The invention discloses a chemical high-chromium cast iron roller which comprises a high-chromium cast iron work layer and a nodular cast iron roller core. Chemical components of the high-chromium cast iron work layer comprise, by mass percent, 2.1%-2.9% of C, 0.4%-0.8% of Si, 0.5%-08% of Si, 0.5%-0.8% of Mn, 15%-20% of Cr, 0.5%-2% of Ni, 0.5%-2% of Mo, 0.2%-3.0% of V, 0.1%-0.4% of Ti, 0.2%-0.8% of Cu, 0.01%-0.03% of RE, smaller than 0.15% of P, smaller than 0.15% of S and the balance iron. During preparation, a composite centrifugation method is adopted for casting; during heat treatment, thetemperature of a forming roller is increased to range from 920 DEG C to 960 DEG C at the speed ranging from 9 DEG/h to 12 DEG/h, heat preservation is carried out, after quenching, the temperature isincreased to range from 200 DEG C to 250 DEG C for tempering, and heat preservation is carried out for 8 h to 10 h. Laser strengthening treatment is carried out, tempering is carried out at the temperature ranging from 200 DEG C to 250 DEG C, and after heat preservation is carried out for 2 h to 3 h, the chemical high-chromium cast iron roller is obtained. According to the chemical high-chromium cast iron roller, no chip off-falling phenomenon happens in the use process, the roller has good corrosion resistance and high hardness and wear resistance, and the service life of the roller is prolonged.