The invention relates to the technical field of anticorrosive paint, in particular to water-based anticorrosive paint, preparation and application in the field of concrete structure protection. The water-based anticorrosive paint comprises a component jia and a component yi, the component jia is prepared from, by weight, 10-20 parts of water-based fluorocarbon emulsion, 10-20 parts of water-basedsilane emulsion, 40-60 parts of water-based epoxy emulsion, 5-10 parts of kaolin, 10-15 parts of talcum powder, 5-10 parts of precipitated barium sulphate, 0.5-1.2 parts of wetting dispersant, 0.5-2parts of defoaming agent, 0.1-0.5 part of neutralizer, 3-10 parts of film forming auxiliary agent, 0.1-0.5 part of thickening agent and 7-15 parts of water, and the component yi is water-based alicyclic amine curing agent. The paint has two functions of sealing primer and finishing paint, has excellent weather resistance performance, adhesive force, alkali resistance performance and concrete permeability, is small in environmental pollution, and can be widely applied to concrete structures of urban viaducts.