The invention belongs to the field of aquatic product processing technology, and specifically relates to an instant double-pepper fish head with a freshwater fish head, capsicum frutescens and red pickled peppers as base materials, and a production method thereof. The freshwater fish head (aristichthys nobilis or silver carp), capsicum frutescens, the red pickled peppers, vegetable oil and the like are used as the base materials and are matched with spices, white sugar, table salt, a flavor agent and other auxiliary materials, and the instant double-pepper fish head (normal-temperature circulating sale type) is prepared through the processes of pretreatment, low-temperature low-salt pickling and deodorization, low-temperature air drying and design finalizing, medium-temperature slight deep-frying, double-pepper sauce seasoning, bagging (placing in pallets) and vacuum sealing, high-temperature short-time sterilization, back-pressure water-spraying cooling and the like. The instant double-pepper fish head maintains the texture and the flavor of a traditional chopped pepper fish head, has the shelf life of more than 180 days at room temperature, has fresh, sweet, sour and spicy compound taste, is fresh, tender, tasty and refreshing, and has the characteristics of being rich in nutrition, and convenient to carry and eat.