Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

136 results about "Hafnium dioxide" patented technology

Hafnium(IV) oxide is the inorganic compound with the formula HfO₂. Also known as hafnia, this colourless solid is one of the most common and stable compounds of hafnium. It is an electrical insulator with a band gap of 5.3~5.7 eV. Hafnium dioxide is an intermediate in some processes that give hafnium metal.

Sintering resistant, low conductivity, high stability thermal barrier coating/environmental barrier coating/environmental barrier coating system for a ceramic-matrix composite (CMC) article to improve high temperature capability

ActiveUS20060121295A1Sufficient thermalSufficient environmental protectionLiquid surface applicatorsBlade accessoriesCoating systemThermal barrier coating
In accordance with an embodiment of the invention, a thermal barrier coating (TBC) for inclusion in a thermal barrier coating / environmental barrier coating system (TBC / EBC system) for use on a silicon containing material substrate is provided. The TBC comprises a compound having a primary constituent portion and a stabilizer portion stabilizing said primary constituent. The primary constituent portion of the TBC comprises hafnia present in an amount of at least about 5 mol % of the primary constituent. The stabilizer portion of said thermal barrier coating comprises at least one metal oxide comprised of cations with a +2 or +3 valence present in the amount of about 10 to about 40 mol % of the thermal barrier coating.
Owner:GENERAL ELECTRIC CO

Basic glaze for ink jet printing, preparation method of basic glaze, and ceramic tile

The invention discloses a basic glaze for ink jet printing, a preparation method of the basic glaze, and a ceramic tile. The basic glaze for the ink jet printing comprises the following chemical components by weight percentage: 2.0-3.0% of igloss, 13.0-17.0% of aluminium oxide, 64.0-69.0% of silicon dioxide, 0.05-0.2% of ferric oxide, 0.3-0.9% of calcium oxide, 3.0-6.0% of magnesium oxide, 1.4-2.0% of potassium oxide, 1.4-2.0% of sodium oxide, 0.03-0.10% of titanium oxide, 5.0-10.0% of zirconium dioxide and hafnium oxide, 0.01-0.2% of lithium oxide, and 0.1-2.0% of zinc oxide. The basic glaze for the ink jet printing is free from such defects as deformation, bubbles, pin holes, sewage suction and poor color when an ink jet printing technique is used, and a fabricated product has good color, the surface of a glazed tile is fine and smooth, and the product quality and effect can be improved.
Owner:GUANGDONG KITO CERAMICS GROUP CO LTD

IVB-family element modified CaCu3Ti4O12-based pressure-sensitive material and preparation method thereof

InactiveCN101880158AReduce leakage currentLower intrinsic conductanceChemical compositionChemical element
The invention discloses an IVB-family element modified CaCu3Ti4O12-based pressure-sensitive material and a preparation method thereof. The general formula of a chemical composition of the pressure-sensitive material is CaCu3Ti4-xAxO12, wherein A is one or the composition of several of IVB-family elements in the periodic table of chemical elements and is not Ti, and x is equal to 0.002-2. The preparation method comprises the following steps of: proportioning calcium carbonate, copper oxide, titanium dioxide, zirconium dioxide and hafnium dioxide in a stoichiometric ratio of the CaCu3Ti4-xAxO12, wherein, x is equal to 0.002-2; A is one or the composition of several of the IVB-family elements in the periodic table of chemical elements and is not Ti; then carrying out the processes of ball milling, calcining, secondary ball milling, pelleting, shaping, rubber discharging and high-temperature sintering to finally prepare CaCu3Ti4O12-based ceramic with good pressure-sensitive characteristic. The invention effectively improves the pressure-sensitive characteristic of the ceramic, reduces the leakage current thereof, and simplifies the preparation process while holding the high dielectric performance of the pressure-sensitive ceramic, thereby making the ceramic meet commercial demands.
Owner:GUILIN UNIVERSITY OF TECHNOLOGY

Electron beam aligning mark based on hafnium oxide and manufacturing method of mark

