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304results about How to "Adjustable performance" patented technology

Trans-1,4-polydialkene composite rubber and preparation methods thereof

The invention relates to a polydialkene composite rubber of trans-1,4- structure and preparation methods thereof. The composite rubber consists of 10 to 80 mass percent of trans-1,4-polyisoprene and 20 to 90 mass percent of trans-1,4-butadiene-isoprene copolymer, wherein over 90 percent of structural units of all dialkenes in the composite rubber have trans-1,4-structures. The first preparation method comprises the following steps of: homopolymerizing isoprene to obtain trans-1,4-polyisoprene by adopting a Ziegler-Natta catalysis system consisting of MgCl2 supported titanium and organic aluminum compound, and then adding butadiene to synthesize the trans-butadiene-isoprene copolymer. The second preparation method comprises the following steps of: adding mixed monomers of butadiene and isoprene into a polymerization device at the same time, performing copolymerization to obtain the butadiene-isoprene copolymer of the trans-1,4-structure, and continuously polymerizing the isoprene to obtain the trans-1,4-polyisoprene after the butadiene with high polymerization speed is completely consumed. The used polymerization device is a stirring reaction kettle or a screw extruder. The composite rubber has excellent performance such as low rolling resistance, low generated heat, abrasion resistance, particularly fatigue break increment resistance and the like, and is suitable for dynamically used rubber products such as tyres, vibration absorption materials and the like.
Owner:SHANDONG HUAJU POLYMER MATERIALS CO LTD

Solvent type polyurethane structure adhesive and preparation method thereof

InactiveCN104893644ADouble curing effectPlay the effect of curing cross-linkingNon-macromolecular adhesive additivesPolyureas/polyurethane adhesivesCross-linkPolyurethane adhesive
The invention discloses a method for preparing a solvent type polyurethane structure adhesive. The method is characterized in that an isocyanate solidifying agent sealed by a sealing agent and a polyurethane prepolymer at the sealed end of hydroxyl group are mixed to obtain a polyurethane adhesive, or the polyurethane prepolymer sealed by the sealing agent and a trihydroxy compound are mixed, or the polyurethane prepolymer sealed by the sealing agent and the isocyanate solidifying agent sealed by the sealing agent are mixed to be added into an adsorbing filling material to obtain the polyurethane adhesive. When in use, the adhesive is heated and unsealed to obtain the isocyanate solidifying agent or polyurethane prepolymer containing NCO, and reacts with polyurethane prepolymer or the trihydroxy compound to obtain cross-linked and cured polyurethane. The adhesive can be stably stored at the room temperature, can be heated to obtain reaction type bi-component when in construction, and is different from the conventional bi-component solvent type polyurethane which wastes time in the processes of metering, mixing and the like, the construction process is simple, the performance adjustment of the single component polyurethane system is realized, and the unsealed unsealing agent cannot overflow.
Owner:UNIV OF SCI & TECH OF CHINA

Phosphorus-containing network structure flame retardant

The invention relates to a network structure flame retardant. A phosphorus-containing macromolecular network structure flame retardant is developed aiming at the defects that the existing small-molecule flame retardant is easy to volatilize and emigrate, polymer flame retardants are less in types and the application field is limited. The preparation method comprises the following steps: preparing linear prepolymers, namely changing reaction conditions so as to obtain the linear prepolymers of different polymerization degrees; adding trifunctional cross-linked components so as to obtain a macromolecular flame retardant of different network structures; and finally, obtaining the final product through functional group end capping. According to the product, the problems of volatilization and transfer of the small-molecule flame retardant is improved, and the thermal decomposition behavior of the flame retardant can be regulated by changing the structure and reaction degree, so that products suitable for different polymer matrixes can be obtained. The raw materials used in the invention are wide in source and low in price, the polymerization process is mild in conditions and easy to produce, and the flame retardant is controllable in structure and can be independently taken as an intumescent flame retardant or serve as a charring agent or can be compounded with other flame retardants.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

