The invention relates to the technical field of packaging materials, in particular to a high-barrier antiskid packaging film and a preparation method thereof. The packaging film is composed of a CPE film, a PET film, a modified VMPET film and a PE film which are sequentially layered, the CPE film and the PE film are prepared in a three-layer co-extrusion forming mode, and one face of the VMPET film is reversely plated with an aluminum-plated layer formed by metal aluminum, so that the barrier property, the aluminum layer adhesive force and the corona value attenuation period are all obviously improved, and under the severe high-humidity and high-temperature conditions, the interface of the packaged PET/VMPET aluminum plating layer is not layered, so that the integrity of the package is ensured, and the contents are not deteriorated; the packaging material with the CPE (heat-resistant)/PET (polyethylene terephthalate)/modified VMPET/PE (low-temperature) composite structure has the characteristics of balanced internal and external structures, flat bag shape, soft buffering of the outer-layer CPE, puncture and falling resistance, high static friction and good stacking and transporting effect, the problems of stacking slipping and unsmooth transportation are solved, and the whole large package is high in tearing strength and puncture resistance, and can resist falling and impact bag breaking.