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95 results about "Phenol degradation" patented technology

Preparation method for mesoporous hollow spherical TiO2 having high visible light catalysis performance

The invention relates to a preparation method for mesoporous hollow spherical TiO2 having high visible light catalysis performance. The preparation method is characterized in that carbon microspheres prepared by adopting glucose as a raw material under high temperature and high pressure hydrothermal conditions are adopted as a template agent, titanium tetrachloride is adopted as a titanium source, urea is adopted as a nitrogen source, an acid catalyzed hydrolysis method is adopted to prepare a spherical TiO2 precursor, the pH value is adjusted with ammonia water, centrifugal separation is performed to obtain a white solid product, a heat treatment is performed on the obtained product at a high temperature in a tube type resistance furnace, and the carbon microsphere template agent is removed to obtain the hollow spherical TiO2 having the mesoporous structure, wherein the obtained hollow spherical TiO2 has high phenol degradation performance under visible light. According to the present invention, the main characteristics of the operation process comprise that the carbon microspheres prepared from the glucose are adopted as the template agent, the titanium tetrachloride is subjected to acid catalyzed hydrolysis and then is coated on the surface of the carbon microspheres, and the high temperature calcination is performed to form the spherical TiO2 with characteristics of hollow structure, rich mesopore, and visible light catalysis activity, wherein the phenol degradation rate of the mesoporous hollow spherical TiO2 achieves 80-90% after light irradiation for 3 h when the calcination temperature is 700 DEG C.
Owner:NORTHEAST FORESTRY UNIVERSITY +1

Device and method for degrading phenol and ammonia nitrogen simultaneously by virtue of microbial fuel cell

The invention belongs to the technical field of wastewater treatment and discloses a device and method for degrading phenol and ammonia nitrogen simultaneously by virtue of a microbial fuel cell. The method comprises the following steps: by building a double-chamber microbial fuel cell system, inoculating domesticated electricity-producing mixed bacterial liquid and denitrifying bacteria to an anode chamber, adding sodium acetate as an electron donor, taking mixed liquid of a phosphate buffer solution of 0.1mol / L with pH value of 7.0 and culture liquid as nutritional substances, and meanwhile, providing a relatively strict anaerobic environment; adding phenol and ammonia nitrogen-containing wastewater and mixed sludge taking the nitrifying bacteria domesticated through ammonia nitrogen and phenol, and phenol degradation bacteria as main components into a cathode chamber, filling air through an aeration device, and connecting a closed circuit switch with an external circuit to start the microbial fuel cell so as to degrade ammonia nitrogen and phenol in the cathode chamber simultaneously. The device and the method are used for removing phenol and ammonia nitrogen in the wastewater, and have good economic and environment-friendly benefits.
Owner:SOUTH CHINA UNIV OF TECH

High-stability ordered mesoporous carbon loaded Fenton catalyst, and preparation method and application thereof

The invention discloses a preparation method and application of a high-stability ordered mesoporous carbon loaded Fenton catalyst. The catalyst comprises a carrier and alpha-FeOOH growing on the surface of the carrier, wherein the carrier is ordered mesoporous carbon having undergone wet oxidation treatment. The preparation method comprises the following steps: subjecting ordered mesoporous carbon to wet oxidation treatment; then carrying out washing and drying, and soaking the ordered mesoporous carbon in a ferric nitrate solution; and subjecting a material obtained in the previous step to washing and drying and then to hydrothermal treatment in aqueous alkali so as to obtain the ordered mesoporous carbon supported Fenton catalyst. The catalyst prepared in the invention has good hydrophilicity and can be uniformly dispersed in water; aciculiform alpha-FeOOH grows on the surface of ordered mesoporous carbon, and the loading amount of ordered mesoporous carbon is adjustable; when applied to decolouring and phenol degradation of rhodamine B, the Fenton catalyst has good degradation effect in a wide pH scope; and the Fenton catalyst has the advantages of high activity, good stability, a wide pH application scope and small iron loss, and overcomes the problem that conventional homogeneous Fenton reactions produce iron-containing sludge and are restricted by the pH value of sewage.
Owner:SHANGHAI JIAO TONG UNIV

