A spirally configured cis-stilbene/fluorene hybrid material is shown in formula (1),
R′ is an alkyl group or represented by formula (2),
wherein R1 to R4, R6, R8 to R11 and R13 to R18 are independently selected from the group consisting of hydrogen atom, halogen atom, cyano group, alkyl group, cycloalkyl group, alkoxy group, amino group, haloalkyl group, thioalkyl group, silyl group and alkenyl group, R5 is a hydrogen atom, tert-butyl group or aryl group, R7 and R12 are independently selected from the group consisting of hydrogen atom, aryl group, diarylamino group, cyano group, heteroaryl (e.g., pyridine group, or pyrimidine group).