142 results about "Radical oxidation" patented technology

Methods for forming a tunnel oxide structure device and methods for forming the structure are described. A structure comprising nitrogen is formed on a semiconductor substrate. The structure is oxidized. Nitrogen of the oxide structure is redistributed to form a region of concentrated nitrogen. Oxidizing the structure and redistributing the nitrogen is performed via radical oxidation. Nitrogen is added to the oxide structure. The region of concentrated nitrogen helps to regulate the depth of the added nitrogen.

Reading margin is improved in a MTJ designed for MRAM applications by employing a pinned layer with an AP2 / Ru / AP1 configuration wherein the AP1 layer is a CoFeB / CoFe composite and by forming a MgO tunnel barrier adjacent to the CoFe AP1 layer by a sequence that involves depositing and oxidizing a first Mg layer with a radical oxidation (ROX) process, depositing and oxidizing a second Mg layer with a ROX method, and depositing a third Mg layer on the oxidized second Mg layer. The third Mg layer becomes oxidized during a subsequent anneal. MTJ performance may be further improved by selecting a composite free layer having a Fe / NiFeHf or CoFe / Fe / NiFeHf configuration where the NiFeHf layer adjoins a capping layer in a bottom spin valve configuration. As a result, read margin is optimized simultaneously with improved MR ratio, a reduction in bit line switching current, and a lower number of shorted bits.

The present invention provides a method for fabricating a semiconductor device having a dual gate dielectric structure capable of obtaining a simplified process and improving device reliability. The method includes the steps of: forming an insulation layer on a substrate; forming a nitride layer on the insulation layer; selectively etching the nitride layer in a predetermined region of the substrate; performing a radical oxidation process to form an oxide layer on the insulation layer and the etched nitride layer; forming a gate conductive layer on the oxide layer; and performing a selective etching process to the gate conductive layer, the oxide layer, the nitride layer and the insulation layer, so that the first dielectric structure formed in the predetermined region includes the insulation layer and the oxide layer and the second gate dielectric structure formed in regions other than the predetermined region includes the insulation layer, the nitride layer and the oxide layer.

A method for manufacturing a non-volatile memory device having a charge trap layer comprises in one embodiment: forming a first dielectric layer over a semiconductor substrate; forming a second dielectric layer having a higher dielectric constant than that of the first dielectric layer over the first dielectric layer; forming a nitride buffer layer for preventing an interfacial reaction over the second dielectric layer; forming a third dielectric layer by supplying a radical oxidation source onto the nitride buffer layer to oxidize the nitride buffer layer, thereby forming a tunneling layer comprising the first, second, and third dielectric layers; and forming a charge trap layer, a shielding layer, and a control gate electrode layer over the tunneling layer.

The present invention is directed to a cosmetic composition comprising effective amounts of fullerene clusters in association with cosmetically acceptable carrier to prevent or retard fee radical oxidation processes in the skin and to the methods of using said composition for reducing damage to healthy skin or mucous membranes by free radicals.

The invention relates to a blueberry leaves drink with health function based on the blueberry leaves as main material and its making method, wherein the blueberry leaves contents a great amount of flavonoid with more than 40 physiologically activities of reducing blood sugar and blood fat and resisting arrhythmia, the resisting free radical oxidation ability of the blueberry is not compared with the other anti-oxidizing agent, meanwhile there is great amount proanthocyanidins contented in the blueberry with very good health function to the nervous system for children especially for the pregnant woman conspicuously. The making method is characterized by the following: picking the blueberry leaves with more than 90 days growth; using the technique process of washing, immersing, quick freezing, disintegrating, chilling, extracting with vacuum low-temperature, freezing, filtering, allocating, flash sterilizing and germ-free canned. The invention guarantees not to damage the nutrition and effective and active substances in the material almost, which makes the product have certain health function.

