69 results about "Chromium-Nickel Alloys" patented technology

The invention relates to a titanium contained high chromel alloy and application thereof in spraying materials. The components of the alloy are (by weight percentage) as follows: the content of chromium is more than or equal to 15 percent and less than or equal to 25 percent, the content of titanium is more than or equal to 1 percent and less than or equal to 6 percent, the content of silicon is more than or equal to 1 percent and less than or equal to 6 percent, the content of carbon is more than or equal to 0 percent and less than or equal to 0.02 percent, the content of nickel is more than or equal to 20 percent and less than or equal to 55 percent, the content of rhenium is more than or equal to 0.5 percent and less than or equal to 6 percent, the content of aluminum is more than or equal to 0 percent and less than or equal to 6 percent, the content of sulfur is more than or equal to 0 percent and less than or equal to 0.035 percent, he content of phosphorus is more than or equal to 0 percent and less than or equal to 0.035 percent, the content of manganese is more than or equal to 0 percent and less than or equal to 0.2 percent, and the rest is iron. After the parts of working equipment are sprayed at high temperature oxidation and high temperature corrosion environments by the spraying material produced by the alloy, since the coating has good high temperature oxidation and vulcanization resistance and hot corrosion resistance performances, the service life of the parts can be greatly improved.

A trivalent chromium-based electroplating solution in accordance with the present invention a trivalent chromium salt, a bivalent nickel salt, a complex agent, a conductive salt, a buffering agent and an additive for electroplating a chromium-nickel alloy deposit on a component. By using the lowly toxic trivalent chromium to substitute highly toxic hexavalent chromium, an electroplating procedure with the present trivalent chromium-based electroplating solution has less pollution and high current efficiency to allow the electroplating performing at the room temperature.

The invention discloses a fluid-bed furnace center barrel alloy using the chromium-nickel alloy as the essential element. The alloy comprises the following components by weight percentage: C of 0.25-.60, Cr of 26.00-30.00, Ni of 9.00-12.00, Si of 0.80-1.50, Mn of 1.00-2.00, N of 0.15-0.30, Mo of 0.20-0.50, W of 0.50-1.00, Ti of 0.20-0.60, Nb of 0.20-0.60, V of 0.20-0.50, Re of 0.20-0.50, S<=0.04, P<=0.05, and Fe of the rest.The manufacturing process of the fluid-bed furnace center barrel comprises steps of moulding preparation, smelting and pouring and thermal treatment. The invention solves a technical problem that the existing fluid-bed furnace center barrel is non-wear-resistant and strain cracking under a high temperature, and the invention has three main advantages of high stretching and rigidity specific elongation index at normal temperature, strong oxidation resistance and antiwear quality at high temperature and service life longer than that of the existing products.

The electric furnace smelting process for recovering Cr and Ni from stainless steel dust includes the following steps: 1. preparing mixed material through adding water in 4-6 wt% and adhesive in 3-5 wt% into stainless steel dust; 2. pelletizing the mixed material; 3.adding the pellet into steelmaking material in the added amount of 2.0-15.0 wt%; 4. smelting Ni-containing stainless steel in an electric furnace; and 5. tapping to obtain stainless steel. The electric furnace smelting process for recovering Cr and Ni from stainless steel dust is simple and low in cost.

The invention discloses a high-temperature wear-resistant kilneye protection iron alloy using the chromium-nickel alloy as the essential element. The kilneye protection iron alloy comprises the following components by weight percentage: C of 0.25-0.60, Cr of 26.00-30.00, Ni of 9.00- 12.00, Si of 0.80-1.50, Mn of 1.00-2.00, N of 0.15-0.30, Mo of 0.20-0.50, W of 0.50-1.00, Ti of 0.20-0.60, Nb of 0.20-0.60, V of 0.20-0.50, Re of 0.20-0.50, S<=0.04, P<=0.05, and Fe of the rest.The manufacturing process of the high-temperature wear-resistant kilneye protection iron alloy comprises steps of moulding preparation, smelting and pouring and thermal treatment. The invention solves the problem that the existing kilneye protection iron is un-wearable under a high temperature and the produced high-temperature wear-resistant kilneye protection iron alloy has three main advantages of high stretching and rigidity specific elongation index at normal temperature, strong oxidation resistance and antiwear quality at high temperature and service life longer than that of the existing products.

