The invention discloses a Schiff base modified graphene oxide cement-based permeable crystallization type waterproof material which comprises a composite concrete admixture, an active anionic catalyst, cement, fine aggregate, a rubber powder, a coupling agent, Fe2O3, CaO and MgO, wherein the active anionic catalyst is Schiff base modified graphene oxide; the composite concrete admixture comprisesa water reducing agent and a retarder; the water reducing agent refers to one or several in NC, ESJ, lignosulfonate, methyl naphthalene sulfonate condensate and polyalkyl aryl sulfonate condensate; the retarder refers to one or several of potassium sodium tartrate, fluosilicate, ferrous sulfate, phosphoric acid, sodium sulfite, lactic acid, calcium tartrate gluconate, sodium lignosulfonate, calcium lignosulphonate and magnesium lignosulfonate; the cement is high-alumina cement or Portland cement; the fine aggregate is quartz sand, silica powdr or natural river sand; the coupling agent is a silane coupling agent. The waterproof material disclosed by the invention has excellent properties such as good effect, simple construction, low environmental requirement, excellent waterproof property,excellent durability and the like.