The invention discloses boiling-resistant aqueous composite ink and a preparation method thereof. The boiling-resistant aqueous composite ink mainly comprises raw materials including aqueous 
polyurethane resin, a 
pigment and water, and a surface 
wetting agent, a 
wetting dispersing agent and a defoaming agent are additionally added. The preparation method of the boiling-resistant aqueous composite ink comprises the following steps of: firstly, adding partial aqueous 
polyurethane resin into a stirring reaction kettle; secondly, slowly adding the surface 
wetting agent, the wetting dispersing agent and partial defoaming agent, and adding the 
pigment after stirring and dispersing; thirdly, stirring and dispersing at high speed, and 
grinding after dispersing; fourthly, adding the residual aqueous 
polyurethane resin and defoaming agent and stirring and dispersing, and adding the water until the required 
viscosity is obtained through regulation; and at last, stirring, dispersing, filtering and packaging. The boiling-resistant aqueous composite ink, provided by the invention, is prepared by taking the high-performance aqueous polyurethane resin as a connecting material, and has the advantages of good 
pigment dispersibility, wide use range, lower film forming temperature, better 
mechanical property of formed film, more uniform 
particle size distribution and the like, and can be used for soft 
retort packages.