction of the double hydroxide functional cortex can be regulated and controlled effectively, which is beneficial to improving the water flux, the hydrophilcity and the chlorine resistance of the membrane. The overall preparation processhas the advantages of mild conditions and convenient operation; the composite nano-filtration membrane with excellent comprehensive performance is obtained, and has the prospect of industrial production and commercial application.
Owner:XIAMEN UNIV OF TECH

Preparing method of Si-B-C-N ceramic with laminated BN(C) grains toughened

The invention provides a preparing method of Si-B-C-N ceramic with laminated BN(C) grains toughened and belongs to the technical field of preparing methods of Si-B-C-N ceramic. The method comprises the steps that 1, cubic silica powder, hexagonal boron nitride powder, graphite powder and lanthanum hexaboride powder are weighed according to the molar ratio and the mass ratio to be served as raw materials for standby application; 2, the raw materials weighed in the step 1 are put into a ball-milling tank, and high-energy ball milling is carried out under the protection of argon atmosphere, so that Si-B-C-N ceramic composite powder containing LaB6 is obtained; the ball material mass ratio is (10-90):1, the ball-milling diameter is 5-9 mm, and ball-milling time is 10-60 h; and 3, the ceramic composite powder obtained in the step 2 is subjected to spark plasma sintering to obtain a Si-B-C-N ceramic material with the laminated BN(C) grains toughened. The Si-B-C-N ceramic material obtained through the preparing method has high breaking tenacity, and the possibility of catastrophic fracture of the ceramic is reduced. The added rare earth compound LaB6 contributes to in-situ growth of the laminated BN(C) grains.
Owner:HARBIN INST OF TECH

Method for preparing spherical aluminum nitride powder under assistance of high atmospheric pressure and fluoride additive

InactiveCN103979507AAccurate control of holding timeLarge particle sizeNitrogen compoundsReaction temperatureNitrogen gas
The invention discloses a method for preparing spherical aluminum nitride powder under the assistance of high atmospheric pressure and a fluoride additive, belonging to the technical field of preparation of non-oxide ceramic powder materials. The method concretely comprises the following steps: evenly mixing aluminum oxide, a carbon source and fluoride additive through a ball-milling technology, drying and then putting in a graphite crucible, transferring into an atmospheric-pressure sintering furnace, performing carbon thermal reduction reaction for 1-6 hours in the nitrogen atmosphere, and maintaining the pressure of nitrogen to be 0.2-2MPa, and the reaction temperature to be 1650-1900DEG C; and after the reaction is completed, putting the obtained product into a muffle furnace, carrying carbon emission for 1-5 hours under the condition of 500-750DEG C, thus obtaining the spherical aluminum nitride powder. The prepared aluminum nitride powder has the characteristics of being high in spherical degree, smooth in the surface, even for particle size distribution and the like, the intermediate particle size is 3-10mu m, and the spherical degree achieves more than 80%; the spherical aluminum nitride powder is very suitable as high-heat-conducting aluminum nitride filler; in addition, the technological method is simple, the raw material cost is relatively low, and large-scale industrial production can be realized.
Owner:天津纳德科技有限公司

Cobweb-like graphene coated beta-FeOOH nano-rod aggregate lithium ion battery negative electrode material preparation method

The invention relates to a cobweb-like graphene coated beta-FeOOH nano-rod aggregate lithium ion battery negative electrode material preparation method, which comprises: dispersing graphene oxide in deionized water to obtain a suspension A; adding FeCl3.6H2O and NaNO3 into deionized water, and adding the obtained solution into the suspension A to obtain suspension B; pouring the suspension B intoa homogeneous phase hydrothermal reaction kettle, sealing the reaction kettle, placing the sealed reaction kettle into a homogeneous phase hydrothermal reaction instrument, and carrying out a reactionto obtain a product C; washing the product C respectively with water and alcohol, and dispersing the washed product in water to obtain a product D; and carrying out freeze drying on the product D toobtain the cobweb-like graphene coated beta-FeOOH nano-rod aggregate lithium ion battery negative electrode material. According to the present invention, the performance of beta-FeOOH is improved by compounding the graphene with the special structure, wherein graphene has advantages of good conductivity and large specific surface area, such that the poor conductivity of beta-FeOOH can be effectively solved by coating the beta-FeOOH with the special cobweb-like graphene while the volume expansion can be inhibited to achieve the stable battery structure so as to improve the cycle stability of the battery.
Owner:SHAANXI UNIV OF SCI & TECH

