The invention belongs to the technical field of photoelectrical-material new energy and relates to a method for preparing a copper, zinc, tin and sulfur film material. The method comprises the following steps that copper nano-powder, zinc nano-powder, and tin nano-powder are used as raw materials and are evenly mixed with sulfur powder, quadrol, absolute ethyl alcohol and sodium borohydride, the mixture is washed and dried after ball milling, and then copper, zinc, tin and sulfur nano-powder is obtained; the nano-powder is evenly mixed with polyvinyl alcohol, isopropanol, and iodine elementary substance, so that a colloidal solution used as an electrophoretic solution is formed; a copper, zinc, tin and sulfur film coating is formed on a substrate through electrophoretic deposition with the electrophoretic deposition method, so that an electrophoretic deposition diaphragm is formed; drying, vulcanization and annealing are carried out on the electrophoretic deposition diaphragm, so that the copper, zinc, tin and sulfur film material is formed. According to the method, the copper, zinc, tin and sulfur film material with the honeycomb-shaped cellular structure is prepared according to the electrophoretic deposition technology and the reduction, vulcanization and annealing comprehensive treatment technology and is large in specific surface area, the cost is reduced, and the solar absorptivity and the efficiency of photovoltaic conversion of a film photovoltaic battery are effectively improved. The method is suitable for manufacturing of the film photovoltaic battery.