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57results about How to "Improve visible light photocatalytic activity" patented technology

Method for preparing sulfur and nitrogen co-doped titanium dioxide with visible light catalytic activity

The invention provides a method for preparing sulfur and nitrogen co-doped titanium dioxide with visible light catalytic activity, which adopts a sol-gel method and comprises the following steps: hydrolyzing titanium ester and introducing sulfur and nitrogen sources to obtain a titanium dioxide sol, wherein the sulfur and nitrogen sources are from thiourea solution; in a sol system, dropwise adding 1 to 5 percent saturated aqueous solution of thiourea to perform the hydrolysis reaction to obtain the sol; then performing aging and volatilizing a diluent to obtain a titanium dioxide gel; drying the titanium dioxide gel and grinding into powders; performing heat treatment on the solid powder; and calcinating to obtain sulfur and nitrogen co-doped titanium dioxide nano powder. In the method, the thiourea is used as the raw materials of the nitrogen and sulfur sources, the sulfur and the nitrogen are simultaneously introduced in the process of the hydrolysis reaction of the sol to achieve synergistic effect and improve the reaction efficiency, raw material consumption is less, the process is simplified, the absorption range of visible light is effectively improved, the wavelength of the visible light is expanded to about 650nm, and the sulfur and nitrogen co-doped titanium dioxide has obvious visible light activity in the photocatalytic degradation reaction of organic pollutant molecules.
Owner:BEIJING UNIV OF CHEM TECH

Hydrothermal method for preparing nano crystal Bi2WO6 powder photocatalytic material with visible light activity

The invention proposes a kind of hydrothermal method used for preparing light catalyzing material with visible light active nano crystal Bi2WO6 powder. The method makes bismuth nitrate and sodium tungstate as raw materials, prepare them into mixed solution, then add into reacting kettle and have hydrothermal treatment for 10 - 48 hours at 100 - 200 Deg. C, take out reacting kettle, after the system cooled to room temperature, repeatedly wash the got output to neutral with deionized water, then dry in vacuum condition, finally through 100 -1000 heat treatment for 0.5 -10 hours, we can obtain light catalyzing material with visible light active nanometer crystal Bi2WO6 powder. The method has such advantages as low synthesizing temperature, large specific surface area of obtained simples and small grains. The prepared material can not only show light catalyzing activeness in ultraviolet, but also show light catalyzing activeness in visible light bound as sunlight or indoor lamplight.
Owner:WUHAN UNIV OF TECH

Bi/g-C3N4 semimetal-organic composite photocatalyst and preparation method

The invention discloses a Bi / g-C3N4 semimetal-organic composite photocatalyst and a preparation method. The preparation method comprises the following steps: (11) mixing a precursor of a bismuth element and graphene-like carbide nitrogen according to the mass ratio of the bismuth element in the precursor to the graphene-like carbide nitrogen being 0.1%-250% so as to obtain a mixture; (12) adding the mixture into 1mol / L salpeter solution so as to obtain a mixture solution, and adjusting the pH value of the mixture solution to be 1-2; and (13) heating the mixture solution in a reduction system of a reducing solvent so as to obtain the Bi / g-C3N4 semimetal-organic composite photocatalyst by an in-situ precipitation method, wherein the temperature is 80-210 DEG C and the heating time is 1 hour-48 hours. The Bi / g-C3N4 semimetal-organic composite photocatalyst and the preparation method which are disclosed by the invention can be used for solving the problem of relatively high cost of the photocatalyst due to expensive precious metal in the prior art.
Owner:CHONGQING TECH & BUSINESS UNIV

Visible light active boron-nickel co-doped titanium dioxide solid solution catalyst and preparation method thereof

The invention relates to visible light active boron-nickel co-doped titanium dioxide solid solution catalyst and a preparation method thereof. The method uses titanium tetrachloride, boron-containing compound and soluble nickel salt as raw materials to prepare the material of the visible light active boron-nickel co-doped titanium dioxide solid solution catalyst by a spray pyrogenation method at a temperature of between 500 and 700 DEG C. The boron-nickel co-doped titanium dioxide solid solution synthesized by the method has high purity, good dispersion, has higher visible light photocatalystic activity, and can be particularly used in the field of environmental pollution treatment. The method has simple process, easily-controlled condition, lower requirement on equipment and low cost, and is convenient for further enlargement of production.
Owner:HUAZHONG NORMAL UNIV