Silica nanowire array chip for enrichment and detection of circulating tumor cells in whole blood, and preparation method of silica nanowire array chip

The invention relates to a silica nanowire array chip which grows on a polydimethylsiloxane interface and realizes enrichment and detection of circulating tumor cells in whole blood. In an organic phase system, water-in-oil microemulsion is prepared by using the difference in solubility and is assembled on the polydimethylsiloxane interface, so that the in-situ growth of a silica nanowire is catalyzed and promoted, and a silica nanowire array chip is obtained; specific antibodies on the surfaces of the circulating tumor cells are then immobilized on the silica nanowire, so that a silica nanowire array chip having the specific antibodies immobilized on the surfaces of the circulating tumor cells is obtained; a whole blood sample, which is to be tested and contains the circulating tumor cells, is dropwise added onto the surface of the chip, and the specific antibodies on the surfaces of the circulating tumor cells have a synergistic effect with the nanowire structure, so that the circulating tumor cells in the whole blood to be tested can be specifically detected.
Owner:BEIJING SCITECH NANOTECH CO LTD

ZnO nanocluster gas-sensitive sensor taking FTO conductive glass as electrode element

The invention relates to a ZnO nanocluster gas-sensitive sensor with FTO conductive glass subjected to laser etching treatment as an electrode element, and belongs to the technical field of gas sensors. The gas-sensitive sensor consists of two parts, namely a gas-sensitive electrode element and a gas-sensitive material, and is characterized in that the gas-sensitive electrode element is obtained by carrying out laser etching treatment on the FTO conductive glass with the specific pattern and line width, the etched pattern is in an interdigital shape, the width of interdigital stripes is 300-500 mum, and the interval of the interdigital stripes is 20-80 mum; the gas-sensitive material is a ZnO nano-cluster array of a hexagonal wurtzite structure, the diameter of a nanowire is 70-100 nm, andthe length of the nanowire is 2-3.5 mum. The FTO gas-sensitive electrode element has the advantages of low cost, good stability, easiness in in-situ growth of the gas-sensitive material and the like;the sensor has the advantages of low cost, simple process, excellent gas sensitivity, good stability and the like, shows excellent response capability to gases such as ethanol, methanol, hydrogen sulfide and the like, and is a novel gas-sensitive sensor with wide development and application prospects.
Owner:SHANDONG UNIV OF TECH

Method for in-situ preparation of PbTiO3 nano-tube array film by using hydrothermal process

The invention relates to a method of preparing a PbTiO3 nanotube array film in situ by utilizing the hydrothermal method. The method adopts phosphoric acid, hydrofluoric acid, lead acetate and deionized water as raw materials. Firstly, a TiO2 nanotube array film is prepared on the titanium foil sheet through anodic oxidation; and secondly, under the condition that the lead acetate aqueous solution with a molarity of 0.00001 to 10 mol per liter is used as the medium, the TiO2 nanotube array film is adopted as the template, and the hydrothermal reacting solution with a volume percentage of 20 to 90 percent, i.e. the lead acetate aqueous solution is added in and kept constant for 0.5 to 50 hours at a temperature of 150 to 300 DEG C and then the PbTiO3 nanotube array film is finally obtained. The method is fit for manufacturing electronic devices of various types and has a far-ranging application prospect in the industrial fields of piezoelectricity, pyroelectricity and semiconductors.
Owner:TSINGHUA UNIV

Preparation method of graphene-loaded Alpha-FeOOH sandwiched sheet layer-structure lithium ion battery negative electrode material

