This invention relates to an organic-inorganic
hybrid passivation solution and method for
zinc-aluminum-
magnesium plating to
resist blackening. It primarily aims to provide a novel,
pollution-free
passivation solution and treatment method for enhancing the anti-blackening and
corrosion resistance of
zinc-aluminum-
magnesium products, belonging to the field of
metal material surface treatment technology. The
passivation solution contains a key component, an
acrylic acid-phosphonic acid
copolymer, which chelates with
zinc, aluminum, and
magnesium ions on the plating surface through phosphonic acid groups in its molecular chain, constructing a chemically bonded organic-inorganic
hybrid network that significantly improves the adhesion and
corrosion resistance of the passivation film. This
copolymer remains stable under strongly acidic conditions with a pH of 1-3 and can form a film normally. The passivation solution of this invention is
chromium-free,
environmentally friendly and safe, and can be directly applied to continuous zinc plating production lines without a separate
degreasing process, simplifying the process flow.
Zinc-aluminum-magnesium plating treated with this invention exhibits excellent resistance to white
rust and blackening in salt spray tests, effectively replacing traditional chromate passivation processes.