The invention relates to the technical field of skin care beauty cosmetics, and in particular relates to a pure fruit-water, herbal medicine and vinegar skin-beautifying spray and a preparation method thereof. An innovative technical formula is adopted and is characterized by comprising pure fruit water, herbal medicine essence and vinegar, wherein the pure fruit water is given preference and includes apple water, lemon water, grape water and kiwi water; the pure herbal medicine essence includes a licorice root extract, a scutellaria root extract and a phyllanthus emblica Extract; vinegar is the fresh and edible fruit vinegar and includes apple vinegar and lemon vinegar. Compared with the prior art, the preparation method provided by the invention has the advantages and unique characteristics that 'water' serving as the major component in the formula is 100% natural fruit water, which is used in match with the pure herbal medicine essence and fresh fruit vinegar, thus the spray is fully functional. The spray has the effects of long-lasting hydrating, instantaneously repairing, compacting and smoothening, dispelling sallow complexion and whitening, and removing oil and cleaning and refreshing, and is a pure, natural, high-safety and multi-effect skin-beautifying spray.