The invention discloses a hollow product with a microporous wall, a large number of micropores are formed in the wall part and the bottom of the hollow product, the micropores are uniform in size, and the
diameter of the micropores is within 150 microns; and the inner and outer wall surfaces of the wall part and the bottom part are of
solid structures. The invention also discloses a preparation method of the hollow product with the microporous wall, which comprises the following steps: (1) preparing a foaming master batch: uniformly mixing the pretreated
foaming agent, nano nucleating agent, dispersing agent, activity
regulator and matrix resin, and preparing the foaming master batch through a plastic extruder; (2) melting, extruding and
pelletizing the dried plastic
raw material through a plastic extruder to form a main material of a to-be-molded hollow product; (3) adding the foaming master batch in the step (1) into the main material in the step (2), and uniformly mixing to form a mixed material; (4) the mixed material is subjected to a heating
gas release experiment, a
gas release time curve of the mixed material at the corresponding temperature T is determined, and characteristic values of the curve comprise peak time tP, starting time tS and ending time tE; (5) based on the
gas release time curve obtained in the step (4), the mixed material is added into a three-in-one injection-
blow molding machine provided with a
bottle blank mold and a
bottle blowing mold, in the injection-blow process, the highest temperature of a charging
barrel of the injection-
blow molding machine is set to be T, and the time interval between the time when the mixed material enters the charging
barrel of the
machine from a hopper and the time when the melt starts to be blown is between tS and tP; a hollow product with a microporous wall is obtained.