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50results about How to "Regulation content" patented technology

Linear-chain C5/C6 alkane catalyst prepared by sorbitol aqueous phase hydrogenation and preparation method thereof

The invention relates to a preparation method of a linear-chain C5/C6 alkane catalyst prepared by sorbitol aqueous phase hydrogenation. The method comprises the following steps: (1) selecting activated carbon as a catalyst carrier, and drying at the temperature of 100-200 DEG C; (2) adding the dried activated carbon into an ammonium paramolybdate aqueous solution, and drying to obtain a catalyst carrier precursor containing molybdenum; (3) calcining the catalyst carrier precursor containing molybdenum in a muffle furnace to obtain a catalyst carrier containing molybdenum; (4) adding a ruthenium trichloride solution into the catalyst carrier for soaking, and drying to obtain a catalyst carrier precursor containing ruthenium and molybdenum; (5) calcining the catalyst carrier precursor containing ruthenium and molybdenum to obtain an initial catalyst; and (6) performing hydrogen gas reduction on the initial catalyst at the temperature of 250-400 DEG C for 4-8h to obtain the sorbitol aqueous phase hydrogenation catalyst. According to the method, a step soaking method is adopted to inhibit carbon-carbon bond breakage and selectively break carbon-oxygen bonds, so that the selectivity and the excitation capacity of sorbitol hydrodeoxygenation reaction can be improved.
Owner:GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI

A method for preparing aluminum-nitrogen co-doped diamond-like composite film

The invention discloses a method for preparing an aluminum-nitrogen co-doped diamond-like composite film. Two dual-excitation energy source cathode arc coating devices with different characteristics are configured by adopting an ion source-assisted cathode arc deposition technology, one dual-excitation energy source cathode arc coating device adopts a direct-current arc evaporation cathode sourceand is used for installing an aluminum target, and the other dual-excitation energy source cathode arc coating device adopts a pulsed arc evaporation cathode source and is used for installing a graphite target; nitrogen gas is taken as reaction gas in the deposition process, nitrogen gas (N2) is ionized into ionic nitrogen (N<+>) through an ion source, the aluminum target installed on the direct-current arc evaporation cathode source and the graphite target installed on the pulsed arc evaporation cathode source achieve sputtering deposition on the surface of a workpiece by rotating the workpiece, and the component-controllable aluminum-nitrogen co-doped diamond-like composite film is obtained. According to the method for preparing the aluminum-nitrogen co-doped diamond-like composite film,the film is doped with N in an ion mode, and hard aluminum nitride (AlN) and metal Al nanocrystalline particles are promoted to be formed in the diamond-like composite film; and the diamond-like composite film has the advantages of being smooth in surface, high in hardness and toughness and low in stress.
Owner:BEIJING WUKE GUOHUA TECH CO LTD

Catalyst for preparing low-carbon alcohol through carbon dioxide conversion as well as preparation method and application of catalyst

The invention discloses a catalyst for preparing low-carbon alcohol through carbon dioxide conversion and a preparation method and application thereof, and belongs to the technical field of carbon dioxide resource utilization. The preparation method comprises the following steps: carrying out mechanical ball milling on a cobalt simple substance, a cobalt compound and / or a catalyst carrier which are uniformly mixed, and then carrying out heat treatment to obtain a catalyst product after the heat treatment is completed. According to the preparation method of the catalyst for preparing the low-carbon alcohol by converting the carbon dioxide, provided by the invention, the cobalt elementary substance and the oxide or hydroxide of the cobalt are used as raw materials, the interaction between the elementary substance cobalt and a cobalt compound is enhanced under the action of mechanical ball milling, Co0-Cox + double sites are created, and the double sites can catalyze the generation of the alcohol and the growth of a carbon chain; the selectivity of the low-carbon alcohol is greatly promoted, and the selectivity of the low-carbon alcohol is higher than 90%; the preparation method has the characteristics of less waste liquid, low cost, simple process and the like, and has a good application prospect.
Owner:NANJING UNIV OF TECH

Doped CaFe2O4@alpha-Fe2O3 heterojunction composite photocatalyst, and preparation method and applications thereof

ActiveCN106914248ABreak through the limitations of relying solely on multiple chemical reagentsBreak through the limitations of relying on multiple chemical reagentsWater/sewage treatment by irradiationSolid waste disposalHeterojunctionOrganic dye
The invention discloses a doped CaFe2O4@alpha-Fe2O3 heterojunction composite photocatalyst, and a preparation method and applications thereof. According to the preparation method, converter sludge is subjected to hydrochloric acid acidolysis so as to transfer metal ions such as Fe, Ca, Al, Mg, and Mn in converter sludge into an obtained acidolysis liquid, insoluble substances are removed via filtering so as to obtain an acidolysis solution, a certain amount of sodium oxalate is added so as to obtain a mixed solution, and the mixed solution is subjected to hydrothermal reaction, room temperature secondary precipitation, and short time heat treatment so as to obtain a finished product. The component elements of the doped CaFe2O4@alpha-Fe2O3 heterojunction composite photocatalyst all come from converter sludge, no chemical reagent raw material is added, a problem in the prior art that raw materials all come from a plurality of chemical reagents is solved, preparation cost is reduced, a novel method used for high additional value utilization of iron containing metallurgical dust is provided, the obtained doped CaFe2O4@alpha-Fe2O3 heterojunction composite photocatalyst possesses excellent photocatalytic activity and recycling performance, and can be used for photocatalytic degradation of organic dye pollutants in waste water.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Method for reinforcing surface of zirconium-based amorphous alloy through laser irradiation of silicon carbide particles

The invention relates to a method for reinforcing the surface of a zirconium-based amorphous alloy through laser irradiation of silicon carbide particles, and belongs to the technical field of amorphous alloy surface modification. A silicon carbide particle medium is irradiated by laser, a silicon carbide particle phase is introduced into a parent phase on the surface of the zirconium-based amorphous alloy, and the surface hardness and the plastic deformation capacity of the zirconium-based amorphous alloy are improved. The method effectively solves the problems that the mechanical property is difficult to regulate and control, the manufacturing process is complicated and the like in the existing amorphous alloy particle reinforcing method. By changing laser irradiation parameters and types and parameters of the silicon carbide particle medium, the content of the silicon carbide phase on the surface of the zirconium-based amorphous alloy can be effectively regulated and controlled. The method is simple in implementation process, high in efficiency, clean, free of pollution and high in practicability, and can be applied to regulation and control of the surface hardness of the zirconium-based amorphous alloy and enhancement of functional application of the zirconium-based amorphous alloy.
Owner:JILIN UNIV
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