The present application relates to the technical field of
nickel-containing
waste recovery, and specifically discloses a method for producing electrolytic
nickel from
nickel-containing
solid waste raw materials, which blends and calcines nickel-containing waste,
tin-containing waste and a synergist.
Tin in the
tin-containing waste has a
low melting point, can form a Ni3Sn2
metal compound with Ni, and can also form an
alloy phase with Co and Cr, and can permeate between nickel-based
alloy grains, destroying the original dense structure, effectively reducing the
dissolution leaching difficulty of the nickel-based high-temperature
alloy waste, and improving the
dissolution leaching efficiency of nickel in the waste. Meanwhile, through the action of the synergist, rapid heating and melting can be achieved, and the
ferrous iron in the nickel-containing waste can be oxidized to
iron oxide, breaking the dense continuity of the original iron-nickel
metal phase, reducing the subsequent
dissolution leaching difficulty, and by oxidizing Fe 2+ to Fe 3+ , Fe 3+ can form a precipitate at a lower pH, and is easier to separate.