The application belongs to the field of membrane separation materials, and discloses a visible light catalytic self-cleaning oil-water separation membrane and a preparation method and application thereof, and comprises the following steps: 4-cyanopentanoic acid dithiobenzoate is used to prepare an
alkyne functionalized RAFT
reagent; the
alkyne functionalized RAFT
reagent is grafted on the
polymerization chain of azidation polyether
sulfone through a
click chemistry reaction to obtain a RAFT
reagent functionalized polyether
sulfone polymer; based on the RAFT reagent functionalized polyether
sulfone polymer, a PES / PES-CPPA membrane is prepared through a non-
solvent induced phase
separation method; a hydrophilic
zwitterion PSBMA is modified on the surface of the PES / PES-CPPA membrane through a RAFT
polymerization method to obtain a super-hydrophilic /
underwater super-oleophobic membrane; Fe 3+ The super-hydrophilic /
underwater super-oleophobic membrane is subjected to complex treatment to obtain the visible light catalytic self-cleaning oil-water separation membrane; and the application significantly improves the stability and effect of the membrane material in long-term use.