The invention provides a high-
temperature resistance basic anion exchange membrane, and preparation and application thereof, including synthesis of poly-R-iminazole, quaternization, preparation of a blended membrane
casting solution, and membrane formation. The preparation comprises the following steps of: after dissolving, carrying out
polymerization reaction under the action of a
radical initiator to obtain the poly-R-iminazole, wherein R is C1-C10 chain-shaped or ring-shaped monoolefine, dissolving the obtained poly-R-iminazole, adding C1-C6 substituted halogenated
hydrocarbon, and carrying out quaternization of 3-N; adding the
solid into water, increasing the temperature, magnetically stirring to swell and dissolve, adding one or more of imidite,
polyimide, polyether-
ether-
ketone and polyether
sulfone into a polar
organic solvent, blending the two solutions while heating, paving on a glass plate after forming
emulsion, increasing the temperature through a program, and moulding. The membrane disclosed by the invention has the characteristics of easiness for forming a membrane,
high conductivity and good mechanical flexibility,
heat stability and electrochemical stability.