61results about How to "Avoid carburization" patented technology

A stainless steel pipe includes a base metal containing 20-35 mass % of Cr, and a Cr-depleted zone is formed in the surface region of the pipe. The Cr concentration in the Cr-depleted zone is at least 10%, and the thickness of the Cr-depleted zone is at most 20 micrometers. A Cr-based oxide scale layer having a Cr content of at least 50% and a thickness of 0.1-15 micrometers may be provided on the outer side of the Cr-depleted zone. An Si-based oxide scale layer with an Si content of at least 50% may be provided between the Cr-based oxide scale layer and the Cr-depleted zone. The pipe is particularly suitable for use in petroleum refineries or petrochemical plants, such as for use as a pipe of a cracking furnace of an ethylene plant.

The invention discloses a magnesia-based dry material for a tundish with aluminum hydroxide, which belongs to a refractory material. The magnesia-based dry material for the tundish with the aluminum hydroxide comprises the following compositions in percentage by weight: 1 to 15 percent of aluminum hydroxide fine powder, 82 to 89 percent of magnesia, and 1.5 to 6.5 percent of bonding agent. During the baking and use, the aluminum hydroxide fine powder is decomposed to produce activated alumina and vapor, the vapor moistens the surfaces of particles inside the dry material to ensure that the surfaces of the magnesia and silica fume in the dry material are hydrated, and the bonding agent is partially dissolved and diffused to bond with the surface of the magnesia. The generated activated alumina has a spinel reaction with magnesia fine powder at a temperature higher than 900 DEG C to form a large quantity of fine magnesium aluminate spinels, which remarkably improves the penetration-resistant action of the dry material on molten steel and steel slag and plays a role in ceramic bonding. The dry material does not depend on carbon-containing bonding agents such as phenolic resin, asphalt, which avoids the carburization to molten steel of low carbon steel and also reduces the poisonous fume emission. The construction of the magnesia-based dry material adopts a dry-press process, and then the dry material is subjected to heat conduction through the heating on a metal mold to make the bonding agent fused or solidified to form a fixed tundish working lining for receiving the molten steel.

The invention discloses a coke oven ascension pipe raw gas evaporative cooling device and a preparation method thereof. The device comprises a cooling pipe, a raw gas inlet flange and a raw gas outlet flange, wherein the raw gas inlet flange and the raw gas outlet flange are connected with the two ends of the cooling pipe respectively. The cooling pipe is sequentially composed of an inner sleeve, an outer sleeve, a heat preservation layer and a protection layer from inside to outside. Through holes are formed in the two ends of the side wall of the outer sleeve respectively. A water inlet steel pipe is installed on the through hole close to the raw gas inlet flange. A vapor outlet steel pipe is installed on the through hole close to the raw gas outlet flange. An annular expansion joint section is arranged at the portion, between the water inlet steel pipe and the vapor outlet steel pipe, of the outer sleeve. The high temperature structural strength and high temperature breakage resistant capacity of the cooling device are remarkably improved, the heat transfer behavior of the pipe wall of the inner sleeve of the cooling device is improved, the radial temperature distribution of the pipe wall is optimized, the efficient function coordination of multiple layers of materials is achieved, and the comprehensive use performance of the inner sleeve is improved; the aim of long-term efficient and stable running of the ascension pipe raw gas evaporative cooling device is finally achieved.

The invention provides a lead-carbon super battery anode material which is a graphene/Pb nano composite material. The lead-carbon super battery anode material is prepared by mixing a lead salt solution with a graphite oxide solution, carrying out hydrothermal reaction, and then carrying out macro body freeze drying and burning. The lead-carbon super battery anode material is prepared from 91 to 99.5 percent of lead and 0.5 to 9 percent of graphene. The lead salt solution is prepared by dissolving soluble lead salt into deionized water; the soluble lead salt is one or several of lead-containing nitrate, acetate, carbonate, hydrochloride, sulfate and complex salt. The invention further provides a preparation method of the lead-carbon super battery anode material. The preparation method provided by the invention has the advantages of high efficiency, environmental friendliness, high uniformity and the like; the prepared lead-carbon super battery anode material is high in uniformity, high in stability and wide in application prospect.