A process for pulse electro-deposition nanometer Cr-Ni alloy plating of carboxylic acid or the salt-urea system of carboxylic acid is provided, which relates to the technology for surface engineering and surface treatment, comprises the pretreating and pulse electro-deposition treatment of the plating. The current efficiency of the plating solution system in the invention is up to 45.28%, about 35% higher than the 10% current efficiency in conventional trivalent Cr plating solution system; the toxicity of Cr3+ in the plating solution is only 1% of Cr6+, and the Cr content in the plating solution is only 1/7 of that in the plating solution of chromic acid. The invention is characterized by low toxicity and energy consumption, and greatly reduces the production cost of Cr-Ni plating and the environmental pollution during the production. The nanometer Cr-Ni plating prepared by the present invention is bright, intense, flat, and strongly bonded with the substrate, and is of excellent resistance to wear and corrosion in air. The invention is applicable for corrosion protection and decoration of metallic or metal alloy surfaces.

The invention discloses a method for recycling stainless steel pickling wastewater. The method comprises the following steps: 1) adding a neutralizing agent A to the stainless steel pickling wastewater to adjust a pH value to 3.0-8.0, then adding a neutralizing agent B to adjust the pH value to 9.0-12.0, respectively precipitating Fe, Cr, Ni and F in the wastewater in the forms of Fe(OH)3, Cr(OH)3, Ni(OH)2 and CaF2, and performing solid-liquid separation to obtain a solid phase sludge and a liquid phase; 2) drying the solid phase sludge obtained in the step 1) and adding a reducing agent for carbothermal reduction, and roasting the material in reducing atmosphere at 1150 DEG C to 1300 DEG C to obtain a calcined product; 3) performing fragmentation on the calcined product obtained in step 2) and performing ore dressing separation to obtain iron-chromium-nickel alloy powder and fluorine-containing tailings, and realizing separation of metal elements and fluorine elements; 4) performing flotation on the fluorine-containing tailings obtained in the step 3) to obtain a fluorite concentrate; and 5) performing NO3<-> removal on the liquid phase obtained in the step 1), and adjusting the material to neutrality, discharging while reaching the standard. The method can effectively treat the stainless steel pickling wastewater, and the discharge does not pollute the environment.

The invention discloses a cobalt-chromium-nickel alloy material and a powder metallurgy preparation method thereof. The cobalt-chromium-nickel alloy material is prepared from Co-Cr-Ni-M-C original powder, wherein M is selected from one or more of Mo, W, Fe, Si and Mn. In the preparation process of the cobalt-chromium-nickel alloy material, negative-pressure dewaxing is carried out in advance, andsinter molding is carried out in a low-vacuum sintering manner within a sintering temperature range. The scheme that single-phase epsilon-hcp Co alloy and double-phase alpha-fcc and epsilon-hcp Co alloy are obtained through the powder metallurgy method by adjusting the content of the original material component Ni is given.

The invention provides a cardiovascular stent with an Ag-TiO2 coating on the surface. An Ag coating covers a base layer of the cardiovascular stent; the base layer of the cardiovascular stent refers to a magnesium-titanium alloy, a magnesium-titanium-aluminum alloy, a magnesium-titanium-chromium alloy, a magnesium-titanium-chromium-nickel alloy or a magnesium-titanium-cobalt-chromium alloy; the Ag-TiO2 coating comprises an oxide film layer; and the oxide film layer contains nano-silver and/or silver oxide particles. According to the Ag-TiO2 coating, the cardiovascular stent has high biocompatibility, antibacterial property and extremely high application value, and the service life of the cardiovascular stent in a human body is prolonged.

The invention discloses a method for recycling acid regeneration iron powder pressed balls, and belongs to comprehensive utilization of the steel making field. The method is characterized by comprising the following steps of: mixing 50 to 70 mass parts of acid regeneration iron powder and 50 to 30 mass parts of dust removing ash uniformly, adding 3 to 8 mass parts of MgCl2 solution, mixing uniformly, performing extrusion forming on a roll ball press, and adding the formed iron balls into an electric furnace for smelting. By the method, the metal yield is improved, the acid regeneration iron powder is utilized, the dust removing ash is also utilized, and meanwhile, the consumption of chromium-nickel alloy in the steel making process is reduced, so that the production cost of stainless steel is reduced.

The invention discloses a chromium-nickel alloy electroplating solution and an electroplating method. The chromium-nickel alloy electroplating solution includes: 90-120g/L chromium chloride hexahydrate, 25-50g/L nickel sulfate hexahydrate, 50-70g/L ammonium bromide, 130-140g/L citric acid, 55-70g/L formic acid, 0.3-0.5g/L an emulsifier and the balance a solvent. The solvent is a mixed solution of DMF and water in a volume ratio of (0.8-1.05):1. The chromium-nickel alloy electroplating solution provided by the invention adopts the mixed solution of DMF and water as the solvent of the electroplating solution, citric acid and formic acid are taken as the compound complexing agent, citric acid and formic acid are selected as the buffering agent to replace boric acid, thus simplifying the formula, enhancing the hardness and corrosion resistance of the coating, and improving the dispersion ability and deep plating ability of the electroplating solution.