The invention discloses an electron beam aligning mark based on hafnium oxide, which belongs to the field of micro and nano fabrication of a semi-conductor device. The electron beam aligning mark based on hafnium oxide comprises a substrate and a hafnium oxide thin film mark plated on the substrate. The invention further provides a manufacturing method which specifically comprises the steps of: (1) cleaning the substrate; (2) carrying out spin coating of an electronic resist on the substrate and forming a pattern array with an aligned mark in the electronic resist through an electron beam photolithography technique; (3) evaporating hafnium oxide thin films on the electronic resist and the substrate; and (4) peeling the hafnium oxide thin films attached to the positive electronic resist to obtain the hafnium oxide mark. The aligned mark obtained by the electron beam lithography is prepared by using hafnium oxide which is high temperature resistive, good in adhesion and low in cost. Compared with the conventional 'titanium+gold' marks, the process cost is reduced, the problem that the gold mark and the Si substrate are not adhered well is solved, the adhesion and high temperature bearing capacity of the aligned mark to the substrate are improved, and the higher aligning precision is maintained.
Owner:HUAZHONG UNIV OF SCI & TECH

Method for making a refractory ceramic material having a high solidus temperature

A powder metallurgy process for the manufacture of powders of a refractory ceramic material, comprising the consecutive steps of:(i) obtaining a dry mixture of a hafnium dioxide HfO2 powder and an yttrium oxide Y2O3 powder;(ii) step of granulation by pelletization of the dry mixture under stirring in order to obtain a granulated mixture, this granulation step comprising the spraying, into the dry mixture, of an aqueous solution comprising polyvinyl alcohol (PVA) and polyethylene glycol (PEG);(iii) drying of the granulated mixture;(iv) filling of a mold with said granulated mixture;(v) isostatical or semi-isostatical pressing of the granulated mixture in order to obtain a compact mixture;(vi) sintering of the compact mixture in order to obtain a refractory ceramic material at a solidus temperature in the range between 2500° C. and 2800° C.
Owner:COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

Vacuum coating preparation method of aviation organic glass and preparation thereof

The invention relates to a vacuum coating preparation method of an aviation organic glass (polymethylmethacrylate). A set of electronic beam evaporation and ion assisted vacuum coating device is used for continuously preparing a structure of three layers of (auxiliary-main-auxiliary) deposition film series, wherein two auxiliary film layers are respectively located on the bottom layer and the upper layer of a main film layer. The two auxiliary film layers are obtained by heating polytetrafluoroethylene resin liquid, evaporating and vaporizing, spraying into a vacuum chamber, ionizing under ion bombardment, and respectively depositing on the surface of the substrate and above the main film layer. The main film layer is deposited on a bottom layer film by film material (one of zirconium dioxide or hafnium oxide) under electronic beam evaporation and ion assisted bombardment so as to form an optical antireflection film. According to the invention, the structure of three layers of films, which is continuously prepared in vacuum, has the characteristics of high adhesion, high light transmissivity, low haze, friction resistance, weak acid and weak base corrosion resistance and the like. The preparation method provided by the invention is further suitable for vacuum coating of polycarbonate (PC) resin, and can be widely applied in industries of aviation, automobiles, car light outer covers and the like.
Owner:宫杰 +2

Preparation method of high K hafnium dioxide amorphous film

The invention relates to a semiconductor technology, and provides a preparation method of a high K hafnium dioxide amorphous film, which solves the problem that preparation processes of existing HfO2 film materials adopt a doping or heating mode to prepare the HfO2 film materials so that amorphous films can not be entirely generated. The preparation method comprises the following steps: firstly putting a silicon substrate into a vacuum chamber base after the surface of the silicon substrate is cleaned and a natural oxidation layer on the surface is removed, secondly putting a metal hafnium target with surface polished and cleaned into a target position in a vacuum chamber as a target, closing a target baffle, utilizing high vacuum multifunctional radio frequency sputtering coating equipment to vacuumize the vacuum chamber, carrying out backwash cleaning on the substrate, switching on a radio frequency power supply and adjusting the power of the radio frequency power supply after backwash cleaning, carrying out pre-sputtering, finally adjusting the argon flux, filling oxygen and opening the target baffle to formally sputter a hafnium dioxide film, thus forming the hafnium dioxide amorphous film. The preparation method has the beneficial effects that crystallization of the hafnium dioxide film can not be caused, and the preparation method is suitable for preparation of the hafnium dioxide amorphous film.
Owner:UNIV OF ELECTRONIC SCI & TECH OF CHINA