Preparation method for snowflake-shaped ZnO/BiOI composite material

The invention discloses a preparation method for a snowflake-shaped ZnO / BiOI composite material. Firstly, Zn(NO3)3.6H2O and NaOH are dissolved in deionized water; then, lauryl sodium sulfate is dispersed into a mixed solution of absolute ethyl alcohol and deionized water; and next, the two solutions are mixed, and after magnetic stirring is carried out, a microwave-assisted hydrothermal method is adopted, and the flower-shaped ZnO nanorods are obtained. KI and Bi(NO3)3.5H2O are added into ethylene glycol, after a period of magnetic stirring, the prepared flower-shaped ZnO nanorods are added, ultrasonic dispersion is added, and after a solvothermal reaction, the flaxen snowflake-shaped ZnO / BiOI composite material is obtained. Compared with other shapes, the snowflake-shaped ZnO / BiOI composite material is a tightly-stacked laminar BiOI sphere formed on the surfaces of the ZnO nanorods, and the photocatalytic activity is remarkably improved. By means of the solvothermal method, the reaction time and the reaction temperature are controlled easily, equipment is simple, and the cost is low.
Owner:西安环创高科发展有限公司

Sulfur-indium-zinc composite material with homogeneous heterogeneous knot, as well as preparation method and application of material

The invention discloses a sulfur-indium-zinc composite material with a homogeneous heterogeneous knot, as well as a preparation method and an application of the material and belongs to the technical field of material preparation and photocatalysis. The sulfur-indium-zinc composite material disclosed by the invention has a high specific surface area; the phase knot composed of a hexagonal phase and a cubic phase can be used for effectively increasing the separation efficiency of photon-generated carriers of a system, so that the light catalytic activity of visible light of ZnIn2S4 is improved and the sulfur-indium-zinc composite material can be used for efficiently degrading organic pollutants, carrying out photocatalytic sterilization, photolyzing water to prepare hydrogen and carrying out the photocatalysis to selectively oxidize alcohols. The preparation process of a catalyst is simple and low in cost; during the production processing, the green and environment-friendly effects can be realized and the stability of the catalyst is high; the actual production requirements are met and the application potential is great.
Owner:FUZHOU UNIV

Single-step hydrothermal micro-emulsion method for preparing iron-doped nano titanium dioxide powder

The invention relates to a single-step hydrothermal micro-emulsion method for preparing iron-doped nano titanium dioxide powder. The single-step hydrothermal micro-emulsion method specifically comprises the following steps of constituting water-in-oil W / O type micro-emulsion by using alkylphenol ethoxylates (OP-10) as a surfactant, using n-butyl alcohol (C4H9OH) as a cosurfactant, using cyclohexane (C6H12) as an oil phase, using butyl titanate (Ti(OC4H9)4) as a titanium source and using hydrochloric acid (HCl) liquor of ferric chloride (FeCl3.6H2O) as a water phase; uniformly stirring, and transferring into a lined polytetrafluoroethylene reaction kettle for keeping heat for 1 hour-5 hours at a constant temperature of 120 DEG C-160 DEG C, naturally cooling to the room temperature; and washing, separating and drying to prepare the iron-doped nano titanium dioxide powder. According to the single-step hydrothermal micro-emulsion method disclosed by the invention, the iron-doped titanium dioxide is obtained by directly reacting in a low-temperature liquid phase, the preparation process is simple, and the prepared iron-doped nano TiO2 powder is controllable in dimension, uniform in size and provided with average diameter of 10 nm-25 nm; moreover, the iron-doped nano TiO2 powder is expected to be widely applied in the fields such as hydrogen production by photodecomposition of water, degradation of organic pollutants, and the like.
Owner:ZHANJIANG NORMAL UNIV

Graphene/antimony sulfide composite photocatalyst preparation method

The invention discloses a graphene / antimony sulfide composite photocatalyst preparation method. The method comprises adding graphene oxide into deionized water, carrying out ultrasonic dispersion, adding a sulfur source into the solution, carrying out ultrasonic treatment, adding antimony potassium tartrate into the solution, carrying out magnetic stirring to obtain a reaction mixture, carrying out hydro-thermal treatment on the reaction mixture, carrying out cooling, carrying out centrifugation to obtain black precipitates and washing and drying the black precipitates to obtain the graphene / antimony sulfide composite photocatalyst. The graphene / antimony sulfide composite photocatalyst has good compounding effects and high visible light photocatalytic activity and fully utilizes sun lights and indoor natural lights to realize photocatalytic degradation of environment pollutants. The preparation method has the advantages of simple processes, production process environmental friendliness, easy control of reaction parameters, low enforcement cost and excellent product quality and can be widely used for preparation of a graphene-based composite material.
Owner:XIANGTAN UNIV

