The invention discloses a preparation method of nano-coated composite 
powder, and belongs to the technical field of material preparation. According to the preparation method of the nano-coated composite 
powder, in the preparation process, a precipitant is added into an organic solution containing 
powder particles and 
metal compounds, a nano-precursor wrapping the surfaces of the powder particles is obtained, the nano-coated composite powder of a 
nucleus-shell structure is obtained through reduction, through a 
solvation effect of the 
metal compounds in the organic solution and the weak 
electrolyte property of the precipitant in the organic solution, the defects of too high local concentration, too long reaction time and 
large particle size of reaction products during the 
precipitation reaction are overcome, the average particle size of the prepared 
metal precursor is smaller than 200 nm, the metal precursor wraps the surfaces of the powder particles in a colloidal state, after low temperature reduction, nano metal or 
alloy particles adhere to the surfaces of the powder particles, and a nano-
coating layer with highly uniform phase distribution is formed.