A preparation method of a graphene-loaded Alpha-FeOOH sandwiched sheet layer-structure lithium ion battery negative electrode material comprises the steps of dispersing graphene oxide in deionized water to obtain a suspension liquid A; adding a ferric nitrate salt into the deionized water, and mixing with the suspension liquid A to obtain a suspension liquid B; pouring the suspension liquid B into a homogeneous phase hydrothermal reaction kettle, sealing the reaction kettle, placing the suspension liquid B in a homogeneous phase hydrothermal reaction instrument for hydrothermal reaction and naturally cooling to a room temperature to obtain a product C; respectively washing the product C with water and alcohol, and dispersing the washed product in the water to obtain a product D; and freezing and drying the product D to obtain the sandwiched sheet layer-structure graphene-loaded Alpha-FeOOH compound. Since graphene is good in conductivity and has relatively large specific area, the conductivity of Alpha-FeOOH can be remarkably improved by loading the graphene, the dispersion performance of the Alpha-FeOOH is simultaneously improved, and agglomeration is prevented. An ultrasonic assistant method and a homogeneous phase hydrothermal method are combined, the material conductivity is improved by combining the Alpha-FeOOH and the graphene, the electrochemical performance is improved, so that the battery is more stable in structure, and the cycle stability of the battery is improved.
Owner:SHAANXI UNIV OF SCI & TECH

Precious metal ion adsorption material based on magnetic metal organic framework and preparation method

The invention provides a preciousmetal ion adsorption material based on a magnetic metal organic framework and a preparation method, and belongs to the technical field of adsorption materials, wherein the central metal of the adsorption material MOFs is Zr, the organic ligand is terephthalic acid or a derivative thereof, and the expression is Fe3O4@SiO2@UiO-66-functional group. The preparation method comprises the following steps: mixing a NaHCO3 solution with a ferric iron salt solution, reacting, and adding a reducing agent solution to obtain Fe3O4 nanoparticles; adding the Fe3O4 nanoparticles into a mixed solution of water and ethanol, uniformly dispersing, adjusting the solution to alkalescence, stirring, and adding tetraethyl orthosilicate to obtain magnetic nanoparticles Fe3O4@SiO2; and adding the magnetic nanoparticles Fe3O4@SiO2 into N, N-dimethylformamide (DMF), and adding ZrCl4 and BDC or a BDC derivative to obtain a Fe3O4@SiO2@UiO-66-functional group. According to the invention, the adsorption material is high in precious metal ion adsorption efficiency, easy to regenerate and capable of being recycled, can achieve solid-liquid separation and material recycling through an external magnetic field, reduces the precious metal recovery cost, and has huge commercial application value in the field of precious metal enrichment and recovery.
Owner:UNIV OF SCI & TECH BEIJING

Preparation method of Co1-xS-MoS2-nitrogen-doped carbon HER/OER bifunctional catalyst

The invention provides a preparation method of a Co1-xS-MoS2- nitrogen-doped carbon ternary composite material with double functions. The preparation method comprises the following steps: firstly, obtaining a cobalt precursor array growing on a carbon paper substrate through chemical bath deposition, and then, obtaining a cubic phase Co9S8 nanorod array through oxidation and vulcanization; dissolving molybdenum salt, dipyridyl or phenanthroline and a carbon source in an N, N-dimethylformamide solution to obtain a Mo < 5 + >-N-C precursor solution, coating the precursor solution on a substrate on which the Co9S8 array structure grows, and performing drying; and with argon or nitrogen taken as a protective gas and a carrier gas, and thesublimation S elementary substance powder as a solid evaporation source, carrying out chemical vapor deposition reaction to obtain a hexagonal-phase Co1-xS and MoS2 and NC compound array. The product obtained by the technical scheme of the invention has the advantages of low equipment requirement, low cost of required raw materials, easy control of reaction conditions, simple production process, good consistency of the formed product, small environmental pollution and the like, and can be used for multifunctional electrocatalysts of HER and OER.
Owner:CHINA THREE GORGES UNIV

Skin external paste made from Chinese medicines and used for treating wound and production method of same

