The invention discloses a catalytic removal device for NOx and CO in a tail flue of a pi-shaped pulverized coal boiler. The catalytic removal device comprises a shield-type heated surface, a flow guide plate, a flow straightening grid, an active catalytic material, a low-temperature reheater and a low-temperature superheater which are sequentially arranged in the tail flue of the pi-shaped pulverized coal boiler along the flow direction of smoke, wherein the active catalytic material is arranged by virtue of a space in the tail flue of the pi-shaped pulverized coal boiler, NOx is reduced by virtue of CO generated by low-oxygen combustion, and excessive CO is oxidized into CO2, thus the heat efficiency of the boiler is increased while the emission of NOx is effectively reduced. According to the catalytic removal device disclosed by the invention, a heavy-metal oxide catalyst which easily causing secondary pollution is not used, thus normal running of the boiler is not influenced, a running cost is not increased, and a reformation investment is low; the emission of nitrogen oxides at the outlet of the tail flue is effectively reduced in combination with a low-oxygen combustion technology, and meanwhile, the easily-caused problem of efficiency reduction of the boiler due to the low-oxygen combustion is solved; and the catalytic removal device can be used for both environment-friendly reformation for an existing pi-shaped pulverized coal boiler, and design for a newly-constructed pi-shaped pulverized coal boiler.