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58results about How to "Increase the reactive surface area" patented technology

Treatment method of volcanic-ash-paste-reinforced recycled concrete aggregate

ActiveCN106007438AIncrease the reactive surface area of ​​volcanic ashImprove interface performanceSolid waste managementVolcanic ashIon permeability
The invention relates to a treatment method of volcanic-ash-paste-reinforced recycled concrete aggregate. The method comprises the following steps: (1) carrying out crushing treatment and screening on recycled concrete, and drying to obtain recycled aggregate; (2) adding water into a volcanic ash material with the particle size of less than 60 micrometers to prepare a volcanic ash paste, and carrying out ultrasonic dispersion to form a homogeneous paste solution; (3) immersing the dried recycled aggregate in the step (1) in the homogeneous paste solution prepared in the step (2), and stirring; (4) screening the mixture treated in the step (3) to remove the recycled aggregate, and filtering to remove the excessive paste solution; (5) drying the screened recycled aggregate, and carrying out kneading dispersion on the agglomerate aggregate; and (6) screening the recycled aggregate treated in the step (5) to obtain the volcanic-ash-paste-reinforced recycled concrete aggregate. Compared with the mortar prepared from the untreated recycled concrete aggregate, the 3-day compression strength and 28-day compression strength of the mortar prepared from the volcanic-ash-paste-reinforced recycled concrete aggregate are enhanced by 17% or above, the chlorine ion permeability coefficient is lowered by 30% or above, and the new/old interface microhardness of the mortar is enhanced by 30% or above.
Owner:HUNAN UNIV

High-performance super-capacitor electrode material Co-Fe type prussian blue nano cube as well as preparation method and application thereof

The invention relates to a high-performance super-capacitor electrode material Co-Fe type prussian blue nano cube as well as a preparation method and application thereof, and belongs to the technical field of electrode material preparation. According to the preparation method, inorganic cobalt salt and potassium ferricyanide are adopted as reaction raw materials, trisodium citrate is adopted as a complexing stabilizer, a liquid-phase precipitation reaction method is implemented, reaction conditions such as the use amount and the stand aging time of potassium ferricyanide are controlled, a Co-Fe type prussian blue nano cube material with good dispersibility and large specific area is prepared, and the size of the material is about 300nm. By adopting the Co-Fe type prussian blue nano cube material provided by the invention, the capacity of an electrochemical electric container is increased, properties such as the rapid charge and discharge property and the service life of the electric container are improved, the capacitance of the electric container is as high as 447F/g in constant current charge and discharge of 5A/g in a 1mol/L sodium sulfate solution, and the good rate capability is achieved.
Owner:DALIAN NATIONALITIES UNIVERSITY

Catalytic removal device for NOx and CO in tail flue of pi-shaped pulverized coal boiler

The invention discloses a catalytic removal device for NOx and CO in a tail flue of a pi-shaped pulverized coal boiler. The catalytic removal device comprises a shield-type heated surface, a flow guide plate, a flow straightening grid, an active catalytic material, a low-temperature reheater and a low-temperature superheater which are sequentially arranged in the tail flue of the pi-shaped pulverized coal boiler along the flow direction of smoke, wherein the active catalytic material is arranged by virtue of a space in the tail flue of the pi-shaped pulverized coal boiler, NOx is reduced by virtue of CO generated by low-oxygen combustion, and excessive CO is oxidized into CO2, thus the heat efficiency of the boiler is increased while the emission of NOx is effectively reduced. According to the catalytic removal device disclosed by the invention, a heavy-metal oxide catalyst which easily causing secondary pollution is not used, thus normal running of the boiler is not influenced, a running cost is not increased, and a reformation investment is low; the emission of nitrogen oxides at the outlet of the tail flue is effectively reduced in combination with a low-oxygen combustion technology, and meanwhile, the easily-caused problem of efficiency reduction of the boiler due to the low-oxygen combustion is solved; and the catalytic removal device can be used for both environment-friendly reformation for an existing pi-shaped pulverized coal boiler, and design for a newly-constructed pi-shaped pulverized coal boiler.
Owner:HUANENG CLEAN ENERGY RES INST

Method for preparing ZnFe2O4/Fe2O3 three-dimensional heterojunction nano-material by magnetron sputtering

The invention relates to a method for preparing a ZnFe2O4 / Fe2O3 three-dimensional heterojunction nano-material by magnetron sputtering. In a closed environment, Fe and ZnO are taken as target materials, and vacuumized in the closed environment; and when the air pressure in the closed environment is reduced to 2*10<-4>MPa, argon is introduced into the closed environment to serve as sputtering gas;the air pressure of the closed environment is controlled to be 0.15Pa to 0.2Pa, a Fe target material is sputtered through a direct-current sputtering source, the ZnO target material is sputtered by aradio frequency sputtering source, magnetron sputtering is carried out on the Fe target material and the ZnO target material at the same time, and after sputtering is completed, the product is taken out in a muffle furnace for high-temperature annealing treatment to obtain ZnFe2O4 / Fe2O3 three-dimensional heterojunction nano material. The material prepared by the preparation method has a heterogeneous three-dimensional composite nano structure, so that the reaction surface area and the photoelectric catalytic performance of a composite material are effectively improved, and the method can be widely applied to the field of photocatalytic oxidation reduction.
Owner:SOUTHWEST JIAOTONG UNIV

