The invention provides a synthesis method of Sb2S3 nanorods. The method comprises the following steps that 1, high-purity sulfur and oleylamine are added into a reaction flask, vacuumizing is performed, and stirring and heating are performed at the same time; 2, when the temperature reaches 60 DEG C, nitrogen is replaced three times; 3, when the temperature reaches 90 DEG C, a nitrogen valve is turned on, and a vacuum pump is turned off; after sulfur is dissolved completely, the reaction is stopped; 4, SbCl3 is added into the reaction flask, then, octadecene and oleylamine are added, vacuumizing is performed, and stirring and heating are performed at the same time; 5, when the temperature reaches 60 DEG C, nitrogen is replaced three times; 6, when the temperature reaches 100 DEG C, the nitrogen valve is turned on, the vacuum pump is turned off, when the temperature is increased to 200 DEG C, a sulfur source is injected, after the reaction is performed for 5-20 min, heating is stopped,and the nanorods are obtained after centrifuging. According to the method for synthesizing antimony sulfide through a thermal injection method, the reaction time is greatly shortened, the crystallinestate can be achieved directly without annealing, and working procedures are simpler.