High isotactic polypropylene alloy material and preparation method thereof

ActiveCN104761834AHigh modulusExcellent thermal creep resistancePolymer sciencePolyolefin
The invention discloses a high isotactic polypropylene alloy material and a preparation method thereof. The material contains 5-98.9 parts by weight of polybutylene, 1-80 parts by weight of polypropylene and 0.1-15 parts by weight of propylene-butene copolymer; the isotacticity of the high isotactic polypropylene is larger than 85%, and the smelting point of the high isotatic polypropylene is 115-129 DEG C; the isotacticity of the high isotactic polypropylene is larger than 85%, and the smelting point of the high isotactic polypropylene is 155-169 DEG C; the propylene-butene copolymer contains a random copolymer and a segmented copolymer of propylene-butene. The preparation method uses a titanium/vanadium supported catalyst and adopts a multistage sequential polymerization manner and specifically comprises the steps of carrying out propylene polymerization or butane-1 polymerization, then initiating butane-1 polymerization or propylene polymerization, and respectively carrying out propylene polymerization or butane-1 polymerization, and so on to synthesize the high isotactic polypropylene alloy material. The material is a powdery or spherical product, and has the advantages of excellent impact resistance, thermal creep resistance and low shrinking percentage of polybutylene, high modulus, high surface hardness and fast setting of polypropylene, and the like.
Owner:QINGDAO UNIV OF SCI & TECH +1

Elastic compound metal heat interface material and preparation method thereof

The invention belongs to the technical field of a heat interface material and discloses an elastic compound metal heat interface material. The elastic compound metal heat interface material is formed by compounding indium and a through-hole porous metal sheet, wherein the indium is filled in the through-hole porous metal sheet and covers the upper and lower surfaces of the through-hole porous metal sheet. The invention also discloses a preparation method of the elastic compound metal heat interface material. The method comprises the following steps: preparing the through-hole porous metal sheet at first; adding a proper amount of indium; heating for smelting indium so that smelted indium fills in the through-hole porous metal sheet and covers the upper and lower surfaces of the through-hole porous metal sheet; and finally cooling, thereby obtaining the elastic compound metal heat interface material. The two surfaces of the through-hole porous metal sheet are both through-hole porous metal and the middle core of the through-hole porous metal sheet is a metal solid. The compound material of the through-hole porous metal sheet and indium has higher elasticity and flexibility in the direction vertical to a mounting surface, so that the compound material can be quickly filled in bigger gaps caused by heat sink and an uneven silicon surface, the interface can be completely filled and the heat resistance of the interface can be kept.
Owner:SOUTHEAST UNIV

Oxidized graphene/waterborne polyurethane acrylate composite emulsion and preparation method and application thereof

The invention discloses oxidized graphene / waterborne polyurethane acrylate composite emulsion and a preparation method and an application thereof. The preparation method comprises the following steps: using an in-situ polymerization method, and using vinyl monomer as a continuous phase, and using polyester polyol, diisocyanate, a hydrophilic chain extender, and an inner-crosslinking agent as raw materials for preparing a polyurethane prepolymer and vinyl monomer mixture, end-capping by vinyl, neutralizing by antalkali, and adding aqueous dispersion containing polymerizable surfmer and the oxidized graphene for dispersing in high speed, and then dripping a water-soluble initiator and an outer-crosslinking agent, enabling the vinyl monomer to polymerize with the polyurethane, the oxidized graphene and double-bond-contained surface active monomer, and preparing the oxidized graphene / waterborne polyurethane acrylate composite emulsion. The oxidized graphene / waterborne polyurethane acrylate composite emulsion is used for not only improving the heat resistance of the coating effectively, but also improving the surface salt fog resistance and antiseptic property of the coating. The preparation process of the product is simple, the raw materials can be easily obtained, and the product is easy to promote and apply in the actual industry.
Owner:SHAANXI UNIV OF SCI & TECH
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