The invention relates to a
waste recycling method, and particularly relates to a method for extracting and separating metallic
oxide from a
flue gas denitration catalyst. The method comprises the following steps: sequentially performing physical pretreatment, pulverization and high-temperature
roasting on the
flue gas denitration catalyst, then performing leaching by use of
dilute acid, and further performing acidolysis treatment by use of concentrated
sulfuric acid; aging reactants obtained after acidolysis treatment, performing
filtration, then performing boiling hydrolytic treatment on a filtrate so that
titanium dioxide is subjected to hydrolytic
precipitation, and performing
solid-phase separation on liquid obtained by leaching, regulating the pH of the obtained filtrate to 2.0-2.5 by use of aqueous
ammonia, then performing organic extraction, and further performing back extraction by use of dilute sulphuric acid; oxidizing
vanadium in strip liquor from quadrivalence to quinquevalence by use of
sodium chlorate; then adding aqueous
ammonia to regulate the pH to 1.9-2.2, and performing
precipitation separation on
vanadium in an
ammonium metavanadate form; and performing
pyrolysis on a precipitate, thereby obtaining vanadic
oxide. The method provided by the invention has the advantages of simple process, high
recovery efficiency, good product technical index and the like.