The invention discloses a cooling plate (10) for a metallurgical furnace, which comprises a cast iron cooling plate body (12) made of ferrous metal and at least one steel cooling pipe ( 20). The thickness of the metal sleeve (26) on the outer surface of the steel cooling pipe (20) in the cooling plate body (12) is in the range of millimeters, and the metal sleeve (26) is made of copper, copper alloy, nickel and nickel alloy. Made of metal of choice.

The invention relates to a vacuum carburizing heat treatment process of 12CrNi3A materials and belongs to the technical field of carburizing. The vacuum carburizing heat treatment process of 12CrNi3Amaterials is a chemical heat treatment method of the machine building industry. Through the process tests of vacuum carburizing and subsequent heat treatment, and through quality evaluation and performance analysis of a carburizing sample as well as the diffusion layer tissue and the core tissue of a part, technological parameters of vacuum carburizing of the 12CrNi3A materials and a post-carburizing heat treatment process are optimized. The vacuum carburizing technology is a more advanced technology at present. The vacuum carburizing technology mainly has specialities that high temperature short time carburizing can be conducted; grain boundary oxidation is not existed; surface incomplete quenching layer is not produced; carburizing layer controlling is simple; and complex shape carburizing such as slim hole and blind hole can be conducted.

The invention discloses a heat treatment method for high-strength fasteners made of SCM435 steel for automobiles, comprising steps: (1) In the heating stage, the fasteners are sent into a heating furnace, the heating temperature is controlled at 870°C ± 5°C, and methanol is passed through , the feed rate is 20-40ml/min, feed propane, control the carbon potential to be 0.40%±0.04%, and the heating time is 50-80 minutes; (2) quenching stage, the heated fastener enters the oil tank for quenching, When quenching and cooling, the oil temperature is 60-70°C, and the quenching oil is stirred in circulation; (3) Tempering stage, after quenching, the fastener enters the tempering furnace, and the tempering time is 130-170min; when the hardness requirement is 33-38HRC, tempering The temperature is 500-530°C; when the hardness requirement is 38-42HRC, the tempering temperature is 430-460°C. Passing methanol and controlling the carbon potential at 0.40±0.04% can better balance the carbon concentration inside and on the surface of the workpiece to avoid carburization and ensure that no cracks appear on the surface of the workpiece.

The invention relates to a driven gear heat treatment method. According to the scheme of the driven gear heat treatment method, a copper plating layer on the surface of the area where carburization is needed is removed through machining after copper plating treatment is carried out on the whole surface of a driven gear workpiece, then, carburization treatment is carried out, and the purpose that carburization is carried out only in the local area can be achieved; before quenching treatment is carried out, the cavity area, likely to be damaged, of the copper plating layer is coated with an anti-carburization coating, dual-layer protection is carried out on the cavity area, coal oil is added during quenching for atmosphere protection, decarburization on a carburization face can be effectively prevented, carburization can be effectively avoided due to the protection of the anti-carburization coating on the cavity area, and follow-up machining is convenient; and a pressure quenching machine tool is used for oil cooling after quenching, and shrinkage distortion is effectively reduced. By means of the method, the technical effects that carburization is carried out on the designated area of the driven gear, a carburization layer is free of decarburization after carburization is completed and carburization is avoided for the cavity area can be effectively achieved, volume production is easy, and the cost is low.

The invention belongs to the technical field of preparation of microwave ceramics, in particular relates to a pressure control adjustable barium strontium titanate-base compound ceramic material and a preparation method thereof. The compound ceramic material is prepared as follows: Ba(1-x)SrxTiO3 is compounded with Mg(1-y)ZnyO with low dielectric constant and low dielectric loss; little Ta2O5 is added to modify the compound ceramics of (1-m)Ba(1-x)SrxTiO3-mMg(1-y)ZnyO so as to meet the performance requirements of pressure control adjustable microwave ceramics with proper dielectric constant, low microwave dielectric loss, high pressure control adjustability and so on. The barium strontium titanate-base compound ceramic material prepared by adopting the solid reaction process or the coprecipitation coating process is cold isostatic compacted without adding any forming agent and is sintered under atmospheric pressure, thus obtaining high density and high purity ceramic blocks. The pressure control adjustable barium strontium titanate-base compound ceramic material is applicable for such microwave devices as phased array phasers, adjustable filters, delay lines, oscillators, resonators and so on.