A method of desulfurizing / refining a hydrocarbon oil by which sulfur compounds are diminished to an extremely low concentration at a relatively low equipment cost and operating cost. The method of desulfurizing / refining a hydrocarbon oil comprises bringing a hydrocarbon oil containing at least one sulfur compound selected from the group consisting of thiophene compounds, benzothiophene compounds, and dibenzothiophene compounds and optionally further containing aromatic hydrocarbons into contact with a solid acid catalyst and / or an activated carbon having a transition metal oxide supported thereon to thereby desulfurize the oil. The solid acid catalyst preferably is a solid ultrastrong-acid catalyst selected among sulfuric acid radical / zirconia, sulfuric acid radical / alumina, sulfuric acid radical / tin oxide, sulfuric acid radical / iron oxide, tungstic acid / zirconia, and tungstic acid / tin oxide.

Reading margin is improved in a MTJ designed for MRAM applications by employing a pinned layer with an AP2 / Ru / AP1 configuration wherein the AP1 layer is a CoFeB / CoFe composite and by forming a MgO tunnel barrier adjacent to the CoFe AP1 layer by a sequence that involves depositing and oxidizing a first Mg layer with a radical oxidation (ROX) process, depositing and oxidizing a second Mg layer with a ROX method, and depositing a third Mg layer on the oxidized second Mg layer. The third Mg layer becomes oxidized during a subsequent anneal. MTJ performance may be further improved by selecting a composite free layer having a Fe / NiFeHf or CoFe / Fe / NiFeHf configuration where the NiFeHf layer adjoins a capping layer in a bottom spin valve configuration. As a result, read margin is optimized simultaneously with improved MR ratio, a reduction in bit line switching current, and a lower number of shorted bits.

Provided herein is a placental membrane product comprising an immunocompatible amniotic membrane. Such placental membrane products can be cryopreserved and contain therapeutic factors and viable cells after thawing. The placental membrane products are useful in wound healing and tissue repair / regeneration as they are capable of promoting angiogenesis, reducing inflammation, inhibiting proteases and free radical oxidation, reducing scar formation, and other methods that promote healing. The present technology relates to products to protect injured or damaged tissue, or as a covering to prevent adhesions, to exclude bacteria, to inhibit bacterial activity, and / or to promote healing or growth of tissue. The field also relates to methods of manufacturing and methods of use of such membrane-derived products.

The present invention is generally directed towards a method for removing hydrocarbon contamination from a substrate prior to a nitridation step, therein providing for a generally uniform nitridation of the substrate. The method comprises placing the substrate in a process chamber and flowing an oxygen-source gas into the process chamber. A first plasma is formed in the process chamber for a first predetermined amount of time, wherein the hydrocarbons combine with one or more species of the oxygen-source gas in radical form to form product gases. The gases are removed from the process chamber and a nitrogen-source gas is flowed into the process chamber. A second plasma is then formed in the process chamber for a second predetermined amount of time, therein nitriding the substrate in a significantly uniform manner.

An apparatus for cleaning the specimen and interior specimen chamber of Transmission Electron Microscopes, and similar electron- or charged-particle-beam instruments consisting of a plasma cleaning device mounted on a hollow rod that replaces the stage through the air lock of the instrument by being the same shape and size as the stage support rod. The plasma cleaning device is a small hollow cathode that is excited by RF power. Air or other oxygen containing mixtures is admitted to the plasma through the hollow rod at a pressure below 1 Torr. The plasma creates oxygen radicals from the oxygen containing gas. The oxygen radicals oxidize the hydrocarbons contamination and convert them to easily pumped gases. The apparatus can be attached to the electron microscope whenever cleaning is needed, and then is easily removed to return the instrument to its analytical function.

A method of manufacturing a stacked film includes; subjecting a semiconductor substrate to a radical oxidation reaction to form a radical oxide layer on a surface of the semiconductor substrate, annealing the radical oxide layer in a hydrogen atmosphere to convert the radical oxide layer to a first passivation layer, and disposing a second passivation layer on the first passivation layer.

