The invention discloses a preparation method of Ni-B / B4C nano composite plating through pulse electrodeposition. The preparation method comprises the steps that S1, a steel sheet base body is pretreated; S2, an
electroplating solution is prepared, wherein the
electroplating solution comprises the following components according to the concentration: 240 g / L of
nickel sulfate, 45 g / L of
nickel chloride, 30 g / L of
boric acid, 0.5 g / L of
saccharin, 3 g / L of
dimethylamine borane, 0.1 g / L of a surfactant and 1-5 g / L of B4C nano particles; S3, an electrodeposition process is conducted, specifically, the pretreated base body is put into the prepared
electroplating solution to be subjected to electrodeposition; the technological parameters in the
pulse electroplating process are as follows: the
pulse frequency is 1000 Hz, the duty ratio is 40%, the time is 30 min, and the magnetic stirring rate is 400 rmp; and S4, after electrodeposition is finished, the surface of a plated part is subjected to ultrasonic cleaning through ethyl
alcohol and pure water in sequence. The Ni-B / B4C nano composite plating prepared by the method has excellent
corrosion resistance, higher microhardness and lower
friction coefficient, and the comprehensive performance of the Ni-B / B4C nano-composite plating is remarkably improved.