6 results about "Solid phase adsorption" patented technology

This invention discloses a covalent organic framework material for selective solid-phase adsorption and separation, its preparation method, and its applications. The material is prepared by polycondensation reaction of electron-deficient triazine rings with short-chain linkers such as hydrazine hydrate, forming a layered structure with a high specific surface area of ​​602 m² / g and a concentrated pore size of 2.0 nm to 3.0 nm. This structure exhibits high adsorption capacity (up to 1.0 mg / g), rapid adsorption kinetics, and excellent selectivity for PAHs in organic solutions through strong π-π interactions and pore confinement effects. The preparation process is simple and the conditions are mild. The material has good thermal stability (>300℃), and its performance retention rate is higher than 92% after 5 cycles. When applied to the solid-phase adsorption of PAHs in petroleum products such as lubricating oil and white oil, it effectively eliminates matrix interference, allowing direct analysis without complex purification steps after adsorption. This overcomes the limitations of traditional materials such as silica gel and activated carbon, which have weak adsorption capacity and require cumbersome post-treatment, providing a new high-performance adsorption material solution for the efficient detection of trace PAHs in petroleum products.

This invention discloses a resource recovery system for dredged sediment treatment based on ultrasonic extraction and flotation synergy, comprising: a pretreatment unit, a first-stage ultrasonic extraction reaction unit, a second-stage solid-phase adsorption reaction unit, a third-stage flotation separation unit, a dewatering unit, a residual water treatment unit, and a nitrogen and phosphorus recovery unit. It also discloses a resource recovery method for dredged sediment treatment based on ultrasonic extraction and flotation synergy. This invention solves the problems of low pollutant removal rate, high risk of secondary pollution of dredged soil, and limited resource recovery in traditional dredged sediment treatment. Through the synergistic effect of multiple units including "ultrasonic-liquid-solid-phase adsorption-micro-nano bubble flotation," it achieves efficient release of nitrogen and phosphorus, simultaneous removal of microplastics, rapid separation of clean sediment from polluted phases, and recovery of nitrogen and phosphorus for fertilizer production and resource recovery of clean sediment. The entire process is green and low-consumption, suitable for compact layout on water or near shore, and can simultaneously meet the requirements of sediment reduction, harmlessness, and resource recovery.

This application discloses an integrated gas invasion control method that combines inhibition and absorption, applied to wellbores experiencing gas invasion. The method includes the following steps: constructing a composite slurry column system in the wellbore, comprising, from bottom to top, a gas-intake slug and a gas-enhancing slug; the gas-intake slug converts free gas into a solid-phase adsorbed state or a liquid-phase dissolved state by adding gas-intake material to the drilling fluid, thereby reducing the gas volume in situ within the wellbore; the gas-enhancing slug triggers viscosity enhancement when residual gas enters by adding a gas-responsive material to the drilling fluid, increasing fluid resistance and mitigating gas slippage. This application achieves a synergistic gas control effect through a segmented composite slurry column system, first reducing gas volume through absorption and then increasing viscosity and reducing gas flow rate, enabling early proactive intervention in gas invasion, avoiding fluid instability and gas channeling risks, and improving well control success rate.

The present application relates to the technical field of drilling fluid detection, in particular to a green drilling fluid environmental protection performance comprehensive test evaluation method, comprising: configuring a standardized environment simulation reactor, injecting a green drilling fluid sample to be tested and a simulated environment medium containing fresh water sediments, salt water sediments and land soil, separating the whole system liquid-solid mixture after leaching reaction under constant temperature and frequency conditions to obtain filtrate and solid residue. The filtrate is subjected to full component spectrum scanning, compared with a standard spectrum library to identify target pollutants and preliminary concentration interval; the residue is subjected to thermal analysis and gas phase capture, data is imported into a pollutant migration and transformation prediction model, combined with medium physicochemical parameters to calculate solid phase adsorption retention and long-term release potential, and the solid phase occurrence state of pollutants is evaluated. The method can adapt to multi-element environment simulation, completely detect liquid-solid two-phase pollutants, accurately identify pollutants and quantify solid phase occurrence characteristics, and realize comprehensive evaluation of drilling fluid environmental protection performance.

The application discloses a kind of based on ultrasonic extraction floatation cooperation's dredged sediment treatment resource system, comprising: pretreatment unit, first stage ultrasonic extraction reaction unit, second stage solid-phase adsorption reaction unit, third stage floatation separation unit, dehydration treatment unit, residual water treatment unit and nitrogen and phosphorus recovery unit.It also discloses a kind of based on ultrasonic extraction floatation cooperation's dredged sediment treatment resource method.The application solves the problems of low pollutant removal rate, high risk of secondary pollution of dredged soil and limited resource utilization in traditional dredged sediment treatment.Through the cooperation of "ultrasonic-liquid extraction-solid-phase adsorption-micro-nano bubble floatation" multi-unit, efficient release of nitrogen and phosphorus, simultaneous removal of microplastics, rapid separation of clean silt and pollution, and recycling of nitrogen and phosphorus for fertilizer production, the application realizes the resource utilization of clean silt.The whole process is green and low in consumption, suitable for compact arrangement on water or near shore, and can simultaneously meet the needs of sediment reduction, harmless and resource utilization.

The application relates to a preparation method of a solid-phase adsorption resin and application of the solid-phase adsorption resin in uranium purification, and the preparation method comprises the following steps: (1) taking triethylamine, carbodiimide hydrochloride and 1-hydroxyphenyltriazole as catalysts, carrying out a substitution reaction of nitrilotriacetic acid and dialkylamine in dichloromethane solvent, drying a reaction product, and removing impurities through reduced pressure distillation to obtain a polyamide ligand product; and (2) loading the polyamide ligand onto a P120 carrier through a vacuum impregnation method to obtain the solid-phase adsorption resin. The solid-phase adsorption resin is suitable for deep purification of trace plutonium in a large amount of uranium, is suitable for a wide concentration range of uranium, plutonium and acid, has high purification depth, and is simple to operate, and is superior to existing related field separation materials.