The invention discloses a worm-expelling mold-proof and environmentally-friendly composite board. The worm-expelling mold-proof and environmentally-friendly composite board is characterized by being made of, by weight, 5-10 parts of camphorwood powder, 5-10 parts of elm bark powder, 20-30 parts of manioc waste, 3-5 parts of purple perilla powder, 10-15 parts of kieselguhr, 0.5-1 part of eucalyptus oil, 0.5-1 part of litsea cubeba oil, 0.5-1 part of sodium diacetate, 1-2 parts of sodium humate, 1-2 parts of zinc oxide, 3-5 parts of magnesium stearate and 10-20 parts of bonding accessory ingredient. The worm-expelling mold-proof and environmentally-friendly composite board has good worm-expelling, mold-proof and mothproof functions, and can clean indoor air, the intensity and toughness are good, the property is stable, the texture is even, and the using performance is good; the source of the raw materials is wide, and the composite board is economic, practical, toxic free, harmless, environmentally friendly, and suitable for being applied to indoor environment.