The application discloses an
ion exchange
composite membrane, a preparation and application thereof, and a
hydrogen production device for electrolyzing water, and a preparation method of the
ion exchange
composite membrane comprises the following steps: (1) placing a perfluorosulfonyl
fluoride resin membrane, a reinforcing mesh cloth and the perfluorosulfonyl
fluoride resin membrane in sequence and superimposing to obtain a superimposed membrane, and then performing
hot pressing to obtain a perfluorosulfonyl
fluoride composite membrane; and (2) performing
hydrolysis transformation on the perfluorosulfonyl fluoride composite membrane to obtain the
ion exchange composite membrane. The mesh cloth wire structure of the
perfluorosulfonic acid ion exchange composite membrane prepared by the method is kept intact, the mesh cloth is uniformly distributed, the membrane body is flat and free of bubbles, the
resin matrix and the reinforcing mesh cloth layer do not separate after long-time high-temperature water soaking treatment, the tensile strength is higher, the elongation at break is lower, the surface swelling rate is lower, the structure is denser, the stability is higher, and the performances are better than those of a dipping
coating membrane.