The invention provides composite silver
soldering paste and a preparation method and application thereof.The preparation method comprises the following steps that
silver nitrate and PVP are dissolved in an
ethylene glycol solution, and stirring is conducted for 20-45 min through a constant-temperature
magnetic stirrer at the temperature of 45-75 DEG C; adding a certain amount of HCl into the
mixed solution, magnetically stirring for 15-30 minutes, and cooling to
room temperature; putting the mixture into a reaction kettle, and performing vacuum constant-temperature heating for 150-200min at 100-190 DEG C; and after washing with deionized water and absolute ethyl
alcohol, carrying out ultrasonic treatment to obtain the composite silver
soldering paste. According to the multi-scale composite silver
soldering paste, an
ethylene glycol reduction method is adopted, silver ions in a solution are reduced into silver atoms, submicron or micron particles are secondarily grown on the basis of nano-
silver particles, and the multi-scale composite silver soldering paste is prepared and has better electrical and mechanical properties; the multi-scale
silver particles are easy to generate, the
reaction conditions are easy to control, the preparation method is simple, safe and
environmentally friendly, the needed
raw material types are few, the number of devices is small, few
organic matter is added, and the nano-
silver particles controllable in morphology and size are easy to obtain.