The invention relates to a method for preparing high-purity 
vanadium pentoxide by use of a stone 
coal one-
step method. The technical solution is as follows: a 
fluidized bed furnace for one-step 
roasting of stone 
coal is adopted to perform one-step 
fluidized bed roasting on the stone 
coal; roasted materials are leached in three segments, final 
pickling slurry is subjected to primary separation so as to obtain final pickle liquor, secondary overflow is returned to be subjected to primary size mixing, and 
tertiary overflow is returned to be subjected to secondary size mixing; the pH value of the final pickle liquor is regulated, and slags obtained after regulation are returned to a segment III so as to be leached; the regulated pickle liquor is crystallized to obtain a 
potassium alum byproduct; after 
crystallization, the liquid is subjected to reduction and 
precipitation-based 
impurity removal, and filter residues are dried to obtained a 
ferrous oxalate byproduct; after 
impurity removal, pH value regulation is performed on the liquid by use of weak 
acid salt, then counter-current extraction is performed on the liquid, and extraction 
raffinate is returned to be subjected to 
tertiary size mixing; after being washed, the loaded organic phase is subjected to countercurrent reverse extraction; a lean organic phase is regenerated and then is returned to be extracted; after a 
vanadium-rich solution is oxidized, 
urea is added, stirring is performed, the obtained 
molybdenum precipitation mother solution is returned to be subjected to primary size mixing, and 
ammonium polyorthovanadate is calcinated to prepare 
vanadium pentoxide. The method has the characteristics of short process flow, less 
pollution, low 
energy consumption, less chemical usage, high vanadium 
recovery rate and high product purity.