The present invention relates to a coking depressor for an ethylene cracking furnace, and a method for using the same. The depressor consists of a thiol compound, a quinoline compound, a disalicylic acid compound and an organic solvent. The coking depressor not only overcomes the shortcomings in the prior depressor that the manufacturing cost is high, the injection operation is difficult, the distribution in the cracking furnace tube is uneven, and the depressor erodes the inner wall of the furnace tube, etc., but also effectively prolongs the service life of the cracking furnace and improves the yield of ethylene, the usage of the material and the load of an ethylene device. The producing amount of CO and CO2 is largely reduced, and thus the depressor is safe and environment-friendly.

The invention relates to a method for preparing transparent calcium fluoride ceramics. The method comprises the following steps: 1) loading powder materials, namely coating the inner wall of a graphite jig by using a metal foil, filling calcium fluoride powder into the graphite jig, and coating the outer wall of the jig by using a carbon felt so as to insulate heat; 2) sintering transparent ceramics, namely putting the graphite jig into a discharge plasma sintering furnace for sintering; and 3) performing sample treatment, namely taking out the sintered sample, coarsely grinding and polishing, thereby obtaining the transparent calcium fluoride ceramics. Compared with the prior art, the method disclosed by the invention has the advantages that with the adoption of the method disclosed by the invention, carbon pollution can be eliminated, light transmittance of the transparent calcium fluoride ceramics is improved, the maximum transmittance in an ultraviolet-visible band can be greater than 87%, and the problem in the traditional discharge plasma sintering technology that a carbon pollution sample is caused by carburization of the graphite jig at a high temperature is solved.

Carburization and metal-dusting while hydrodealkylating a hydrodealkylatable hydrocarbon are reduced even in the substantial absence of added sulfur.

The invention discloses an electromagnetic heating carbon-bearing pellet continuous direct steelmaking device and belongs to the technical field of ferrous metallurgy. The electromagnetic heating carbon-bearing pellet continuous direct steelmaking device comprises a steelmaking furnace body, a material distributing port and a coal gas outlet are formed in the top of the steelmaking furnace body, a double-circular-truncated-cone structure is composed of a material distributing area, a reduction area and a soft melting area of the steelmaking furnace body, and an iron slag melting separation area is of a cylindrical structure. At least two rows of microwave heating devices are arranged on the parts, in the material distributing area and the reduction area, of the periphery of the furnace body, and electromagnetic induction heating devices are arranged on the parts, in the soft melting area and the iron slag smelting separation area, of the periphery of the furnace body. By means of the electromagnetic heating carbon-bearing pellet continuous direct steelmaking device, an iron smelting and manufacturing device and a steelmaking device can be integrated, qualified high-quality molten steel can be produced directly through carbon-bearing pellets without blowing, the problem that secondary decarburization is needed in traditional furnace slag foaming and molten iron carburization is solved, the production efficiency is high, continuous steelmaking is achieved, and the capital construction cost and equipment investment are greatly saved.

The invention provides protective paint for heat treatment of metal, which is characterized by being prepared from the following raw materials in parts by weight: 2-5 parts of W type ethyl cellulose resin, 5-10 parts of organobentonite paste having an organobentonite content of 20%, 10-15 parts of 11# frit, 10-12 parts of 04# frit, 5-13 parts of M-1 frit, 5-8 parts of industrial grade barium metaborate, 1-6 parts of 400-mesh mica powder, 5-8 parts of industrial grade rubellan iron oxide, 3-11 parts of industrial grade pigment and 20-50 parts of ethanol. In an environment of 900 DEG C, the paint can achieve favorable drying property and excellent physical and chemical properties through secondary film forming of the combined frit; and meanwhile, a coating formed by the paint also has favorable self-releasing property.