The invention discloses a skin external paste made from Chinese medicines and used for treating wound and a production method of the skin external paste. The skin external paste is made from the following crude drugs in percentage by weight: 18% to 22% of Fructus Forsythiae, 20% to 24% of Radix Astragali, 20% to 24% of Rhizome Coptidis, 24% to 28% of Angelica officinalis, and 8% to 9% of Yunnan Baiyao. The production method of the skin external paste comprises the following steps: putting Fructus Forsythiae, Radix Astragali, Rhizome Coptidis and Angelica officinalis in water of which the total weight is 1.35 to 1.37 times that of the three crude drugs; heating for 30 min with slow fire; filtering with gauze and collecting the filtrate; dissolving Yunnan Baiyao in the filtrate. The skin external paste can induce liquefaction and exfoliation of necrotic tissues and promote rapid in-situ growth of regenerated tissues, avoids surgical treatment and long-term medication, has definite efficacy, is safe and reliable and free of toxic or adverse effect, has abundant drug resources, low price and simple production process, and is easy to use.
Owner:王秀锋

Preparation method of graphene-loaded iron oxide self-assembly mulberry-like structure negative electrode material of lithium-ion battery

The invention discloses a preparation method of a graphene-loaded iron oxide self-assembly mulberry-like structure negative electrode material of a lithium-ion battery. The method comprises the steps of dispersing graphene oxide into ethanol to prepare a suspension A; adding ferrous chloride to deionized water and then mixing with the suspension A to obtain a mixed solution B; pouring the mixed solution B into a heterogeneous hydrothermal reactor for hydrothermal reaction, after the reaction is completed, naturally cooling to a room temperature to obtain a product C; carrying out washing and alcohol washing on the product C separately, dispersing the washed product into water to obtain a product D; and freezing the product D until no liquid exists, and then putting the product D into a freezing dryer to obtain a dried sample, namely the final graphene-loaded iron oxide self-assembly mulberry-like structure negative electrode material of the lithium-ion battery. In-situ growth of iron oxide on the graphene surface is achieved to form a graphene-loaded structure by using coordination of a ferric salt and the graphene oxide; and the preparation method is simple in experimental method, low in cost and easy to implement.
Owner:SHAANXI UNIV OF SCI & TECH

Whisker reinforced zirconium oxide planting integrated crown

ActiveCN112656990AEnhanced phase transformation tougheningPromote in situ growthCoatingsProsthesisNano siliconTitanium metal
The invention discloses a whisker reinforced zirconium oxide planting integrated crown, which comprises a whisker reinforced zirconium oxide substrate, a longitudinally-through screw hole is formed in the center of the whisker reinforced zirconium oxide substrate, and the whisker reinforced zirconium oxide substrate is composed of an implant upper crown, a gum penetrating part and a connecting part used for being connected with an implant from top to bottom; the whisker reinforced zirconium oxide matrix is made of whisker reinforced zirconium oxide, the whisker reinforced zirconium oxide comprises the following raw materials in percentage by mass: 80-99% of zirconium oxide and 1-20% of whisker; the additive comprises the following components in percentage by weight: 0.1-1% of superfine nano aluminum oxide powder and 0-0.1% of superfine nano silicon oxide powder. According to the invention, the aesthetic property requirement can be met, the mechanical strength requirement similar to that of a titanium metal integrated crown can be met, the surface roughness is controllable, and good biological activity and biocompatibility are achieved.
Owner:HANGZHOU ERRAN TECH

A kind of layered double metal hydroxide composite nanofiltration membrane and preparation method thereof