The invention relates to the method for manufacturing the soft circuit based plate. The base plate comprises the macromolecular thin film layer and the metal, the nickel alloy and the copper bond coat is sequence. The manufacturing method is as following steps. (1) The macromolecule thin film is as the basis material and the metal is as the sputter target material. The metal bond cost is sputtered on the surface of one side of the macromolecule thin film. (2) The nickel alloy is as the sputter target material. The nickel alloy bond cost is sputtered on the surface of the metal bond cost. (3) The copper bond coat is sputtered on the surface of the nickel alloy bond coat by using copper as the sputter target material. Chromium-nickel alloy layer with coefficient of expansion between the coefficients of chrome sputter layer.

The invention discloses a method for manufacturing a pyroelectric infrared detector sensing unit, comprising the steps of: preparing a lithium tantalate wafer substrate; Forming a chromium metal filmon the first surface of the lithium tantalate wafer substrate; Forming a nickel metal film on the chromium metal film; Forming a first chromium-nickel alloy layer on the nickel metal film and etchingto form an upper electrode; A second chromium-nickel alloy layer is formed on the second surface of the lithium tantalate wafer substrate and etched to form a lower electrode. The absorption layer ofthe pyroelectric infrared detector sensing unit manufactured according to the method of the embodiment of the present invention has the advantages of firm adhesion, good repeatability, wide absorptionband, flat spectrum, high absorption rate, small specific heat capacity and excellent heat transfer performance. At the same time, the absorbing layer can also be used as the electrode, which is suitable for the pyroelectric infrared detector.

The invention belongs to the technical field of grinding machining, and particularly relates to a ceramic microcrystalline grinding wheel for grinding cobalt-chromium-nickel alloy sealing block and amanufacturing method of the ceramic microcrystalline grinding wheel. The ceramic microcrystalline grinding wheel comprises a first ceramic microcrystalline abrasive, a second ceramic microcrystallineabrasive, a low-temperature ceramic binding agent, an additive, a pore-forming agent, a temporary binder and a wetting agent. The coarse-grain-sized first ceramic microcrystalline abrasive is taken asthe main abrasive; the fine-grain-sized second ceramic microcrystalline abrasive is taken as the auxiliary abrasive; the low-temperature ceramic binding agent which is prepared from the raw materialsof SiO2, B2O3, Al2O3, K2O, Na2O, MgO, and TiO2 in a certain ratio and through high-temperature smelting is selected to be matched with the additive (MnO2) in a certain ratio; and the shortage of workpiece burning and the grinding wheel surface retentivity conflict when an existing ceramic microcrystalline grinding wheel grinds and machines a cobalt-chromium-nickel alloy is overcome.

The invention relates to a Ni-Cr alloy temperature sensor based on magnetostrictive torsional waves. The sensor comprises a cylindrical shell, a measuring rod, a Fe-Ga wire, a chromium-nickel alloy wire, a pulse signal generation module, a control sampling module, a ceramic sleeve, a damper, a permanent magnet and a detection coil; the right end of the measuring rod is closed, one end of the chromium-nickel alloy wire is fixed to the center of the inner wall of the right end of the measuring rod, the other end of the chromium-nickel alloy wire penetrates through the measuring rod, enters the shell and is connected with the right end of the Fe-Ga wire at the right portion in the ceramic sleeve, and the left end of the Fe-Ga wire passes through the interior of the ceramic sleeve, penetrates through the damper and is fixed to the center of the inner wall of the left end of the shell; and the appearance of the measuring rod is a linear measuring rod and a planar disc-shaped measuring rod. According to the invention, the noise signal influence caused by high voltage, high frequency and vibration in ultrasonic temperature measurement can be effectively reduced.