Catalytic-cracking metal passivator

The invention discloses a catalytic-cracking metal passivator which is composed of the following components in parts by weight: 7-9 parts of organic acid, 22-27 parts of triethylamine, 140-160 parts of hydrogen peroxide, 135-160 parts of antimony trioxide, 30-40 parts of ammonium bicarbonate and 160-180 parts of water. According to a formula disclosed by the invention, the ammonium bicarbonate is used and is decomposed along with continuous temperature rise to generate gas, so that a reaction surface area is enlarged to make the antimony trioxide react fully and completely. The catalytic-cracking metal passivator disclosed by the invention is high in antimony content, and the pentavalent antimony passivator is low in viscosity, low in solidifying point, high in thermal decomposition temperature and good in stability, has an obvious effect on pollutant metallic nickel on a passivation catalyst in a catalytic cracking process, and has the antimony hanging rate far more than that of organic antimony and trivalent antimony passivators; and in addition, raw materials used according to the invention are low in toxicity and are free from harm to a human body, secondary pollution to the environment and adverse influences to products and subsequent processing of the products.
Owner:江苏汉光实业股份有限公司

A titanium-based tin x /iro 2 -ta 2 o 5 coated anode

The invention belongs to the technical field of preparation of an insoluble anode in electrochemical industry, and particularly relates to a titanium-based TiNx / IrO2-Ta2O5 coating anode. The titanium-based TiNx / IrO2-Ta2O5 coating anode comprises a titanium base, a TiNx middle layer and an IrO2-Ta2O5 coating, wherein the titanium base is positioned on the inside of the anode, the TiNx middle layer is positioned in the middle of the anode, and the IrO2-Ta2O5 coating is positioned on the outside of the anode; the TiNx middle layer is prepared by carrying out ion nitriding treatment on the titanium base; and the IrO2-Ta2O5 coating is prepared through a thermal decomposition. The titanium-based TiNx / IrO2-Ta2O5 coating anode provided by the invention can achieve the thickness of the TiNx middle layer at 50-200 micrometers and has the advantages of excellent electricity-conducting property and heat-conducting property and corrosion resistance; compared with an anode which is not subjected to nitrizing treatment, the titanium-based TiNx / IrO2-Ta2O5 coating anode provided by the invention achieves more fine surface crack of the IrO2-Ta2O5 coating and no penetrable crack, has larger reaction surface area, can provide more electrochemical reaction places and can be used for effectively enhancing the stability of the anode and prolonging the service life of the anode.
Owner:NORTH CHINA UNIV OF WATER RESOURCES & ELECTRIC POWER

A method for treating recycled concrete aggregate strengthened by volcanic ash

The invention relates to a treatment method of volcanic-ash-paste-reinforced recycled concrete aggregate. The method comprises the following steps: (1) carrying out crushing treatment and screening on recycled concrete, and drying to obtain recycled aggregate; (2) adding water into a volcanic ash material with the particle size of less than 60 micrometers to prepare a volcanic ash paste, and carrying out ultrasonic dispersion to form a homogeneous paste solution; (3) immersing the dried recycled aggregate in the step (1) in the homogeneous paste solution prepared in the step (2), and stirring; (4) screening the mixture treated in the step (3) to remove the recycled aggregate, and filtering to remove the excessive paste solution; (5) drying the screened recycled aggregate, and carrying out kneading dispersion on the agglomerate aggregate; and (6) screening the recycled aggregate treated in the step (5) to obtain the volcanic-ash-paste-reinforced recycled concrete aggregate. Compared with the mortar prepared from the untreated recycled concrete aggregate, the 3-day compression strength and 28-day compression strength of the mortar prepared from the volcanic-ash-paste-reinforced recycled concrete aggregate are enhanced by 17% or above, the chlorine ion permeability coefficient is lowered by 30% or above, and the new / old interface microhardness of the mortar is enhanced by 30% or above.
Owner:HUNAN UNIV

Integral dioxin removal catalyst and preparation method thereof

The invention discloses an integral dioxin removing catalyst, which is prepared by coating a catalyst coating constituted by V2O5, WO3 and TiO2 onto honeycomb ceramic of 30-600 meshes serving as a carrier. The catalyst is a vanadium-tungsten-titanium system catalyst, and has a better anti-poisoning effect on HCl and SO2 in waste incineration tail gas; the honeycomb ceramic of 30-600 meshes is taken as the carrier, and has higher adaptability to flue gas dust due to a regular pore canal, so that industrialization and engineering minimization are realized easily, larger reaction surface area is provided, high reaction efficiency can be kept at high space velocity of flue gas, and the investment cost of the catalyst is reduced; catalyst active ingredients are loaded onto the carrier by using a coating process, so that operation is convenient, and the production efficiency is high; in the preparation process of the catalyst, an inorganic pore forming agent is added, so that void ratio is increased, the contact area between a reactant and the catalytic active ingredients is increased, and the catalyst activity is increased; the inorganic bonding agent is added, so that the bonding performance between the coating and the carrier is enhanced, and the coating firmness is improved; in the presence of the catalyst, the decomposition conversion rate of dioxin is over 95 percent at the temperature of 160-180 DEG C.
Owner:CHONGQING YUANDA CATALYST MFG
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