Preparation method of flower-like BiOCl photocatalyst, prepared BiOCl photocatalyst and application of BiOCl photocatalyst

The invention provides a preparation method of a flower-like BiOCl photocatalyst, the prepared BiOCl photocatalyst and application of the BiOCl photocatalyst. The method comprises the following steps: (1) adding bismuth nitrate and maltose into water, dripping a chloride solution, and stirring to form a bismuth precursor, wherein a molar dose ratio of the bismuth nitrate to maltose is 1:(0.2-3); (2) regulating the pH value of the bismuth precursor to be 5.0-6.5 by adopting an alkaline solution so as to form reactants; (3) reacting the reactants at the temperature of 150-160 DEG C for 24-30 hours so as to obtain a precipitate; (4) washing and drying the obtained precipitate in the step (3), thereby obtaining the BiOCl photocatalyst with a flower-like structure. According to the method disclosed by the invention, the defects in the preparation method of the conventional BiOCl photocatalyst are overcome, the obtained BiOCl photocatalyst is capable of well responding to visible light and has high visible light photocatalytic activity as well as excellent stability and reusability.
Owner:WUHAN TEXTILE UNIV

Preparation method of rutile type boron-doped titania (B-TiO2) microsphere with exposed high energy crystal face {001}

The invention provides a preparation method of a rutile type boron-doped titania (B-TiO2) microsphere with an exposed high energy crystal face {001} and belongs to the technical field of the preparation of inorganic material. The preparation method comprises the following specific steps: adding titanium boride (TiB) into a hydrochloric acid solution hydrazine containing natrium fluoride (NaF) to obtain a mixed solution, forcefully agitating, then transferring the mixed solution to a reactor with a polytetrafluoroethene lining, keeping the mixed solution at a constant temperature of 200 DEG C for 12-24 hours, naturally cooling the mixed solution to the room temperature so as to obtain a product, filtering the product, respectively washing and settling the product with distilled water and absolute ethyl alcohol for three times, drying the product at a temperature of 60-80 DEG C for 12-24 hours, and finally preparing the B-TiO2 microsphere with the exposed high energy crystal face {001}, of which exposing rate nearly reaches 100 percent. The preparation method is simple in preparation technology and good in repeatability; the prepared B-TiO2 microsphere is controllable and uniform in size and has a diameter of 3-5 micron; the element boron is doped, and is uniform in distribution and controllable in the amount of dopping; in addition, the prepared B-TiO2 microphere has excellent visible light catalytic activity, and is likely to be widely applied in the fields of photolytic water hydrogen preparation, organic contaminant degradation and the like.
Owner:ZHANJIANG NORMAL UNIV

Silver-carbon-codoped bicrystal mesoporous titanium dioxide visible light photocatalyst and preparation method thereof

The invention relates to a silver-carbon-codoped bicrystal mesoporous titanium dioxide visible light photocatalyst and a preparation method thereof and belongs to the technical field of visible light photocatalytic materials. The visible light photocatalyst consists of silver nanoparticles, amorphous carbon and bicrystal mesoporous titanium dioxide. Compared with the commercial anatase phase titanium dioxide nano-particle (particle size is 5-10 nm), silver-carbon-codoped bicrystal mesoporous titanium oxide prepared by utilizing the method shows an obviously enhanced visible light photocatalytic activity.
Owner:CHINA ACADEMY OF SPACE TECHNOLOGY

Preparation of composite photocatalyst and application of composite photocatalyst in purification of VOCs