The invention discloses a novel chromium-nickel alloy and a method for centrifugally casting and producing a high-temperature dusting corrosion resistant furnace tube by using the alloy. The contents of chemical ingredients of the novel chromium-nickel alloy are as follows: 0.3-0.5% of Si, 0.3-0.5% of Mn, not more than 0.02% of P, not more than 0.01% of S, 24-26% of Cr, 59.3-65.5% of Ni, not more than 0.5% of Mo, 0.03-0.05% of Cu, 1.8-2.4% of Al, and the balance of micro alloying elements, including Ti, Zr and Re. The novel chromium-nickel alloy is adopted to produce the high-temperature dusting corrosion resistant furnace tube through a centrifugal casting method, the produced high-temperature dusting corrosion resistant furnace tube can replace an imported rolled 602CA alloy furnace tube, the requirement of a petrochemical high temperature device on an alloy furnace tube with metal powder dusting corrosion resistance and hydrogen resistance can be met, and a methanol device can produce methanol through recycled waste gases and tail gases.

End support for parallel tubes of a superheater or reheater with a bend tubular portion, a linear tubular portion extending away from each end of the bend tubular portion, and a supporting member formed on a curved section of the bend tubular portion. The tubular portions form a connection between two consecutive parts of a fluid passage. In a preferred embodiment, the tubular portions and the supporting member are integrally formed, molded or cast of a suitable material, such as carbon steel, stainless steel, chromium-nickel alloy, or other suitable alloys that have high temperature strength and oxidation resistance. The supporting member is configured to securely attach the end support configuration to the wall support brackets on the wall support tube. Preferably, the supporting member and the wall support bracket slide on one another to provide relative movement between the superheater tubes and the wall support or boiler tubes.

The invention discloses a method for preparing a low-sulfur iron-chromium-nickel alloy block through stainless steel dust. The method is conducted according to the following steps that firstly, a bonding agent and an additive are added into stainless dust after the stainless dust is broken, and the stainless dust is prepared into a mixed raw material; secondly, the mixed raw material is put into a die to be pressed into a block, the block is dried to reach constant weight, and a cold consolidation block is obtained; and thirdly, the cold consolidation block and cast iron are put into an alumina crucible in a reducing furnace to be heated to 1400 DEG C to 1600 DEG C and are reduced for 40 min to 50 min, and the iron-chromium-nickel alloy block and slag are obtained in the alumina crucible. By means of the method, the stainless steel dust can be directly used for preparing the iron-chromium-nickel alloy block needed in stainless steel production, the production technology is relatively simple, rough products have the beneficial effects that impurities are few and purity is high; and stainless steel other liquid source supply in the stainless steel production process can be achieved on the premise that high additional value utilization of stainless steel dust of a steel making enterprise is achieved.

The invention provides a chromium-nickel alloy sputtering target material and a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing chromium powder and nickel powder to obtain chromium-nickel powder; (2) filling and compacting the chromium-nickel powder obtained in the step (1) to obtain a chromium-nickel green body; (3) conducting vacuum hot pressing sintering treatment on the chromium-nickel green body obtained in the step (2) at the temperature of 850-1200 DEG C to obtain a chromium-nickel blank; and (4) machining the chromium-nickel blank obtained in the step (3) to obtain the chromium-nickel alloy sputtering target material. According to the preparation method provided by the invention, the compactness and microstructure uniformity of a target product are improved, and internal defects are eliminated.

The invention discloses a high-resistance chromium-nickel electrothermal alloy material for electric heating elements. The alloy material comprises a chromium-nickel alloy main body, wherein the chromium-nickel alloy main body is subjected to film coating treatment; the film coating treatment comprises the following steps: (1) sequentially adding 1-2 parts (by weight) of sodium silicate, 1.1 parts (by weight) of hydrolytic polymaleic anhydride, 2.8 parts (by weight) of polyethylene glycol and 0.7 part (by weight) of sodium alkylarylsulfonate into 40 parts (by weight) of deionized water, and carrying out uniform stirring; (2) then, sequentially adding 5.9 parts (by weight) of methyl laurate, 3.1 parts (by weight) of methacrylic acid, 1.3 parts (by weight) of sodium alpha-cyclohexylsulfamate and 0.8 part (by weight) of N-phenyl-2-naphthylamine into the solution, and continuing to carry out stirring until thorough and uniform mixing is achieved, so as to prepare a film coating treatment solution; (3) dipping the chromium-nickel alloy main body in the film coating treatment solution, taking out the chromium-nickel alloy main body, and then, baking the chromium-nickel alloy main body. According to the high-resistance chromium-nickel electrothermal alloy material for the electric heating elements, disclosed by the invention, the surface of the chromium-nickel alloy main body is coated with a protective film, so that the performance is good, and the surface smoothness is good.

