The present invention relates to a manufacturing method of a complex copper-zinc alloy shell. The method comprises the following steps: 1) sampling: selecting a certain ratio of Zn, C, Mn, Si, Nb, Ti, V, Mo, Cr, Al and Cu; 2) placing the materials in a 5t cover-type resistance furnace for smelting with gas and slag removal, thus carrying out refining with high cleanliness; 3) moulding a shell; 4) carrying out homogeneous annealing treatment for 24 h at of 440 to 460 DEG C. The invention is characterized in that the method optimizes composition of complex copper zinc alloy through experiment and combines with a heat treatment technology, so as to further refine crystal grains and distribution morphology of the second phase of the Cu-Zn alloy, improve stability, strength and toughness of the alloy, and in that the process operation and equipment requirement are simple.