The present invention relates to a tea-polyphenol soft capsule including capsule core and capsule shell, its capsule core contains (wt%) 5-60% of tea-polyphenol, 0-20% of soya bean lecithin, 0-2% of vitamin E, 0-15% of stabilizing agent and the rest is diluting agent. Its capsule shell composition contains (wt%) 35-45% of gelatin, 0-3% of polyglycol 400, 18-22% of plasticizer, 0.08-0.11% of preservative, 0-1% of covering agent, 0-0.35% of coloring matter, 0-0.1% of corrective and the rest is water. Its preparation process includes preparation of capsule core, preparation of capsule shell and pressing capsule. The capsule has the several actions of reducing blood fat, resisting cancer, resisting free radical oxidation, resisting atheroscleorsis, promoting absorption of VitC and preventing and curing scorbutus.

The invention relates to a method for simultaneous desulfurization denitrification and mercury removal based on hydroxyl and sulphate radical oxidation. According to the method, ultraviolet radiation is adopted to decompose peroxide to produce hydroxyl and sulphate radical with strong oxidizing property, which serves as an oxidizing agent, and oxidation is performed in an impact bed, so as remove SO2, NOx and Hg0 in flue gas. The flue gas from an emission source is mixed with peroxide solution and then is sprayed into the impact bed at a high speed through coaxially and oppositely distributed nozzles, and two atomized gas-liquid mixtures are oppositely impacted and mixed in the impact bed. Ultraviolet radiation decomposes the peroxide in the solution to produce hydroxyl and sulphate radical to oxidize and remove the SO2, NOx and Hg0; divalent mercury produced during reaction enters a mercury separation tower, so as to be separated and recycled; sulfuric acid and nitric acid solution enter an absorption tower to produce ammonium sulfate and ammonium nitrate solution; the ammonium sulfate and ammonium nitrate solution finally enter an evaporation crystallization tower to produce solid ammonium sulfate and ammonium nitrate solution. A system can realizes complete removal of the SO2, NOx and Hg0, no secondary pollution exists during removal, and the method has a wide market application prospect.

Disclosed herein is a semiconductor device including: a semiconductor substrate; a gate insulating film formed on surfaces of the semiconductor substrate including an internal surface of a hole formed in the semiconductor substrate and formed by radical oxidation or plasma oxidation; and a gate electrode formed as buried in the hole. The gate insulating film and the gate electrode form a vertical MOS.

Compositions containing N-acetylcysteine ​​amide (NAC amide) and derivatives thereof, and their use in the treatment and therapy of diseases, conditions, disorders and conditions in humans and non-human mammals. Administration of pharmaceutically or physiologically acceptable compositions of NAC amide or derivatives thereof alone or in combination with other suitable drugs to reduce, prevent or antagonize oxidative stress and the formation and excess of free radical oxidants in cells and tissues Produce, and provide a new source of glutathione.

The present invention relates to an anti-free radical oxidation, liver-protective, senile dementia preventing and anti-aging active dehydrogenation silybin double-ester derivative and the related medicinal salt or solvent compound. The invention also relates to the preparation method for the compound on the formula 1, as well as the related medication compounds and the curatorial uses. The compound of the invention can protect the liver cells of a rat liver cell injury in vitro model, which can be expected to prevent liver damage in drug use; the compound of the invention is provided with the biological activities of in vitro removing superoxide anion free radicals and diphenyl-benzyl-hydrazine free radicals, and restraining generation of grease peroxide induced by free radicals. The compound can strongly confront the PC12 cells damage caused by free radicals, which can be expected to prevent various diseases caused by free radicals in drug use.