The invention belongs to the field of steel pipe processing and manufacturing and particularly relates to a method for removing oil of an inner surface of a small-caliber cold-rolling pipe. A water-soluble cleaning agent and ultrasonic vibration are adopted, an inner wall is subjected to sand blasting washing, and oil stains of the inner surface of the small-caliber cold-rolling pipe are removed. The method comprises the steps of filling a material and immersing the pipe, conducting ultrasonic vibration, washing the inner wall by using a solution, washing the pipe by using hot water for the first time, subjecting the inner wall to sand blasting washing, cleaning the inner wall by using clean water, washing by using hot water for the second time, and checking. According to the method, the oil stains of the inner wall of the small-caliber cold-rolling pipe which is immersed in the water-soluble cleaning agent are subjected to vibration stripping through ultrasonic waves, the inner wall is washed by the solution which flows circularly, the oil stains of the inner wall are removed, the hot water and clean water are used for washing the inner wall respectively, and finally the inner wall is subjected to ceramic sand blasting, cleared completely and cleaned by using hot water. According to the method, the oil stains which are attached to the inner surface of the small-caliber cold-rolling pipe can be cleared completely, the problem that carburization of the inner wall of the steel pipe is caused during subsequent heat treatment due to the fact that the oil stains are carbonized is solved, and the method is pollution-free for the environment and causes no damage to a processed material.

The invention discloses a hard alloy sintered anti-sticking coating adopting alcohol-soluble boron modified phenolic resin as well as a preparation method and application of the hard alloy sintered anti-sticking coating; the anti-sticking coating is formed by mixing solid isolation powder and a liquid adhesive; the solid isolation powder comprises the components in parts by weight: 18-53 parts ofzirconium oxide, 1-6 parts of cerium oxide, 1-5 parts of silicon oxide, 10-30 parts of crystalline flake graphite and 5-45 parts of fine carbon black; and the liquid adhesive comprises the componentsin parts by weight: 3-10 parts of alcohol-soluble boron modified phenolic resin, 1-5 parts of a thickening agent, 2-5 parts of a dispersing agent, 3-5 parts of an active agent, 2-5 parts of a curing agent, 0.1-1.5 parts of a defoaming agent and 250-300 parts of a diluent. The anti-sticking coating has enough bonding strength and hardness after being brushed, and a coating layer is not prone to falling off and chipping in the hard alloy product placing, transporting and charging processes; after sintering, the coating layer can still keep high hardness and bonding strength, and the influence ofwater on the stability of an alloy product during sintering is avoided.

The invention relates to a method for producing foamed slag on high-chromium steel melts in an electric furnace, whereby a mixture consisting of a metal oxide and carbon is introduced into the furnace, the metal oxide in the slag is reduced by the carbon, and the gases created in the slag form bubbles which thus foam up the slag. In order to be able to control the gas formation and thus the foaming process, the mixture consisting of a metal oxide and carbon and optionally an iron carrier is introduced as preforms, such as pellets, which are compressed and/or provided with a binding agent. The gas formation can be controlled in terms of location, type and time, by adjusting the characteristics of the pellets, especially the density and/or compression characteristics thereof.

The invention relates to a stainless steel tube and its making technology, and concretely relates to a precise stainless steel tube for a nuclear power unit, and its making technology. The precise stainless steel tube comprises the following components, by mass, 0.04-0.05% of C, 0.15-0.3% of Si, 0.8-1% of Mn, 13-15% of Ni, 15-17% of Cr, 0.2-0.4% of Nb, 2.5-3.5% of Cu, 0.15-0.2% of N, 0.15-0.25% of Mo, 0.2-0.3% of Al, 6-8% of lanthanide rare earth, and the balance Fe. The limitation of the components and technological parameters, the addition of proper amounts of lanthanide rare earth elements, and the pure hydrogen protection gas bright-heat treatment operation make the stainless steel tube have a good corrosion resistance, and simultaneously the internal surface roughness, the external surface roughness, the yield strength, the tensile strength and the like of the precise stainless steel tube for a nuclear power unit are high.

The invention relates to the field of cast steel, and particularly discloses casting powder for a continuous casting crystallizer and a preparation method of the casting powder. The casting powder of the continuous casting crystallizer comprises the following components of, in parts by weight, 24.00-31.00 parts of SiO2, 26.00-33.00 parts of CaO, 5.40-5.70 parts of Al2O3, less than or equal to 3.00 parts of Fe2O3, less than or equal to 3.00 parts of MgO, 6.50-10.50 parts of Na2O and Li2O, 3.50-7.50 parts of CaF2, 4.5-5.5 parts of ZrO2 and 3.5-4.5 parts of Y2O3. The preparation method comprises the following steps of uniformly mixing the components, and grinding to obtain the finished product casting powder slag which has the advantage of good heat insulation effect.