The invention belongs to the technical field of
lithium ion battery diaphragms, and particularly discloses a
polyolefin composite diaphragm for a
lithium battery as well as a preparation method and application of the
polyolefin composite diaphragm. When the
polyolefin composite diaphragm provided by the invention is prepared, the bonding functional layer can be formed without a
coating process, the thickness of the film is reduced, the
adverse effect on the performance of the diaphragm caused by thickening the diaphragm by a
coating is avoided, and the wettability of the polyolefin diaphragm can be improved due to the existence of the bonding functional layer. Besides, the
coupling agent is added into the raw materials, so that the diaphragm can be endowed with stable and firm polar sites, the
binding force between the functional
polymer material and the polyolefin matrix is enhanced, and the formed binding functional layer is fixed on the surface of the diaphragm and is not easy to peel and fall off. According to the diaphragm preparation process provided by the invention, the preparation of one kind of
coating films can be realized almost without modifying an existing wet-process polyolefin diaphragm
production line, so that the process can be simplified, the enterprise load and the production cost can be greatly reduced, and the diaphragm preparation process has a good application prospect and economic value.