The invention provides a preparation method of a composite photocatalyst and application of the composite photocatalyst in purification of VOCs, and belongs to the technical field of environmental pollution control. The preparation method comprises the following steps: taking commercial nano titanium dioxide as a catalytic main body, polyvinylpyrrolidone as a surfactant, methanol as a solvent, zinc nitrate / cobalt as a metal salt, 2-methylimidazole as an organic ligand and polystyrene nano microspheres as an etching template, preparing a porous metal organic framework ZIF-8 through a one-pot method, and taking the porous metal organic framework ZIF-8 as a carrier, highly uniformly dispersing the PVP modified nano titanium dioxide on the composite photocatalyst of the metal organic framework, enhancing the adsorption performance of the photocatalyst on VOCs in the photocatalytic degradation process, remarkably enhancing the photocatalytic oxidation performance on typical VOCs so that the problems that a traditional titanium dioxide photocatalyst is poor in adsorption performance and low in degradation efficiency are solved.
Owner:紫科装备股份有限公司

Nitrogen-doped titanium dioxide solvent thermal preparation method

The invention provides a solvent-heat preparing method of N-doped TiO2, comprising: adding TiO2 into the solvent of N-containing organic alkali and water or alcohol, ultrasonic vibrating, pouring the mixture into a corrosion-resistant stainless steel hydrothermal reactor at room temperature, raising temperature to make solvent heat reaction, filtering, washing and drying and making it. And the invention overcomes the aggregation growth in the high temperature gas-phase reacting course, directly adopts TiO2 to one-step synthesize it by simple solvent heat synthesis process. And it has good dispersivity, small and uniform particles, high nitrogen doping quantity, high catalytic activity in the sun, etc.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method of self-doped titanium dioxide nanorod

The invention provides a preparation method of a self-doped titanium dioxide nanorod. The method comprises the following steps of: adding butyl titanate [Ti(OC4H9)4] into liquor of hydrazine (N2H4.H2O) and ethylene glycol (C2H6O2); powerfully stirring; then, transferring to a reaction kettle lined with polyvinyl fluoride; maintaining the constant temperature at 200 DEG C for 12-24 hours; naturally cooling to room temperature; and filtering, washing and drying to obtain the self-doped titanium dioxide nanorod provided by the invention. According to the method provided by the invention, self-doped titanium dioxide is directly reduced in a liquid phase without thermal reduction treatment. The preparation method is simple in process, and the self-doped TiO2 nanorod is controllable in size and uniform in dimension, and the average length is 50-80nm and the average diameter is 8-15nm. The self-doped titanium dioxide nanorod prepared by the method provided by the invention is expected to be widely applied to the fields of hydrogen generation by photolysis of water, degradation of organic pollutants and the like.
Owner:ZHANJIANG NORMAL UNIV

Method of producing high visible light active nano titanium dioxide photocatalyst codoped with nitrogen and indium

the invention discloses a new making method of titanium oxide catalyst with high-visible light catalytic activity doped by nitrogen and indium element, which is characterized by the following: adopting titanate ester as primer and nitrogen compound and indium salt as doping agent; using hydrolytic sediment to make nanometer optical catalyst of anatase phase and rutile phased mixed crystal with even grain size of the catalyst at 8. 4nm, crystal form at anatase phase and rutile phase with strong visible optical catalyst activity. The invention uses one non-metal element and one metal ion to dop to prepare the titanium oxide catalyst with high visible optical catalytic activity to be used in the environmental scientific and engineering domain, which has low request for equipment, small grain size for product, large specific surface area, good dispersibility and higher visually optical activity than pure TiO2, single nitrogen doped TiO2 and single indium doped TiO2.
Owner:NANKAI UNIV

Copper-nickel alloy nanowire/titanium dioxide composite material as well as preparation method and application thereof

The invention relates to a copper-nickel alloy nanowire / titanium dioxide composite material as well as a preparation method and application thereof. The copper-nickel alloy nanowire / titanium dioxide composite material comprises copper-nickel alloy nanowires and titanium dioxide granules which are grown on surfaces of the copper-nickel alloy nanowires in situ. The titanium dioxide granules are grown on the surfaces of the copper-nickel alloy nanowires by using a wet chemical method, so that the copper-nickel alloy nanowire / titanium dioxide composite material can be prepared, and the purposes that VOCs are effectively degraded and thus air is purified can be achieved when the copper-nickel alloy nanowire / titanium dioxide composite material is applied to photocatalytic acetaldehyde degradation under visible light.
Owner:SHANGHAI INST OF CERAMIC CHEM & TECH CHINESE ACAD OF SCI

Preparation method of Fe-doped Bi2O2CO3 photocatalyst and Fe-doped Bi2O2CO3 photocatalyst