The invention relates to a regeneration method and a circulating restoration device for an organic contaminated soil restoration eluate. According to the invention, the theory is as follows: on the basis of free-radical oxidation of sulfate radicals, hydrophobic organic matters in the eluate are selectively and preferably degraded. The method and the device can be used for preferably degrading pollutants in the eluate during the organic contaminated soil eluting restoration process, so that the eluate can be regenerated and recycled, and the defects of a traditional leaching process can be well solved; the regeneration of the eluate in a hydrophobic organic contaminated soil eluting restoration technology is realized, repeated eluting can be carried out, the regenerative recycling of the eluate in the eluting process is realized, the total water consumption and surfactant consumption for soil eluting can be greatly reduced, the soil restoration cost is lowered, and secondary pollution cannot be caused.

Plasma assisted low temperature radical oxidation is described. The oxidation is selective to metals or metal oxides that may be present in addition to the silicon being oxidized. Selectivity is achieved by proper selection of process parameters, mainly the ratio of H2 to O2 gas. The process window may be enlarged by injecting H2O steam into the plasma, thereby enabling oxidation of silicon in the presence of TiN and W, at relatively low temperatures. Selective oxidation is improved by the use of an apparatus having remote plasma and flowing radicals onto the substrate, but blocking ions from reaching the substrate.

Plasma assisted low temperature radical oxidation is described. The oxidation is selective to metals or metal oxides that may be present in addition to the silicon being oxidized. Selectivity is achieved by proper selection of process parameters, mainly the ratio of H2 to O2 gas. The process window may be enlarged by injecting H2O steam into the plasma, thereby enabling oxidation of silicon in the presence of TiN and W, at relatively low temperatures. Selective oxidation is improved by the use of an apparatus having remote plasma and flowing radicals onto the substrate, but blocking ions from reaching the substrate.

The invention relates to a method for producing sulfate radical free radicals to oxidize pollutants through in-situ electrocatalysis. The method comprises the steps: sulfate in wastewater is activatedin situ by an anode material with high oxygen evolution potential to generate persulfate radicals, the generated persulfate radicals are catalyzed into sulfate radical free radicals at a cathode material with electrocatalytic activity, pollutants in the wastewater are oxidized by the sulfate radical free radicals and the sulfate radical free radicals are converted into sulfate at the same time, the sulfate are activated at the anode material again, and the processes are repeated. Compared with the prior art, the method has the advantages that sulfate ions in the water body are used for generating the sulfate radical free radicals in situ to oxidize and remove the pollutants, oxidants (such as peroxymonosulfate and peroxydisulfate) do not need to be added, and the salt concentration of thewater body cannot be increased; the water pollution control technology is high in removal efficiency and small in secondary pollution, and has the characteristic of easiness in automation.

A method by which generation of leak current can be suppressed and also a fine element can be formed by performing element isolation at a temperature at which a glass substrate can be used is provided. The method includes a first step of forming a base film over a glass substrate; a second step of forming a semiconductor film over the base film; a third step of forming, over the semiconductor film, a film preventing oxidation or nitridation of the semiconductor film into a predetermined pattern; and a fourth step of performing element isolation by radical oxidation or radical nitridation of a region of the semiconductor film, which is not covered with the predetermined pattern, at a temperature of the glass substrate lower than a strain point thereof by 100° C. or more, where radical oxidation or radical nitridation is performed over a semiconductor film placed apart from a plasma generation region, in a plasma treatment chamber with an electron temperature within the range of 0.5 to 1.5 eV, preferably less than or equal to 1.0 eV, and an electron density within the range of 1×1011cm−3 to 1×1013cm−3.

The invention discloses a chalcone derivative with good anti-free radical oxidative damage activity. The structural formula of the chalcone derivative is shown as the following. The preparation method of the chalcone derivative includes: letting syringaldehyde and para-substituted acetophenone react in piperidine and under a high temperature so as to generate corresponding substituted chalcone; reacting purified chalcone with sodium borohydride under a cerous chloride heptahydrate condition to generate a chalcone derivative crude product, and then conducting purification. , Compared with ascorbic acid, the product provided by the invention has low anti-DPPH free radical and anti-ABTS<+> free radical IC50 value, and strong free radical scavenging ability, thus having broad application prospects in preparing drugs for treating neurodegenerative diseases. (formula I).