Low-dimensional nano photodetector based on in-plane asymmetric local field control and preparation method thereof

The invention discloses a low-dimensional nano photodetector based on in-plane asymmetric local field control and a preparation method thereof. The device structure sequentially includes a substrate,an oxide layer, a nano semiconductor, source and drain electrodes and a dielectric layer from bottom to top. The preparation steps of the device are as follows: transferring ultra-thin zinc oxide (ZnO) nanosheets grown by using a CVD method onto a silicon substrate with the oxide layer, preparing the source and drain electrodes by using electron beam exposure, thermal evaporation and other processes, and then preparing a hafnium dioxide (HfO2) dielectric layer by using electron beam exposure, atomic layer deposition and other processes, and finally preparing a low-dimensional nano photodetector. By introducing asymmetric HfO2, the partial adsorption of charged gas molecules on the nanosheets is formed to control the concentration of carriers on both sides of the zinc oxide nanosheets, andthus an in-plane asymmetric local field is formed, the response speed of the device can be finally increased, and the device can also show an ultra-high detection rate. The scheme of the invention hasthe advantages of simple preparation, fast response speed, low dark current, high detection rate and low power consumption.
Owner:SHANGHAI INST OF TECHNICAL PHYSICS - CHINESE ACAD OF SCI

Preparation method for atomic energy level hafnium dioxide

The invention belongs to the technical field of wet-process zirconium and hafnium metallurgy, and particularly relates to a preparation method for atomic energy level hafnium dioxide. According to themethod, P204 is adopted as an extraction agent to extract and enrich hafnium in raffinate, the concentration of the hafnium in the enriched hafnium solution can be improved by 20-30 times, the consumption of caustic soda for precipitation is obviously reduced, and a precipitation mother solution can return to prepare a stripping agent; hafnium-extracted raffinate water can return to a zirconium and hafnium separation system for recycling or for producing a sodium nitrate product; the color of the produced hafnium dioxide is white, and the total impurity content conforms to the atomic energy level hafnium dioxide quality standard; and compared with direct precipitation of the raffinate, the preparation method has the advantages that the waste water amount is reduced by 60% or above, the raffinate can be recycled, the consumption of the caustic soda is reduced by 85% or above, the production cost is low, the product quality of the hafnium dioxide is stable, and obvious social benefits and obvious economic benefits are achieved.
Owner:中核二七二铀业有限责任公司

Three-dimensional tapered nano-layer film structure, preparation method thereof and application thereof

PendingCN109943810AEnhanced infrared absorptionSolve the technical defect of low net radiative cooling powerMaterial nanotechnologyVacuum evaporation coatingCooling powerSilicon dioxide
The invention belongs to the field of novel energy technical development, in particular to a three-dimensional tapered nano-layer film structure, a preparation method thereof and application thereof.The three-dimensional tapered nano-layer film structure provided by the invention comprises silicon dioxide layer-hafnium dioxide composite layers and sliver layers, wherein silicon dioxide layers arearranged above hafnium dioxide layers; number of the silicon dioxide layer-hafnium dioxide composite layers is greater than 10; and the silicon dioxide layer-hafnium dioxide composite layers are arranged above the sliver layers. The invention further provides a preparation method for the three-dimensional tapered nano-layer film structure, and further provides application of the three-dimensionaltapered nano-layer film structure or a product prepared by the preparation method in a radiation cooling device. The three-dimensional tapered nano-layer film structure is introduced, so that high-performance dual-window atmospheric radiation can be realized, and high-efficiency passive radiation cooling ability can be finally realized. The technical defect that a daytime cooling method has low net radiation cooling power in the prior art is solved.
Owner:SHENZHEN UNIV

