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46results about How to "High decomposition activity" patented technology

Low-temperature activation efficient ammonia decomposition catalyst

The invention provides a low-temperature activation efficient ammonia decomposition catalyst and a preparation method thereof, and belongs to the field of ammonia decomposition catalysis. The catalyst is a nickel-containing FER molecular sieve; according to the molecular sieve, a nickel-containing carbon material is taken as a nickel source and a hard template agent, and metal nickel is introduced into the FER molecular sieve in situ; and the content of nickel in the nickel-containing molecular sieve is 0.1-5wt.% in terms of nickel element. the invention also provides a preparation method of the catalyst. The method specifically comprises the following steps of: adding a nickel-containing carbon material, a silicon source, an aluminum source, an organic template agent, inorganic base and a solvent into a reactor according to proportions; continuously stirring the materials to obtain uniform sol, aging the uniform sol; transferring the sol to a hydrothermal reaction kettle for crystallization; performing filtering, washing, drying and roasting on a product which is obtained after the reaction is finished; carrying out hydrogen transformation on an obtained molecular sieve; and finally roasting to obtain the nickel-containing FER molecular sieve. The catalyst disclosed by the invention has the advantages of rich microporous structure, short crystallization time and high catalyst activity and stability; the temperature required by ammonia decomposition is greatly reduced; and the catalyst has huge industrial application potential.
Owner:XIAMEN UNIV

Ammonia decomposition catalyst

Disclosed is an ammonia decomposition catalyst which is obtained by subjecting a complex to a heat treatment at a temperature of 360-900 DEG C in a reducing atmosphere, said complex being obtained by coordinating a transition metal to a polymer that is represented by formula (I) and has a molecular weight of 1,000-500,000, and adding activated carbon or a carbon nanotube to the polymer. In the case when a carbon nanotube is added, an alkali metal compound or an alkaline earth metal compound is added to the heat-treated complex. In formula (I), R1 represents H or a hydrocarbon group having 1-10 carbon atoms; R2 and R3 each represents H, a halogen, a nitro group, an acyl group, an ester group, a carboxyl group, a formyl group, a nitrile group, a sulfone group, an aryl group or an alkyl group having 1-15 carbon atoms; X and Y each represents H or OH; Z represents CH or N; R4 and R5 each represents H, OH, an ether group, an amino group, an aryl group or an alkyl group having 1-15 carbon atoms; x represents a real number between 1 and 2; y represents a real number between 1 and 3; and n represents a real number between 2 and 120. The ammonia decomposition catalyst is capable of increasing the amount of transition metal loaded thereon without lowering the dispersion of the transition metal, and is capable of reducing the use amount of catalyst necessary for obtaining desired activity.
Owner:HITACHI ZOSEN CORP +2

Preparation method of nitric acid industrial carbon emission reduction catalyst

The invention discloses a preparation method of a nitric acid industrial carbon emission reduction catalyst. The method comprises the following steps: 1, dissolving an active component precursor and an auxiliary agent precursor in deionized water to obtain a transparent dipping solution; 2, adding the cerium dioxide powder into a dipping solution for dipping treatment, and drying to obtain a catalyst precursor; 3, uniformly mixing an adhesive, a pore forming agent and the catalyst precursor, adding water, kneading, and carrying out extrusion molding to obtain a catalyst blank; and 4, drying the catalyst blank, and roasting to obtain the nitric acid industrial carbon emission reduction catalyst. According to the present invention, the types and the proportions of the active components and the auxiliary agent are designed, and the roasting treatment process and the process parameters are controlled so as to obtain the catalyst with the relatively dispersed active components and the high crystallinity, such that the number of the effective active centers in the catalyst is increased so as to improve the activity of the catalyst, and the catalyst has better high-temperature stability and is suitable for N2O emission reduction in the nitric acid production process.
Owner:XIAN ORIGIN CHEM TECH
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