The invention discloses a method for separating a 
methanol-containing 
organic solvent binary 
azeotrope. The method comprises the following steps: S1, rectifying a 
methanol-containing 
organic solvent solution by using a first rectification 
tower, and repeatedly heating and rectifying the solution to remove impurities and concentrate in order to obtain an 
methanol-containing azeotropic 
organic solvent A1; S2, heating the methanol-containing azeotropic organic 
solvent A1, performing repeated cycle purification by using 
pervaporation modules 3, heating the purified organic 
solvent A1 to a certaintemperature, separating a methanol 
vapor liquid A2 containing an extremely small amount of other organic solvents through a penetration side port under a vacuum condition under the action of 
pervaporation membranes, and cooling the methanol 
vapor liquid A2 by using a condenser to obtain a methanol solution A3 containing the extremely small amount of other organic solvents; and S3, rectifying the methanol solution A3 by using a second rectification 
tower to respectively obtain methanol and an 
azeotrope containing an extremely small amount of methanol. The method has the advantages of effectiveness in separation and 
recovery of the methanol-containing organic 
solvent binary 
azeotrope by using the modules and the rectification towers, low 
energy consumption, simplicity in operation of the whole 
system, simple process, solving of the difficulty in the separation of the methanol-containing azeotrope in the 
chemical industry, and saving of 30-60% of energy.