Bacillus foecalis alkaligenes and method for catalysis degradation of phynol wastewater

The invention discloses a microbial strain which can effectively degrade phenol and relates to alcaligenes faecalis JH1013 CCTCC NO: M 208006 and a method for degrading phenol wastewater by using a fixed alcaligenes faecalis that is produced by alcaligenes faecalis. The method has the following advantages that: 1. the alcaligenes faecalis is easy to culture, the fixing technique is simple, the catalytic degradation effect is good, the high-concentration phenol can be resistance, the phenol degradation capacity is strong, which can high efficiently degrade the phenol wastewater with the concentration of as high as 2000mg. L<-1> and be used repeatedly; 2. hydrotalcite, hydrotalcite-like compounds, nano calcium carbonate, Gamma-Al2O3 or the loading solid base are used as carriers for preparing the fixed alcaligenes faecalis, the elasticity is good, the temperature and pH value resistances are strong, the mechanical strength is high, the degradation performance is stable and the half-time is long; 3. the carriers of the hydrotalcite, the hydrotalcite-like compounds, the nano calcium carbonate and the Gamma-Al2O3 of the fixed cell can be used repeatedly by calcinations; 4. the fixed alcaligenes faecalis is used for degrading the phenol, the degradation process is simple, the conditions are moderate, the environment is friendly, the bacterial cells are difficult to loss, the concentration of the microorganisms in the carriers is high, the degradation speed is fast, the degradation efficiency is high and the secondary pollution is not easy to be caused.
Owner:XIANGTAN UNIV

Microorganism reduced noble metal (S) modified TiO2 catalyst and its prepn. method

A microbe reduced and noble metal modified TiO2 catalyst for catalytic degradation of phenol has a formula No-La / TiO2, where No is Ag and / or Pd. Its preparing process includes such steps as calcining TiO2, ultrasonic dispersing, adding it into the bottle containing microbe R08 and SH10, dark culture, impregnating in the solution of nitrate or chloride of noble metal, laying aside, washing, putting it in flowing N2, and carrying the nano-particles of noble metal by the í‹anchoríŒ and reducing action of microbes.
Owner:XIAMEN UNIV

Zeolite Fenton catalyst containing isolated metal species as well as preparation method and application thereof

The invention belongs to the technical field of wastewater treatment catalyst preparation and particularly relates to a zeolite Fenton catalyst containing an isolated metal species as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing zeolite with a metal chloride precursor solution to prepare a catalyst precursor; and then preparing the Fenton catalyst containing the isolated metal species with a freeze-drying method. According to the zeolite Fenton catalyst containing the isolated metal species prepared with the method, the tetra-coordinated isolated metal species content reaches up to 8.90%; in a process of degrading phenolic waste water, the catalyst has high phenol degradation catalysis efficiency and hydrogen peroxide utilization efficiency as well as low active species leakage amount; and the catalyst is simple in preparation process, low in device requirement and low in cost, can be produced on a large scale and is applied to an actual wastewater treatment process.
Owner:TIANJIN POLYTECHNIC UNIV

Method for preparing stanniferous double-perovskite type phenol photocatalytic degradation catalyst