Methods for forming a tunnel oxide structure device and methods for forming the structure are described. A structure comprising nitrogen is formed on a semiconductor substrate. The structure is oxidized. Nitrogen of the oxide structure is redistributed to form a region of concentrated nitrogen. Oxidizing the structure and redistributing the nitrogen is performed via radical oxidation. Nitrogen is added to the oxide structure. The region of concentrated nitrogen helps to regulate the depth of the added nitrogen.

The present invention discloses one industrial method of oxidizing four-valent sulfide with non-thermal plasma in the co-existence of OH, H, O, N and other high chemical activity free radicals. High voltage power source is applied to the discharge system of streamer discharge plasma reactor to form the streamer discharge plasma reaction area while sulfite solution is fed into the reaction area, and the four-valent sulfur is oxidized into six-valent sulfur during the streamer discharge oxidizing process. Meanwhile, atomizing mode, bubbling mode or high specific surface area electrode is used to increase the gas-liquid mass transfer interface and raise the mass transfer efficiency. Compared with conventional method, the present invention has high oxidization rate, low power consumption, short processing time, small covered area, less ammonia leakage and other advantages.

The invention provides an acanthopanan trifoliatus extract, and a preparation method and an application thereof. According to the invention, acanthopanan trifoliatus entire plant is weighed and is soaked by using ethanol; rotary evaporation concentration is carried out, and a water solution is obtained; the water solution is sequentially extracted by using petroleum ether, ethyl acetate, and n-butanol; and an obtained extraction liquid is subjected to reduced-pressure distillation, such that a paste is obtained, wherein the paste comprises petroleum ether extract, ethyl acetate extract, n-butanol extract, and water-soluble matter. Through a free radical oxidation resistance experiment, a macrophage growth experiment, a NF-kB nuclear transcription factor inhibition experiment, and an Erk1 / 2 activation effect experiment, it is verified that the acanthopanan trifoliatus extract has anti-oxidative and anti-inflammatory capacities. Inflammatory-treating medicines or anti-oxidative cosmetics or foodstuff compositions with added acanthopanan trifoliatus and extracts thereof are provided with anti-inflammatory and anti-oxidative effects. The acanthopanan trifoliatus extract can be used in inflammation-controlling or aging-controlling cosmetics, medicines, vegetable beverages and health-care foodstuffs.

The invention discloses a side chain type imidazolyl benzdine and a preparation method thereof. The preparation method comprises the following steps of: utilizing 3, 3'-dihydroxydiphenylamine as a raw material, carrying out three reaction steps of etherification grafting, acidification hydrolyzing and condensation cyclizing, and thus obtaining the side chain type imidazolyl benzdine. An imidazole group of a diamine monomer is grafted with a side chain which is far from a main chain, so that the performance of a polymer can be effectively improved, and particularly, the anti-radical oxidation stability and hydrolytic stability of sulfonated polyimide are improved. The side chain type imidazolyl benzdine can also be served as the raw material for synthesizing polymers such as polyimide, polyamide, polyurethane, polyether amine and the like, and has a wide application prospect on the aspects of high-performance fibers and fuel cells.

Embodiments described herein generally relate to flash memory devices and methods for manufacturing flash memory devices. In one embodiment, a method for selective removal of nitrogen from the nitrided areas of a substrate is provided. The method comprises positioning a substrate comprising a material layer disposed adjacent to an oxide containing layer in a processing chamber, exposing the substrate to a nitridation process to incorporate nitrogen onto the material layer and the exposed areas of the oxide containing layer, and exposing the nitrided material layer and the nitrided areas of the oxide containing layer to a gas mixture comprising a quantity of a hydrogen containing gas and a quantity of an oxygen containing gas to selectively remove nitrogen from the nitrided areas of the oxide containing layer relative to the nitrided material layer using a radical oxidation process.