The invention discloses a nano ZSM-5
molecular sieve based catalyst and preparation and use methods. The
molecular sieve catalyst consists of molecular sieves and
metal components, wherein the molecular sieves are nano ZSM-5 molecular sieves with a short b-axis, a medium
high silica-
alumina ratio, less strong acid, high Lewis
acid content, and resistance to hydrothermal deactivation. The preparation method is as follows: mixing a
silicon source, an aluminum source, a template agent, a structure
promoter, an additive and alkali with water, and stirring to prepare a precursor solution, then crystallizing, separating
solid from liquid, and calcinating to obtain
molecular sieve raw
powder; mixing the molecular
sieve raw
powder with an
ammonium salt solution, stirring, filtering, mixing with the
ammonium salt solution for several times, stirring, filtering, and calcinating to obtain
hydrogen-type ZSM-5 molecular sieves; mixing with the
metal precursor solution,
drying and calcinating to obtain the
aromatization catalyst. The use method is as follows: transforming oxy-compound raw materials to
aromatic hydrocarbon through the catalyst under the
reaction conditions. The nano ZSM-5 molecular
sieve based catalyst has the characteristics of being high in aromatics yield (reaching up to 99%) and long in service life (the catalyst is alive after 300 hours, and the aromatics selectivity reaches up to 70% after the catalyst is subjected to hydrothermal aging at 760 DEG C for 4 hours).