The invention provides an environment-friendly grafted chloroprene rubber plant cleaning agent and a preparing method thereof. The cleaning agent is prepared from, by weight, 18-22 parts of phosphoric acid, 16-19 parts of glycolic acid, 11-14 parts of ethoxyl ammonium salt of alkylphenol, 11-12 parts of ethylene tetraacetic acid tetrasodium, 11-13 parts of xanthic acid gum, 12-14 parts of methylbenzene, 25-27 parts of methyl ethyl ketone, 10-12 parts of chloroprene rubber DCR-10, 8-9 parts of MMA, 1-3 parts of BPO1, 3-5 parts of BHT, 6-9 parts of phenolic resin, 30-50 parts of water, 4-5 parts of draba, 10-12 parts of cassia twigs, 10-12 parts of radix paeoniae alba, 10-12 parts of dried ginger, 8-10 parts of ephedra herbs, 8-10 parts of pinellia ternate, 5-8 parts of thunberg fritillary bulb, 3-5 parts of asarum sieboldii, 10-15 parts of schisandra chinensis, 8-10 parts of liquorice and 4-5 grains of scented tea. The cleaning agent has the advantages that the preparing technology is simple and convenient, the cleaning agent is not pungent in the cleaning process, plant ingredients in the formula are used for neutralization, and therefore environment-friendly and pollution-free effects are achieved; meanwhile, during application, contamination of petroleum and the like is cleaned mainly; compared with a common cleaning agent, the cleaning agent is good in decontamination effect, high in neutralizing capacity and obvious in use effect.