The invention provides an aviation gasoline composition capable of being used as 91 # lead-free aviation gasoline and a production method thereof, the aviation gasoline composition contains base oil and an additive, and the base oil contains a blending component A, a blending component B and an optional blending component C. The aviation gasoline composition disclosed by the invention meets various index requirements of ASTM D910 standard, ASTM D7547 standard and GB 1787-2018 standard on anti-knock property, evaporability, low-temperature fluidity, stability and the like of 91 # aviation gasoline, meanwhile, the blending components are few, and the components do not need to be highly refined, are cheap and easy to obtain and are wide in source. Besides, the aviation gasoline composition does not contain tetraethyl lead, is environment-friendly, and can meet the requirements of people on environmental protection.