The invention discloses a preparation method of a Fe-doped Bi2O2CO3 photocatalyst and the Fe-doped Bi2O2CO3 photocatalyst, and belongs to the technical field of photocatalysis. The preparation methodcomprises the following steps: uniformly mixing a dopant containing Fe<3+> in alkaline solvent solution with dissolved Bi(NO3)3 and sodium citrate, and carrying out hydrothermal reaction under the condition of containing ammonia water. The photocatalyst is prepared according to the preparation method. The Fe-doped Bi2O2CO3 photocatalyst disclosed by the invention has the advantages that Fe can bedoped into lattices of Bi2O2CO3, and the absorption of Bi2O2CO3 for visible light can be improved, so that the photocatalytic activity of Bi2O2CO3 for the visible light is improved.
Owner:HUBEI UNIV OF ARTS & SCI

A method of preparing a macroporous/mesoporous stannic sulfide/titanium dioxide photocatalyst

A method of preparing a macroporous / mesoporous stannic sulfide / titanium dioxide photocatalyst is disclosed. The method includes steps of adding absolute ethanol into butyl phthalate, adding tin tetrachloride into the abovementioned solution, and labeling the solution as an A solution, preparing a sodium sulfide solution that has a certain concentration and that is labeled as a B solution, adding the A solution dropwise into the B solution, allowing the mixture to stand for 24 h, transferring the prepared precipitate and solution into a hydrothermal kettle, maintaining the temperature at 180 DEG C for 3-9 h, cleaning the precipitate after hydrothermal treatment, and drying to obtain the macroporous / mesoporous stannic sulfide / titanium dioxide composite photocatalyst. The composite photocatalyst prepared by the method has good visible light photocatalytic activity and can rapidly degrade organic pollutants under visible light.
Owner:襄阳市大学科技园发展有限公司

Preparation method of defective titanium dioxide/ultrathin carbon nitride/defective titanium dioxide Z-type heterojunction photocatalyst

The invention discloses a preparation method of a defective titanium dioxide / ultrathin carbon nitride / defective titanium dioxide Z-type heterojunction photocatalyst, and belongs to the field of photocatalytic water treatment. Comprising the following steps: 1, preparing TiO2 nanoparticles by a sol-gel method; 2, carrying out secondary high-temperature calcination to obtain thin g-C3N4 / ; 3, carrying out ball milling and compounding to obtain TiO2-x / ultrathin g-C3N4 / TiO2-x of a sandwich structure; and 4, carrying out solid-phase reduction to obtain the final defective titanium dioxide / ultrathin carbon nitride / defective titanium dioxide Z-type heterojunction photocatalyst. According to the preparation method of the defective titanium dioxide / ultrathin carbon nitride / defective titanium dioxide Z-type heterojunction photocatalyst, oxygen vacancies are introduced to broaden the light absorption range of the catalyst, a sandwich structure is constructed to increase space conduction and separation of photon-generated carriers, the Z-type heterojunction improves the ability of the photocatalyst to generate strong oxidizing species, and the photocatalytic activity of the photocatalyst is improved. Therefore, the activity and stability of the photocatalyst are stimulated in multiple aspects, and tetracycline or other types of pollutants in water are effectively removed.
Owner:HARBIN INST OF TECH

BiOBr/SiO2 composite aerogel photocatalytic material and preparation method and applications thereof

The invention relates to a BiOBr / SiO2 composite aerogel photocatalytic material, which is prepared by an acid-alkali two-step method. At first, a bismuth source and a bromine source are dissolved in asolvent (anhydrous ethanol or glycol), which is necessary for preparing SiO2 composite aerogel, and water; then anhydrous ethanol (or glycol), ethyl n-silicate, and water are prepared according to avolume ratio of 4:2:1; and finally BiOBr / SiO2 composite aerogel is prepared by an acid-alkali two-step method. The technology is simple, and the prepared BiOBr / SiO2 composite aerogel has the characteristics of BiOBr such as high visible light catalytic activity, and the like, and also has the advantages of silica aerogel, such as high specific surface area, strong adsorption performance, and the like. The BiOBr / SiO2 composite aerogel photocatalytic material can be used as a photocatalytic material and can be applied to the organic sewage processing field.
Owner:QILU UNIV OF TECH

Method for selectively modifying {110} surface of bismuth vanadate with NiOOH assistant

