The invention discloses a composite electrostatic spinning fiber diaphragm material with doped zirconia and compounded polyurethane. The composite electrostatic spinning fiber diaphragm material is prepared from, by weight parts, 80-83 parts of polyvinylidene difluoride, 20-22 parts of polymethyl methacrylate, an appropriate amount of DMF, 2-3 parts of nano boehmite, 0.8-1 part of silane coupling agent KH550, an appropriate amount of deionized water, 2-3 parts of graphite oxide, 2-3 parts of nano zirconia, 3-4 parts of polyethylene glycol, 0.8-1 part of polyvinylpyrrolidone and 2-3 parts of polyurethane. Nano zirconia, graphite oxide and polyurethane and the like are compounded and added into spinning solution, a fiber membrane is obtained through electrostatic spinning, the composite electrostatic spinning fiber diaphragm material has good breaking strength and electrochemical stability, and the hydrophilicity and permeability of the fiber membrane are greatly improved. The fiber membrane can serve as a capacitor diaphragm material, is safe and hydrophilic, has wettability, is high in liquid absorption rate, can meet the high-performance capacitor requirements, and is good in stability.