ActiveCN107583471BHydrophilicHas strong hydrophilicityReverse osmosisAntichlorMembrane technology
The invention provides a layered double hydroxide composite nano-filtration membrane and a preparation method thereof, and relates to the technical field of membranes. The composite nano-filtration membrane is obtained by modifying to generate a polydopamine functional layer on a base membrane firstly, and then constructing a double hydroxide functional cortex on the surface of a polydopamine-modified membrane in situ. Functional groups of a polydopamine-modified layer can improve the hydrophilcity, the permeability, the selectivity and the anti-pollution performance of the membrane, and can interact with a metal salt precursor, so as to promote the deposition and in-situ growth of the precursor on the surface of the membrane; the double hydroxide layer which is generated in an auxiliary manner is distributed uniformly, has stronger acting force with the base membrane, and is beneficial to the stability of the performance of the membrane. The construction of the double hydroxide functional cortex can be regulated and controlled effectively, which is beneficial to improving the water flux, the hydrophilcity and the chlorine resistance of the membrane. The overall preparation processhas the advantages of mild conditions and convenient operation; the composite nano-filtration membrane with excellent comprehensive performance is obtained, and has the prospect of industrial production and commercial application.
Owner:XIAMEN UNIV OF TECH

Spraying process for metal part surface treatment

The invention discloses a spraying process for metal part surface treatment. The spraying process comprises the following steps: 1, surface excitation treatment, wherein a metal part is firstly placed in a corona field to be treated for 10-15 minutes, the field intensity of the corona field is 220-250 KV / m, then plasma treatment is adopted, and the treatment is completed; and 2, arrangement of active point locations. According to the spraying process, active medium points are distributed on the surface of the metal part and irradiated by pulsed ion beams, the activity of rare earth lanthanum oxide is excited, and in-situ growth of nano silicon dioxide on the surface of the metal part is promoted, so that a large number of uniform tiny pits are formed, adsorption and bonding of a subsequent spraying layer are facilitated, and the adsorption strength of the spraying layer is improved.
Owner:衢州创普机械设备有限公司

Whisker-reinforced zirconia implants

The invention discloses a whisker-reinforced zirconia implant, which comprises a one-stage implant and a two-stage implant, the one-stage implant includes a whisker-reinforced zirconia implant matrix 1, and the whisker Strong zirconia implant matrix—an integrated structure composed of the upper abutment, the middle neck for connecting and supporting the abutment, and the lower body for connecting bone tissue and fixing the implant; the two-stage The implant includes a whisker-reinforced zirconia implant base 2, the whisker-reinforced zirconia implant base 2 consists of an upper neck for connecting and supporting the abutment and a lower part for connecting bone tissue and fixing the implant A unitary structure composed of body parts. The invention improves the strength and fracture toughness of the zirconia implant, and takes into account biocompatibility, bioactivity and aesthetic performance.
Owner:HANGZHOU ERRAN TECH

Method for synthesizing anatase titanium dioxide based on eutectic solvent

The invention relates to the technical field of semiconductor photocatalytic material preparation, and provides a method for synthesizing anatase titanium dioxide based on a deep eutectic solvent, which comprises the following steps: S1, dispersing a titanium precursor in first absolute ethyl alcohol to form a solution A; s2, mixing the eutectic solvent with a halogen compound, second absolute ethyl alcohol, deionized water and nitric acid to form a solution B; s3, dropwise adding the solution B obtained in the step S2 into the solution A obtained in the step S1, and aging to obtain titanium dioxide white gel; s4, drying the titanium dioxide white gel obtained in the step S3 to obtain titanium dioxide particles; and S5, grinding the dried titanium dioxide particles, and calcining to obtain the anatase titanium dioxide.
Owner:SOUTHWEST PETROLEUM UNIV

A kind of silver-modified tio2/graphene/bentonite composite material and preparation method thereof

The invention belongs to the field of sewage treatment. It is a silver-modified TiO2 / graphene / bentonite composite material, in which the mass ratio of bentonite to graphene is 50:1-5, and the mass ratio of silver to graphene is 15-20:1. The preparation method of the above-mentioned silver-modified TiO2 / graphene / bentonite composite material, the steps are as follows: (1) Add hydrazine hydrate and titanium dioxide solution to the graphene oxide suspension, and then dropwise add silver nitrate solution thereto, and perform ultrasonic vibration at the same time ; (2) After the dropwise addition of the silver nitrate solution is completed, add the bentonite suspension to the reaction system while ultrasonic vibrating; (3) Dry the above-obtained intermediate product and then calcine it under an inert atmosphere to finally obtain the composite material. The preparation method in this application is simple, the materials are cheap and easy to obtain, and it not only has the adsorption effect of heavy metals, but also has a photocatalytic effect, and can effectively degrade organic pollutants.
Owner:JIANGSU CHENGGONG CONSTR TECH

