The invention relates to a laminated
cell and a preparation method thereof, the laminated
cell comprises a narrow-band-gap bottom
cell and a wide-band-gap top cell, and the preparation method comprises the following steps: preparing a
hole transport layer on a transparent conductive substrate of the narrow-band-gap bottom cell; sequentially arranging a first inorganic salt layer and an organic salt layer on the surface of the
hole transport layer to obtain a
perovskite layer; evaporating a second inorganic salt layer on the surface of the
perovskite layer to enable the second inorganic salt layer to react with residual organic salt on the surface of the
perovskite layer, and annealing to obtain a
passivation layer; and sequentially preparing an
electron transport layer, a buffer layer, a conductive layer and an
electrode layer on the
passivation layer to obtain the laminated cell. According to the invention, the problem of surface organic salt residue in a dry-wet two-
step method is overcome, and non-radiative recombination is reduced, so that the service life of a carrier is prolonged, the
overall efficiency of the cell is improved, the sensitivity of a perovskite material to
moisture and
oxygen is reduced, and the long-term stability is improved; the quality of an interface between the perovskite thin film and the
electron transport layer is improved, and charge recombination at the interface is reduced.