The invention discloses a preparation method of
acrylic acid organic
silicon soap-free copolymerization
emulsion. Unsaturated monomers, organic
silicon, a reactive emulsifier, an initiator and water are adopted as raw materials, temperature of a reaction kettle is controlled by virtue of core-shell
polymerization and
soap-free
polymerization technologies, then treatment is carried out for removing residual monomers, and a neutralizing agent is added for
neutralization, so that
emulsion is obtained. By virtue of the
soap-free
polymerization technology, better water white resistance can be realized with less expensive organic
silicon monomer, and water absorption of a paint film is reduced. By virtue of the core-shell polymerization technology, a core layer with high
glass transition temperature and a shell layer with lower
glass transition temperature are obtained, so that synthetic
emulsion has lower film formation temperature under the condition that the average
glass transition temperature is the same with a homopolymerization technology, usage amount of a coalescing agent is reduced, and influence of
solvent volatilization on atmospheric environment is reduced. The
acrylic acid organic silicon soap-free copolymerization emulsion product does not contain a free emulsifying agent, so that influence of the
acrylic acid organic silicon soap-free copolymerization emulsion product on the environment is greatly reduced, and the acrylic acid organic silicon soap-free copolymerization emulsion product is
environmentally friendly; and the acrylic acid organic silicon soap-free copolymerization emulsion has excellent
weather resistance,
water resistance and
pollution resistance.