The invention relates to a method for selectively modifying the {110} surface of bismuth vanadate with a NiOOH assistant. The method comprises the following steps: 1) preparing an electrolyte solution; 2) adjusting the pH value of the electrolyte solution prepared in step 1) to 2-12; 3) mixing the solution obtained in step 2) with a Pt / BiVO4 powder to form a uniform suspension; 4) adding a water-soluble nickel salt to the suspension obtained in step 3); 5) uniformly stirring the suspension in step 4) at room temperature, and illuminating the suspension for a certain period of time; and 6) filtering, washing and drying a precipitate obtained in step 5) to obtain a photocatalyst selectively modified with the NiOOH assistant. The synthesis method has the advantages of simplicity in operation,greenness, environmental protection, energy saving, and no need to add various organic surfactants, and the nickel oxyhydroxide has the advantages of wide sources of raw materials, low price, no toxicity, no pollution and stable chemical properties.
Owner:WUHAN UNIV OF TECH

Method for preparing fluorine and tungste co-doped anatase type nano titanium dioxide composite powder

The invention relates to a method for preparing fluorine and tungste co-doped anatase type nano titanium dioxide composite powder, which is characterized by comprising the following steps: 1) preparing butyl titanate, absolute ethanol, acetic acid, HF, deionized water and ammonium tungstate according to a ratio of 20mL:200mL:5mL:(0.1 to 0.15mL):5mL:(85-340g), mixing and uniformly stirring the absolute ethanol and the acetic acid to obtain mixed liquid and dripping the butyl titanate into the mixed liquid to obtain yellowish sol; 2) preparing solution of fluorine and tungsten; 3) adding F-W-H2O into the yellowish sol to obtain milky sol, and standing the milky sol for 2 to 3 days; and 4) washing the milky sol which is stood for 2 to 3 days with deionized water till the pH value is 7, filtering to obtain a precipitate and drying to obtain the fluorine and tungste co-doped anatase type nano titanium dioxide composite powder. The method has the characteristics of low cost and simple preparation process and can realize batch production, and the prepared fluorine and tungste co-doped anatase type nano titanium dioxide composite powder has the characteristics of high catalytic activity and the like.
Owner:WUHAN UNIV OF TECH

Bismuth and zinc doped titanium dioxide photocatalyst and preparation method and application thereof

The invention discloses a bismuth and zinc doped titanium dioxide photocatalyst and a preparation method thereof.The preparation method of the photocatalyst comprises the steps that titanyl sulfate, bismuth nitrate and zinc nitrate solvents are heated, filtered, washed, dried and calcined.The molar ratio of bismuth to titanium is 0-3%, and the molar ratio of zinc to titanium is 0-5%.The prepared bismuth and zinc doped titanium dioxide photocatalyst achieves visible light absorption within the range of 400 nm to 600 nm, and has good visible light photocatalytic degradation efficiency on gas phase methylbenzene.
Owner:INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI

Single-step hydrothermal micro-emulsion method for preparing iron-doped nano titanium dioxide powder

The invention relates to a single-step hydrothermal micro-emulsion method for preparing iron-doped nano titanium dioxide powder. The single-step hydrothermal micro-emulsion method specifically comprises the following steps of constituting water-in-oil W / O type micro-emulsion by using alkylphenol ethoxylates (OP-10) as a surfactant, using n-butyl alcohol (C4H9OH) as a cosurfactant, using cyclohexane (C6H12) as an oil phase, using butyl titanate (Ti(OC4H9)4) as a titanium source and using hydrochloric acid (HCl) liquor of ferric chloride (FeCl3.6H2O) as a water phase; uniformly stirring, and transferring into a lined polytetrafluoroethylene reaction kettle for keeping heat for 1 hour-5 hours at a constant temperature of 120 DEG C-160 DEG C, naturally cooling to the room temperature; and washing, separating and drying to prepare the iron-doped nano titanium dioxide powder. According to the single-step hydrothermal micro-emulsion method disclosed by the invention, the iron-doped titanium dioxide is obtained by directly reacting in a low-temperature liquid phase, the preparation process is simple, and the prepared iron-doped nano TiO2 powder is controllable in dimension, uniform in size and provided with average diameter of 10 nm-25 nm; moreover, the iron-doped nano TiO2 powder is expected to be widely applied in the fields such as hydrogen production by photodecomposition of water, degradation of organic pollutants, and the like.
Owner:ZHANJIANG NORMAL UNIV

