The invention discloses high-temperature-resistant conveyor belt cover rubber for a cement plant and a preparation process thereof. The invention belongs to the technical field of conveying belts, andthe conveyor belt cover rubber comprises, by mass, 88-93 parts of ethylene propylene diene monomer, 8-12 parts of chloroprene rubber, 8-10 parts of high-temperature-resistant resin, 6-8 parts of softener, 30-40 parts of carbon black, 4-5 parts of nano zinc oxide, 1-2 parts of stearic acid, 10-20 parts of high-temperature-resistant filler, 5-7 parts of vulcanizing agent, 2-3 parts of accelerant, 3-4 parts of anti-aging agent and 2-3 parts of antioxidant. The preparation process comprises the following steps: gluing the ethylene-propylene-diene monomer and the neoprene, mixing into master batch, controlling the temperature to be 60-75 DEG C, then adding the high-temperature-resistant resin, the zinc oxide, the stearic acid, the accelerant, the anti-aging agent, the thermal oxidant, the carbon black, the softener and the high-temperature-resistant filler step by step, mixing, controlling the mixing temperature to be less than 120 DEG C, and finally controlling temperature to 90 DEG C formolding vulcanization. The prepared cover rubber can be used for a long time at the temperature of 180 DEG C, and has excellent high temperature resistance and reproducibility.