The invention discloses application of a chrome-nickel containing alloy vertical concentrated sulfuric acid cooler in a low-temperature-position waste heat recycling device and a power generation system comprising the same. The chrome-nickel containing alloy is composed of 19-30% of Cr, 5-50% of Ni and greater than or equal to 0.5 and less than or equal to 3 of (Cr+Si)/(Ni+Mo) or 19-30% of Cr, 5-50% of Ni and greater than or equal to 0.54 and less than or equal to 2.9, and the vertical concentrated sulfuric acid cooler has an anode protection system. The cooler has wider application range andbetter environment-friendly performance than existing concentrated sulfuric acid. The cooler has the main advantages that on an acid side, usable sulfuric acid concentration range is 93-100%, usable temperature range is 40-130 DEG C, equipment corrosion rate is lower than or equal to 0.1mm per year, and service life of the concentrated sulfuric acid cooler is longer than or equal to 8 years; shell-side acid concentration of the cooler is 93-100%, and temperature range is 40-130 DEG C; circulating water on a tube side is 0-130 DEG C; a cathode of the vertical protection concentrated sulfuric acid cooler is arranged perpendicular to a barrel, so that the defect of cathode replacement at the top end of equipment is avoided. The cooler is compact in structure, small in occupied area and suitable for existing anode protection concentrated sulfuric acid coolers realizing cooling through circulating water and organic working media.

The invention discloses a chromium-nickel electrothermal alloy material which comprises a chromium-nickel alloy main body, wherein the chromium-nickel alloy main body is subjected to filming treatment; the filming treatment comprises the following steps: (1) sequentially putting 1-2 parts by weight of alkylolamides polyoxy ethane ether, 1.2 parts by weight of sodium xylene sulfonate, 2.3 parts byweight of vinyl acetate and 2.8 parts by weight of potassium sodium tartrate into 35 parts by weight of deionized water, and uniformly stirring; 92) further sequentially adding 2.6 parts by weight of2-phosphate-1,2,4-tricarboxylic acid butane, 1.9 parts by weight of sodium hexametaphosphate, 3.7 parts by weight of 1,3 glutaric acid morpholine and 2.8 parts by weight of 2-aminoethyl heptadecene imidazoline, continuously stirring till sufficient and uniform mixing is achieved so as to obtain a filming treatment solution; and (3) soaking the chromium-nickel alloy main body into the filming treatment solution, taking out, and drying. As the surface of the chromium-nickel alloy main body is covered by a protection film, the chromium-nickel electrothermal alloy disclosed by the invention is good in performance and good in surface smoothness.

The invention provides superfine ground calcium carbonate and a preparation method thereof, and belongs to the technical field of ground calcium carbonate. Mixing calcite particles, water and a grinding aid to obtain a mixture; the grinding aid comprises polyethylene glycol, diethylene glycol and a titanate coupling agent; carrying out ball milling on the mixture to obtain a ball-milled material; a grinding medium of the ball mill is an Al2O3 ceramic ball or a zirconia ball, and a lining of the ball mill is an Al2O3 full-ceramic lining or a chromium-nickel alloy lining; and grading the ball-milled material to obtain the superfine heavy calcium carbonate. The ball-milled lining is an Al2O3 full-ceramic lining or a chromium-nickel alloy lining, so that the situation that the product is polluted due to the fact that scrap iron of a traditional iron lining and a steel ball is brought in is effectively avoided, the whiteness of the product and the low iron impurity content are guaranteed, the influence on the whiteness of calcium carbonate is small, the iron impurity content is low, and the problems that the whiteness is influenced by a traditional dry ball-milling process, and the product quality is poor are solved. And the product has high magnetic substance content (iron scrap pollution).

The invention belongs to the field of welding materials, and particularly relates to an anti-coating reddening and anti-cracking double-core flux-coated electrode for stainless steel welding. The coreis formed by connecting a solid core with beads and a hollow core with grooves through matching the beads with the grooves, a gap of 0.8-1.2mm is reserved between the solid core and the hollow core,and the outer surface of the hollow core is coated with a coating. The hollow core is made of carbon steel, the volume expansion is small after the hollow core is heated, the generated resistance heatis little, and the phenomena of reddening and cracking of the coating are avoided. The solid core is made of chromium-nickel alloy, the volume expansion is large after the solid core is heated, and much resistance heat is generated. Due to the gap between the solid core and the hollow core, the outer circle of the hollow core does not expand, the heat generated by the solid core can be rapidly dissipated from the gap, and the phenomena of reddening and cracking of the coating are avoided. After the electrode is melted, elements such as nickel and chromium can be uniformly mixed with other parts of a molten pool under the action of electric arc blowing force, and chemical components of a formed weld joint meet the requirements of stainless steel deposited metal.