Preparation method of photocatalytic complexing agent with high light conductivity and high adsorption performance for purifying air

The invention discloses a preparation method of a photocatalytic complexing agent with high light conductivity and high adsorption performance for purifying air. The preparation method comprises the following steps: (1) synthesizing a composite adsorption carrier; (2) synthesizing a Pd / TiO2 composite colloidal solution, wherein the content of Pd in the Pd / TiO2 composite colloidal solution is controlled to be 0.001-0.1 wt%; and (3) immersing the composite adsorption carrier prepared in the step (1) into the Pd / TiO2 composite colloidal solution prepared in the step (2) for 10-120 minutes, takingout the composite adsorption carrier, and drying the composite adsorption carrier at 25-100 DEG C to obtain the photocatalytic complexing agent with high light conductivity and high adsorption performance for purifying air. The photocatalytic complexing agent with high light conductivity and high adsorption performance for purifying air has high purification efficiency, good water resistance andhigh adsorption performance.
Owner:绍兴蓝竹新材料科技有限公司

Composite photocatalyst, preparation method of composite photocatalyst, and photocatalytic hydrogen production method

The invention relates to a composite photocatalyst, a preparation method of the composite photocatalyst, and a photocatalytic hydrogen production method. The composite photocatalyst is prepared by thefollowing steps: modifying graphite phase carbon nitride by adopting barium niobate nanosheets, and preparing the graphite phase carbon nitride-barium niobate composite photocatalyst. The 3d track ofniobium participates in composition of the valence band, so that the conduction band is enriched in free electrons; due to the diversity of the crystal structure and electron structure, the barium niobate has an appropriate energy band structure and high photo-induced carrier mobility; in addition, the graphite phase carbon nitride is modified by the barium niobate nanosheets, so that heterojunctions are produced between the barium niobate nanosheets and the graphite phase carbon nitride. Due to the special energy band structure produced by the heterojunctions and the carrier transport characteristics, the graphite phase carbon nitride-barium niobate composite photocatalyst having the heterojunction structure is capable of effectively inhibiting compounding of the photo-induced electron holes in a light-catalyzed reaction, and the quantum efficiency is improved. Therefore, the graphite phase carbon nitride-barium niobate composite photocatalyst has excellent visible light photocatalytic activity.
Owner:王楷

Indoor purifier

The invention discloses an indoor purifier. The indoor purifier is characterized in that photocatalyst spray liquid comprises the following components in percentage by weight: 1-2% of modified nanometer TiO2 photocatalyst, 0.5-1% of an antibacterial agent, 30-35% of plant essence, 1-2% of a chelating agent and 60-65% of water, wherein the modified nanometer TiO2 photocatalyst is modified by doping precious metal. According to the photocatalyst spray liquid, by doping a proper amount of the precious metal, the photocatalytic performance is guaranteed, and the photocatalyst spray liquid can continuously play a purification role in dark light or even in the absence of light in a certain period of time. The indoor purifier has the beneficial effects that the indoor purifier has the advantages of high crystallization degree, wide spectral response range, large specific surface area, small grain size, high photocatalytic activity of visible light and the like; the photocatalyst spray liquid is in a water agent form, and can be sprayed in indoor air or on the wall or furniture, the capture rate to the indoor hazardous gas is high, and the use is convenient.
Owner:张亚东

Graphene/silver molybdenum oxide compound visible-light catalyst and preparation method thereof

The invention relates to a graphene / silver molybdenum oxide compound visible-light catalyst and a preparation method thereof, in particular to a method for preparing the graphene / silver molybdenum oxide-combined visible-light catalyst by water and heat, belonging to the technical field of compound materials and photocatalysis. The preparation method comprises the following steps: taking graphene oxide, silver nitrate and ammonium heptamolybdate as raw materials according to certain proportion, mechanically stirring and mixing the raw materials uniformly in sequence, adjusting the pH value of solution, and then utilizing hydro-thermal reaction to prepare the graphene / silver molybdenum oxide compound visible-light catalyst. The photocatalytic degradation experiment shows that the graphene / silver molybdenum oxide compound visible-light catalyst prepared by the method has a good phtocatalytic degradation effect on rhodamine B due to the irradiation of the visible light and is ideal.
Owner:JIANGSU UNIV
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