The invention relates to a method for synthesizing N,N'-diphenyl-N-(9,9-dimethyl-2-fluorenyl)-N'-(9',9'-dimethyl-7'-bromine-2'-fluorenyl)-benzidine. In the method, a novel convergent synthesis route is adopted, and 9,9-dimethyl-2-aminofluorene and 9,9-dimethyl-2-bromofluorene are respectively used as starting raw materials for respectively preparing two fragments for synthesizing a final product;and finally, the two fragments are condensed and purified to obtain the final product N,N'-di-phenyl-N-(9,9-dimethyl-2-fluorenyl)-N'-(9',9'-dimethyl-7'-bromine-2'-fluorenyl)-benzidine. Because the price of the raw materials used by the synthesis method is low, the consumption of a solvent is small and the solvent is easy to recover, the production cost can be greatly reduced on the premise of guaranteeing the product purity and the productivity, thus the method is suitable for industrial production. In addition, the synthesis method has the advantages of simple operation, convenience, safety,and the like.