The invention relates to a process for casting a wear-resistant hammer head, in particular to a process for casting the wear-resistant hammer head by compounding two kinds of metal liquid. A method for synchronously smelting and pouring the two kinds of metal liquid, and molding by using a stripping plate molding machine is adopted. The process comprises the following steps of: manufacturing a mold, a core box, a sand core and the stripping plate molding machine, molding, smelting, pouring, opening the box for cleaning, and performing heat treatment. The hammer head cast by the process has the characteristics of high toughness, strength and wear resistance, the conditions of cracking and falling-off of a hammer handle and the hammer head can be avoided, and wear resistance is high; the stripping plate molding machine is convenient and easy to use, a casting mold is standard, production efficiency is high, and production cost is low; meanwhile, multiple purposes can be achieved, and hammer heads of multiple specifications can be provided for users.