The invention discloses a method for preparing a stanniferous double-perovskite type phenol photocatalytic degradation catalyst. The catalyst is applied to carrying out a degradation reaction on low-concentration phenol sewage under the condition of simulated sunlight. According to the catalyst, a sol-gel method is used for preparation, and saccharose serves as a complexing agent. The method includes the steps that Sn powder is dissolved into a dilute nitric acid solution in a cold bath first, the obtained light yellow settled solution is then subjected to reacting and complexing with La(NO3)3-6H2O(1 / 8), Fe(NO3)3-9H2O(1 / 8) and polyethylene glycol 2000, and after roasting is conducted for 3 hours in the air atmosphere of 700 DEG C, a pure-phase double-perovskite type La2FeSnO6 photocatalyst sample is obtained. The molar ratio of selected La atoms to Fe atoms to Sn atoms is 2:1:1. The molar ratio of the saccharose to metal cations is 2:1. The method has the advantages that the sol-gel method with the saccharose used as the complexing agent is used for preparation, and the pure-phase double-perovskite type catalyst La2FeSnO6 is synthesized at a low temperature. The preparation method is simple, low in cost and free of pollution. The method has high catalytic activity and good structural stability when being used for low-concentration phenol degradation.
Owner:INNER MONGOLIA UNIVERSITY

Phenol degrading and regulating gene and acting promoter thereof

The invention discloses a phenol degrading and regulating protein and a nucleotide sequence for coding the protein. The invention also discloses an acting phenol hydroxylase promoter of the phenol degrading and regulating protein and a functional binding site for the phenol degrading and regulating protein in the sequence of the promoter. The invention constructs a recombinant vector including the gene and a testing expression vector of the phenol hydroxylase promoter, and implants the two vectors into Escherichia coli. As proved by tests, the invention expresses the regulating gene in the Escherichia coli to activate the expression of the phenol hydroxylase promoter, thus acting as a whole-cell biological sensor to detect phenolic compounds including phenol, pyrocatechol, orthocresol, dichlorophen and the like.
Owner:THE INST OF BIOTECHNOLOGY OF THE CHINESE ACAD OF AGRI SCI

Phenol-degradation microbial agent, immobilized globules and preparation method

The invention provides a phenol-degradation microbial agent, immobilized globules and a preparation method. Microorganisms in the phenol-degradation microbial agent are separated and extracted from surface filter materials of a biological manganese sand filter pool of a waterworks, and after the microorganisms are cultured and screened in a manganese-contained MSVP liquid medium and a manganese-contained MSVP solid medium and are activated in a TBS medium, the phenol-degradation microbial agent is prepared. The invention further provides the preparation method for preparing the phenol-degradation microbial agent into the immobilized globules. According to the preparation method, the gel globules are prepared by using cross-linking polymerization products of silicon dioxide or manganese dioxide and sodium alginate as carriers and embedding the phenol-degradation microbial agent. The phenol-degradation microbial agent can be applied to rapidly degrading phenol at low-temperature oxygen-free and neutral conditions of underground water. The phenol-degradation microbial agent immobilized globules can provide stable degradation environment, are more suitable for toxic environment, and are used for treating phenol pollution of the underground water with higher concentration.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Iron-sulfur coupled catalyst capable of efficiently degrading high-concentration phenol, and preparation method and application of catalyst

The invention belongs to the technical field of catalytic materials, and particularly relates to an iron-sulfur coupled catalyst capable of efficiently degrading high-concentration phenol, and a preparation method and application of the catalyst. The preparation method of the catalyst comprises the following steps: 1) preparing goethite; 2) mixing an iron-source material with deionized water, introducing nitrogen and carrying out stirring until the iron-source material is dissolved; 3) adding the goethite prepared in the step 1), continuously introducing nitrogen, and continuously carrying outstirring; and 4) adding a sulfide solution, continuously introducing nitrogen and continuously carrying out stirring, then carrying out centrifuging to remove the supernatant to obtain a solid, and carrying out vacuum freeze drying on the solid to obtain the iron-sulfur coupled catalyst. The catalyst can improve performance of a Fenton process system for treating organic pollutants and improve degradation efficiency on the organic pollutants. High-efficiency phenol degradation can be realized in a neutral or acidic environment, and cost of phenol treatment can be reduced. The novel high-efficiency Fenton reaction process system provided by the invention has an important application prospect.
Owner:SOUTH CHINA NORMAL UNIVERSITY
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