A preparation method of ultra-large lamellar rgo loaded ultrafine β-feooh nanoparticles lithium-ion battery anode material

A method for preparing ultra-large sheet RGO loaded ultrafine β-FeOOH nanoparticles lithium-ion battery negative electrode material, dispersing graphene oxide in deionized water to obtain suspension A; adding a certain amount of soluble salt, sodium chloride and urea Add absolute ethanol and deionized water, and then mix with suspension A to obtain suspension B; pour suspension B into a homogeneous hydrothermal reaction kettle, then seal the reaction kettle, and put it into a homogeneous hydrothermal reaction kettle. After the hydrothermal reaction in the reactor, naturally cool to room temperature to obtain product C; wash product C with water and alcohol respectively, and disperse the washed product in water to obtain product D; freeze-dry product D to obtain RGO large sheet-loaded ultrafine β ‑FeOOH nanoparticle lithium-ion battery negative electrode material, the present invention uses composite graphene, particle size reduction method to improve the performance of β‑FeOOH, can provide more electrochemical active sites and ion transport channels, thereby improving the reversible capacity of the battery . 5000mA g ‑1 The lower reversible capacity exceeds 1000mAh g ‑1 , is a very potential lithium battery negative electrode material.
Owner:SHAANXI UNIV OF SCI & TECH

Whisker reinforced zirconium oxide implant

The invention discloses a whisker reinforced zirconium oxide implant. The implant comprises a one-section implant and a two-section implant, wherein the one-section implant comprises a whisker reinforced zirconium oxide implant matrix I; the whisker reinforced zirconium oxide implant matrix I is of an integrated structure consisting of an upper abutment, a middle neck part for connecting and supporting the abutment and a lower body part for connecting bone tissues and fixing the implant; the two-section implant comprises a whisker reinforced zirconium oxide implant matrix II; and the whisker reinforced zirconium oxide implant matrix II is of an integrated structure consisting of an upper neck part for connecting and supporting the abutment and a lower body part for connecting the bone tissues and fixing the implant. According to the invention, the strength and fracture toughness of the zirconium oxide implant are improved, and the biocompatibility, the biological activity and the aesthetic property are considered.
Owner:HANGZHOU ERRAN TECH

A kind of preparation method of nacl modified graphene network coating β-feooh lithium ion battery negative electrode material

A preparation method of a NaCl-modified graphene net-coated Beta-FeOOH lithium ion battery negative electrode material comprises the steps of dispersing graphene oxide in deionized water to obtain a suspension liquid A; adding analytically-pure FeCl<3>.6H<2>O and NaCl into the deionized water, adding the mixture to the suspension liquid A to obtain a suspension liquid B; pouring the suspension liquid B into a homogeneous-phase hydrothermal reaction kettle for hydrothermal reaction to obtain a product C; respectively washing the product C with water and alcohol, and dispersing the washed product in the water to obtain a product D; and freezing and drying the product D to obtain the NaCl-modified graphene net-coated Beta-FeOOH lithium ion battery negative electrode material. The performanceof Beta-FeOOH is improved by employing a composite graphene method, and the reason is that the graphene is good in conductivity and has relatively large specific area; by graphene wrapping, the problem of poor conductivity of Beta-FeOOH can be effectively solved, volume expansion also can be prevented, so that the battery structure is more stable; and by adding the NaCl, the grain size of the product can be controlled, the active sites of oxidization-reduction reaction during lithium intercalation and de-intercalation of the FeOOH are increased, so that the capacity and the cycle stability ofthe battery are improved.
Owner:SHAANXI UNIV OF SCI & TECH

A preparation method of a spider web-like graphene-wrapped β-feooh nanorod aggregate lithium-ion battery negative electrode material

