The invention provides a preparation method of a battery edge
passivation composite film layer and a battery piece, and the method comprises the following steps: placing a sliced substrate in a magnetron
sputtering cavity, and controlling the temperature of the substrate at 25-250 DEG C;
sputtering a first target material by using a first medium-frequency power supply so as to deposit and form a
passivation buffer layer on the substrate;
sputtering a second target material by using a
radio frequency power supply so as to deposit and form a
passivation layer on the passivation buffer layer; sputtering a third target material by using a second medium-frequency power supply to deposit and form a passivation
protection layer on the passivation layer to obtain a substrate with a passivation
composite film layer; and the substrate with the passivation
composite film layer is put into an annealing furnace to be subjected to an annealing process, and the temperature range is 100-300 DEG C. Compared with the prior art, the method provided by the invention is suitable for temperature-sensitive low-temperature process batteries such as
heterojunction batteries, HBC batteries, HTBC batteries and the like, and passivation is realized without sacrificing the performance of the battery body.