Method for preparing hafnium-oxide-based thin ferroelectric film by using all-inorganic precursor solution and application

The invention, which belongs to the technical field of material preparation, discloses a method for preparing a hafnium-oxide-based thin ferroelectric film by using an all-inorganic precursor solutionand application of the film. A hafnium-oxide-based precursor solution doped with different elements is prepared by using inorganic hafnium salt and an inorganic high-symmetry phase stabilizer as rawmaterials; a substrate is cleaned based on a standard RCA process to remove impurity contamination on the surface of the substrate and then the substrate is preprocessed to enhance wettability of thesurface of the substrate; a hafnium-oxide-based thin film is deposited on the surface of the substrate; and then pre-heat treatment and annealing crystallization are carried out on the thin film to realize stability of the high-symmetry quadrature phase, tetragonal phase, cubic phase or other mixed phase at a room temperature, so that the thin film having the initially intrinsic property may generate a ferroelectric property under the field induction. According to the method, the prices of the raw materials are low and thus the cost is lowered; the equipment and operation environment requirements are simple; the types of the doped elements are diversified and thus selection becomes flexible; the ferroelectric property is easy to control; and the industrialized production is realized easily.
Owner:DALIAN UNIV OF TECH

Preparation method of low leakage current HfO2 film suitable for gate dielectric layer

The invention relates to a semiconductor technology, and provides a preparation method of a low leakage current HfO2 film suitable for a gate dielectric layer, which solves the problem that preparation processes of existing HfO2 gate dielectric film materials are unfavourable for large-scale preparation of films. The preparation method comprises the following steps: firstly putting a silicon substrate into a vacuum chamber base after the surface of the silicon substrate is cleaned and a natural oxidation layer on the surface is removed, secondly putting a metal hafnium target with surface polished and cleaned into a target position in a vacuum chamber as a target, closing a target baffle, utilizing high vacuum multifunctional radio frequency sputtering coating equipment to vacuumize the vacuum chamber, carrying out backwash cleaning on the substrate, switching on a radio frequency power supply and adjusting the power of the radio frequency power supply after backwash cleaning, carrying out pre-sputtering, finally adjusting the argon flux, opening the target baffle, pre-depositing an ultra-thin hafnium film and filling oxygen to formally sputter a hafnium dioxide film, thus forming the hafnium dioxide film. The preparation method has the beneficial effects that the preparation method is convenient for large-scale preparation and is suitable for MOS (metal oxide semiconductor) capacitors.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Infrared waveband diaphragm composite membrane and preparation method as well as composite material

The invention discloses an infrared waveband diaphragm composite membrane and a preparation method as well as a composite material, belonging to the technical field of manufacturing of optical thin films. The infrared waveband diaphragm composite membrane has a double-layer membrane structure; the first layer is a hafnium oxide membrane layer and the second layer is a chromium membrane layer; the first layer and the second layer have strong bonding force with a calcium fluoride base; and the inner stress is small and the manufacturability of an infrared diaphragm prepared by a photographing copying method is good. According to the preparation method of the infrared waveband diaphragm layer, the hafnium oxide membrane layer and the chromium membrane layer are plated by adopting an evaporation manner and the chromium membrane layer is plated by two times so that the diaphragm prepared by adopting the photographing copying method has flat and smooth lines and have no light-transmitting point; and the preparation method has a simple technological process, is easy to operate and is suitable for industrial popularization and application. A base material of the infrared waveband diaphragm composite material is calcium fluoride, the inner layer membrane is the hafnium oxide membrane layer and the outer layer is the chromium membrane layer; and the bonding capability of the chromium membrane layer and calcium fluoride is strong and the process performance is good.
Owner:LUOYANG INST OF ELECTRO OPTICAL EQUIP OF AVIC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products