ActiveCN107732168BImprove conductivityStructural recovery and stabilizationMaterial nanotechnologyCell electrodesFreeze-dryingSpider web
The invention relates to a cobweb-like graphene coated beta-FeOOH nano-rod aggregate lithium ion battery negative electrode material preparation method, which comprises: dispersing graphene oxide in deionized water to obtain a suspension A; adding FeCl3.6H2O and NaNO3 into deionized water, and adding the obtained solution into the suspension A to obtain suspension B; pouring the suspension B intoa homogeneous phase hydrothermal reaction kettle, sealing the reaction kettle, placing the sealed reaction kettle into a homogeneous phase hydrothermal reaction instrument, and carrying out a reactionto obtain a product C; washing the product C respectively with water and alcohol, and dispersing the washed product in water to obtain a product D; and carrying out freeze drying on the product D toobtain the cobweb-like graphene coated beta-FeOOH nano-rod aggregate lithium ion battery negative electrode material. According to the present invention, the performance of beta-FeOOH is improved by compounding the graphene with the special structure, wherein graphene has advantages of good conductivity and large specific surface area, such that the poor conductivity of beta-FeOOH can be effectively solved by coating the beta-FeOOH with the special cobweb-like graphene while the volume expansion can be inhibited to achieve the stable battery structure so as to improve the cycle stability of the battery.
Owner:SHAANXI UNIV OF SCI & TECH

A preparation method of graphene-loaded iron oxide self-assembled mulberry-like structure lithium-ion battery negative electrode material

The invention discloses a preparation method of a graphene-loaded iron oxide self-assembly mulberry-like structure negative electrode material of a lithium-ion battery. The method comprises the steps of dispersing graphene oxide into ethanol to prepare a suspension A; adding ferrous chloride to deionized water and then mixing with the suspension A to obtain a mixed solution B; pouring the mixed solution B into a heterogeneous hydrothermal reactor for hydrothermal reaction, after the reaction is completed, naturally cooling to a room temperature to obtain a product C; carrying out washing and alcohol washing on the product C separately, dispersing the washed product into water to obtain a product D; and freezing the product D until no liquid exists, and then putting the product D into a freezing dryer to obtain a dried sample, namely the final graphene-loaded iron oxide self-assembly mulberry-like structure negative electrode material of the lithium-ion battery. In-situ growth of iron oxide on the graphene surface is achieved to form a graphene-loaded structure by using coordination of a ferric salt and the graphene oxide; and the preparation method is simple in experimental method, low in cost and easy to implement.
Owner:SHAANXI UNIV OF SCI & TECH

Preparation method for TiO2/InVO4 composite porous micro-sphere

The invention relates to the field of semiconductor materials and aims to provide a preparation method for a TiO2 / InVO4 composite porous micro-sphere. The method comprises the following steps: adding an NH4VO3 water solution into an InCl3 water solution; adjusting the pH value to 4 and agitating to obtain precipitate; adding the precipitate into a CTAB (Cetyltrimethyl Ammonium Bromide) water solution and carrying out a hydrothermal reaction; filtering, washing and drying the obtained precipitate and carrying out heat treatment to obtain an InVO4 porous micro-sphere; dispersing the InVO4 porous micro-sphere into absolute ethyl alcohol to obtain a dispersion system; gradually dripping polymer type TiO2 sol; filtering and drying the precipitate to finish a dip-coating procedure to obtain a TiO2 gel coated InVO4 porous micro-sphere; adding the TiO2 gel coated InVO4 porous micro-sphere into the water, agitating in a water bath, and filtering, washing and drying the precipitate to obtain a product. According to the preparation method for the TiO2 / InVO4 composite porous micro-sphere, the nucleation and growth problems of a TiO2 nano crystal are solved so as to accelerate the TiO2 nano crystal to grow in the InVO4 composite porous micro-sphere in an in-situ manner and prevent homogeneous separation of the nano crystal in the solution in a traditional method; the problem that the high specific surface area and the recycling of catalytic materials cannot be considered at the same time is solved and the large specific surface area and apparent size can be obtained simultaneously.
Owner:ZHEJIANG UNIV
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